CAS: 18209-60-4; N-[chloro(Dimethyl)Silyl]-N-Methylmethanamine

该化合物是一种含有分子式C4H12ClNSi的氯硅衍生物,其特点是反应式氯和硅功能组,使其成为有机硅化学的多功能中间体,其主要优点包括核循环替代反应中的高度反应性,能够对经过改良的硅和硅氧进行高效合成;四甲基替代在保持反应性的同时可增强...

英文名称N-[chloro(Dimethyl)Silyl]-N-Methylmethanamine
中文名称二甲基二甲氨基氯硅烷
IUPAC名称N-[chloro(dimethyl)silyl]-N-methylmethanamine
其它别名Silylamine,1-chloro-N,N,1,1-tetramethyl- (6CI,7CI,8CI); (N,N-Dimethylamino)dimethylchlorosilane; Chloro(dimethylamino)dimethylsilane; Chlorodimethyl(dimethylamino)silane
CAS编号18209-60-4
MFCD编号:MFCD00054751
EINECS号:242-095-3
分子式:C4H12ClNSi
分子量:137.68
产品CID: 937436
产品分类化学试剂 → 硅烷试剂

相似结构搜索
InChIKey: CFZHOUYDAHXRLY-UHFFFAOYSA-N
1S/C4H12ClNSi/c1-6(2)7(3,4)5/h1-4H3…
计算化学: 氢键受体数1.0氢键供体数0.0可旋转键数1.0

MSDS等安全信息

GHS符号GHS07
警示词Warning
危险描述H302+H312+H332-H315-H319-H335
防范说明P261-P264b-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P330-P362+P364-P403+P233-P501c
UN编号2985
安全声明9-16-26-33
危险类别码11-34

上下游产品

合成工艺路线路线简述

合成目标产物 (N,N-Dimethylamino)Dimethylchlorosilane 主要起始原料 Bis(Dimethylamino)Dimethylsilane And Dichlorodimethylsilane
(文献来源)合成步骤主要原料 Bis(Dimethylamino)Dimethylsilane 和 Dichlorodimethylsilane

双(二甲基氨基)二甲基硅烷置于四氯化钛体系中,化学反应生成二甲基二甲氨基氯硅烷
参考文献:一些二甲氨基取代的第4组化合物的络合和交换反应
标题:一些二甲氨基取代的第4组化合物的络合和交换反应
摘要:Ch 2(nme 2)2,(1),Sime 2(nme 2)2,(2),[ti(cp)(nme 2)3 ](cp =η-环戊二烯基),(3)和[zr(cp)2(nme 2)2 ],(4),以及共价金属卤化物mcl 4(m = Ti,Zr,Hf,Si,Ge或sn)和mcl 3(m = Ti,V或cr)分为两类:(a)n-供体螯合导致复合物形成,以及(b)卤化物-Nme 2交换.化合物(1)与mcl 4产生1:1配合物(m = Ti或sn)和与vcl 3的2∶1配合物.化合物(2)提供与mcl 4的1:1配合物(m = Ti,Zr,Hf或sn).Ticl 4 .sime 2(nme 2)2-> [ticl 3(nme 2)]的分解总是在固态和溶液中发生.(2)与金属(III)的氯化物没有反应.使用mcl 4(m = Si或ge)时,发生涉及卤化物-Nme 2交换的"加扰"反应,这些反应已通过1
Doi:10.1039/dt9810001264

海关参考信息

2921199090-其他无环单胺
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专利信息

专利号:US-6787615-B2
优先权日:2002-01-25
标题 :Synthesis of oligomeric poly(silarylene-siloxane-acetylene)'s and their conversion to high temperature plastics, elastomers, and coatings
发明人：KELLER TEDDY M; HOMRIGHAUSEN CRAIG L
权利人:US NAVY
摘要:The invention comprises a networked polymer comprising the formula: n wherein nâ‰§1; wherein n is an average value obtained by averaging all repeating units of the networked polymer; wherein mâ‰§1; wherein Y is a divalent group containing one or more acetylenic groups, one or more crosslinks, or both; n wherein z is the average number of crosslinks per Y group; wherein Ar 1 and Ar 2 are independently selected aromatic groups; and wherein each R is independently selected from the group consisting of alkyl, aryl, alkylaryl, haloalkyl, haloaryl, and combinations thereof. The invention also includes prepolymers and precursors needed to make the networked polymer and processes for making all of the above. The invention also includes a ceramic composition made by pyrolysis of the networked polymer.

专利号:US-2003158362-A1
优先权日:2002-01-25
标题 :Synthesis of oligomeric poly(silarylene-siloxane-acetylene)'s and their conversion to high temperature plastics, elastomers, and coatings