CAS: 335-76-2; 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Nonadecafluorodecanoic Acid

该化合物是一种全氟碳酸,其特点是用氟原子完全取代长碳链,具体含有19个氟原子和10-亚酸脊椎;该化合物是以其独特的特性,包括高热稳定性,耐化学降解和低表面紧张度而闻名的更大类别全氟烷基物质的一部分;无氨氟二氮酸一般是一种固体,在室内温度下表现出疏水和疏脂特征,因此在各种工业应用中有用,包括表面活性剂和涂层;然而,与许多全氟烷基物质一样,它因其在环境中的持久性和潜在的生物累积性,引起了环境和健康问题;其生产和使用受到越来越多的监管审查,反映出对与全氟化合物有关的生态和健康影响的认识日益提高.

结构式图片

欧盟法规

统一分类与标签ECHA物质工作场所安全标识要求ECHA物质化妆品禁用物质清单C&L通报食品接触材料-禁用CMR物质REACH预注册欧盟候选物质清单废弃物危险特性清单

上下游产品

CAS号334-48-5 正癸酸 | CAS号2082-76-0 癸酸酐 | CAS号307-79-9 全氟癸酸甲酯 | CAS号307-38-0 2,2,3,3,4,4,5,5...

合成工艺路线路线简述

  • 合成目标产物 Perfluorodecanoic Acid 主要起始原料 Decanoic Acid
  • (文献来源)合成步骤主要原料 Decanoic Acid
📜Alkaline Earth Salt Of/the/ Methylsulfuric Acid置于二氧化氮体系中,化学反应生成 十九氟癸酸
参考文献:Process Of Making Fluorocarbon Carbonyl Fluorides
标题:Process Of Making Fluorocarbon Carbonyl Fluorides

海关参考信息

专利信息


专利号:US-11400438-B2
优先权日:2018-12-05
标 题 :Synthesis and immobilization of a ferrous sulfite catalyst and method of degrading fluorinated organic chemicals in aqueous media
发明人:DIONYSIOU DIONYSIOS D; ABDELRAHEEM WAEL H M; NADAGOUDA MALLIKARJUNA N
权利人:UNIV CINCINNATI; THE US ADMINISTRATOR OF THE U S ENVIRONMENTAL PROTECTION AGENCY
摘要:A composition includes an aqueous solution including at least one fluorinated organic compound; and a reaction product of a source of iron(II) and a source of sulfite in the presence of water and molecular hydrogen. A method of making a catalyst includes reacting a source of iron(II) and a source of sulfite in the presence of water and molecular hydrogen. The water may include less than or equal to 1 weight percent dissolved molecular oxygen. The catalyst may be used for degrading fluorinated organic chemicals in aqueous media.

专利号:US-4273947-A
优先权日:1979-01-31
标 题:Hydrogenation of fluorine-containing carboxylic acids
发明人:NOVOTNY MIROSLAV
权利人:ALLIED CHEM
摘要:A process is described for the heterogeneous hydrogenation of fluorine-containing alkyl, cycloalkyl, and benzene carboxylic acids to the corresponding primary alcohols. The hydrogenation can be carried out in the liquid or vapor phase in the presence of a solid rhodium or iridium catalyst, employed as the metal, metallic oxide, or mixture thereof. In the liquid phase, the hydrogenation can be carried out batchwise under mild conditions of temperature and pressure, preferably at about 50°-150° C. and about 5-15 atmospheres, in an atmosphere containing hydrogen gas. A preferred embodiment is the hydrogenation of trifluoroacetic acid in the liquid phase to 2,2,2-trifluoroethanol, said alcohol being useful as an intermediate in the synthesis of the anesthetic, isoflurane, CF 3 CHClOCHF 2 .

专利号:US-8999189-B2
优先权日:2010-03-09
标 题 :Ferroelectric fluoride compositions and methods of making and using same
发明人:HALASYAMANI P SHIV; CHANG HONG-YOUNG
权利人:HALASYAMANI P SHIV; CHANG HONG-YOUNG; UNIV HOUSTON SYSTEM
摘要:A method for synthesis of a ferroelectric material characterized by the general formula A x B y F z where A is an alkaline earth metal, B is transition metal or a main group metal, x and y each range from about 1 to about 5, and z ranges from about 1 to about 20 comprising contacting an alkaline earth metal fluoride, a difluorometal compound and a fluoroorganic acid in a medium to form a reaction mixture; and subjecting the reaction mixture to conditions suitable for hydrothermal crystal growth.

专利号:US-2010311615-A1
优先权日:2009-06-09
标 题:Method for synthesis of titanium dioxide nanotubes using ionic liquids

专利号:WO-2024215360-A2
优先权日:2022-05-08
标 题 :Synthesis of shape-controlled polymer nano/microstructures using initiated chemical vapor deposition (icvd) polymerization in structured liquids

专利号:US-8585886-B2
优先权日:2009-06-09
标题 :Method for synthesis of titanium dioxide nanotubes using ionic liquids
发明人:QU JUN; LUO HUIMIN; DAI SHENG
权利人:QU JUN; LUO HUIMIN; DAI SHENG; UT BATTELLE LLC
摘要:The invention is directed to a method for producing titanium dioxide nanotubes, the method comprising anodizing titanium metal in contact with an electrolytic medium containing an ionic liquid. The invention is also directed to the resulting titanium dioxide nanotubes, as well as devices incorporating the nanotubes, such as photovoltaic devices, hydrogen generation devices, and hydrogen detection devices.

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

主要参考文献


1: Pan X, Ye J, Zhang H, Tang J, Pan D. Occurrence, Removal and Bioaccumulation of Perfluoroalkyl Substances in Lake Chaohu, China. Int J Environ Res Public Health. 2019 May 14;16(10). pii: E1692. doi: 10.3390/ijerph16101692. doi: 10.1016/j.scitotenv.2019.04.118. Epub 2019 Apr 11. doi: 10.1016/j.tiv.2019.03.041. [Epub ahead of print] doi: 10.1016/j.scitotenv.2019.03.240. Epub 2019 Mar 16. doi: 10.1016/j.scitotenv.2019.02.210. Epub 2019 Feb 15. doi: 10.1039/c8sm02301h. doi: 10.1016/j.envint.2019.01.010. Epub 2019 Jan 24. doi: 10.1016/j.scitotenv.2018.12.278. Epub 2018 Dec 19. doi: 10.1016/j.scitotenv.2018.11.453. Epub 2018 Dec 3. doi: 10.1289/EHP3567.
12: Shu H, Lindh CH, Wikström S, Bornehag CG. Temporal trends and predictors of perfluoroalkyl substances serum levels in Swedish pregnant women in the SELMA study. PLoS One. 2018 Dec 31;13(12):e0209255. doi: 10.1371/journal.pone.0209255. eCollection 2018.
13: Jain RB, Ducatman A. Selective Associations of Recent Low Concentrations of Perfluoroalkyl Substances With Liver Function Biomarkers: NHANES 2011 to 2014 Data on US Adults Aged ≥20 Years. J Occup Environ Med. 2019 Apr;61(4):293-302. doi: 10.1097/JOM.0000000000001532. doi: 10.1016/j.envres.2018.11.033. Epub 2018 Nov 27. doi: 10.1007/s00204-018-2365-y. Epub 2018 Nov 27. doi: 10.3892/or.2018.6856. Epub 2018 Nov 9. doi: 10.1016/j.scitotenv.2018.10.362. Epub 2018 Oct 29. doi: 10.1016/j.scitotenv.2018.07.198. Epub 2018 Jul 22. doi: 10.1016/j.toxlet.2018.09.001. Epub 2018 Sep 11. doi: 10.1016/j.envpol.2018.07.076. Epub 2018 Jul 23.

合成参考文献


参考文献:10.1021/es9034733
摘要:Nilsson H, Kärrman A, Westberg H, Rotander A, van Bavel B, Lindström G. A time trend study of significantly elevated perfluorocarboxylate levels in humans after using fluorinated ski wax. Environ Sci Technol. 2010 Mar 15;44(6):2150–5. doi: 10.1021/es9034733.
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