CAS: 189307-64-0; 3A-Amino-3A-Deoxy-(2As,3As)-Gamma-Cyclodextrin

该化合物是一种复杂的有机分子,其特点是高度具体的立体化学,其表现是广泛使用立体中心;该化合物具有多种氢氧化甲基组,表明其高度的功能化,有可能增强溶解性和回活动;氨基氨基组的存在表明生物活动的潜力,有可能在合成路径中充当离子或前体;手工业中心的复杂安排意味着该物质可能具有独特的光学特性,并且可能涉及医学化学或材料科学等领域;其结构复杂性还可能表明在合成和净化方面存在挑战,使研究人员关注不对称合成和气理解技术.

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2A,3A-Epoxy-Manno-γ-Cyclodextrin 129907-35-3

合成工艺路线路线简述

    📜2A,3A-Epoxy-Manno-γ-Cyclodextrin置于ammonium Hydroxide体系中,用 水 用作溶剂,化学反应 4.0H,以56.7%的收率获得3A-氨基-3A-脱氧-(2As,3As)-γ-环糊精水合物
    参考文献:Synthesis Of C6A-To-C6A And C3A-To-C3A Diamide Linked γ-Cyclodextrin Dimers
    标题:Synthesis Of C6A-To-C6A And C3A-To-C3A Diamide Linked γ-Cyclodextrin Dimers
    摘要:The Syntheses Of Three New Diamide-Linked Gamma-Cyclodextrin Dimers Joined By Substitution At Either A Glucopyranose C6(A) Or C3(A) Carbon Are Reported. The Syntheses Involve The Reaction Of Either C6(A) Or C3(A) Amino-Substituted Gamma-Cyclodextrin With Bis(4-Nitrophenyl)Succinate To Form Succinamide Linked Gamma-Cyclodextrin Dimers Or Reaction Of C6(A) Aside-Substituted Gamma-Cyclodextrin With Carbon Dioxide To Form A Urea Linked Gamma-Cyclodextrin Dimer. (C) 2010 Elsevier Ltd. All Rights Reserved.
    Doi:10.1016/j.Tet.2010.02.005

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    专利信息


    专利号:US-2011256592-A1
    优先权日:2008-12-12
    标题:Use of cyclodextrins to improve the specificity, sensitivity and yield of nucleic acid amplification reactions
    发明人：BECKERS MARIE-CLAIRE; CRONET PHILIPPE; VITALE ADELINE; COLLETTE ERIC; GULLUKAYA ARZU
    权利人:EUROGENTEC SA
    摘要:The invention is directed to methods for in vitro DNA synthesis catalysed by a DNA polymerase using cyclodextrins. The invention also relates to methods, compositions and kits comprising cyclodextrins for the amplification of a nucleic acid. The use of cyclodextrins improves the specificity, sensibility and/or yield of the amplification reaction. The invention is related more particularly to kits, compositions and methods for carrying out PCR reactions comprising a cyclodextrin.

    专利号:EP-2373811-A1
    优先权日:2008-12-12
    标题 :Use of cyclodextrins to improve the specificity, sensitivity and yield of nucleic acid amplification reactions
    发明人：BECKERS MARIE-CLAIRE; CRONET PHILIPPE; VITALE ADELINE; COLLETTE ERIC; GUELLUEKAYA ARZU
    权利人:EUROGENTEC SA
    摘要:The invention is directed to methods for in vitro DNA synthesis catalysed by a DNA polymerase using cyclodextrins. The invention also relates to methods, compositions and kits comprising cyclodextrins for the amplification of a nucleic acid. The use of cyclodextrins improves the specificity, sensibility and/or yield of the amplification reaction. The invention is related more particularly to kits, compositions and methods for carrying out PCR reactions comprising a cyclodextrin.

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    合成参考文献

    参考DOI号:10.1016/j.tetlet.2008.05.093
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