CAS: 13411-48-8; 1-Trimethylsilylethanone

该化合物是一种有机硅化合物,其特点是附于乙酸盐的三甲基硅酸盐组,其特点是一种无色,挥发性液体,其香味温和,甜味.该化合物以其作为气体色谱学和质量光谱学的衍生剂的用途而著称,特别是用于分析酒精和碳酸,因为它会增强分析物的挥发性和稳定性.甲酸盐在诸如乙醚和二氯甲烷等有机溶剂中溶解,但由于其水分性盐分,在水溶性硅酸混合物中溶性较低.该化合物在正常条件下相对稳定,但应当谨慎处理,因为它可以与湿气发生反应,导致释放乙酸和硅醇化合物形成.此外,在与该物质合作时,必须考虑安全防范措施,因为如果吸入或吸入,它可能会对健康造成风险.

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chloro-trimethyl-silane ethyl vinyl ether α-(trimethylsilyl)vinyl alcohol carbon monoxide 3-acetylcyclohexanone dimethylglyoxal 3-Acetylcyclopentanone fluoren-9-yl-phenyl ketone

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    专利号:US-5286901-A
    优先权日:1990-03-09
    标题:Prescursors for and synthesis of mono- and difunctionalized acetylenes and difunctional 1,3-diynes
    发明人:STANG PETER J; CRITTELL CHARLES M; WILLIAMSON BOBBY L; ZHDANKIN VIKTOR
    权利人:UNIV UTAH RES FOUND
    摘要:Precursors and methods for the synthesis of mono- and difunctionalized acetylenes are described. The invention includes novel tricoordinate iodonium transfer reagents and novel alkynyldi(phenyliodonium) salts, both of which are precursors for the functionalized acetylenes. The iodonium transfer reagents take the general form of mixed iodonium sulfonates PhI + (X)OSO 2 R f , where X may be OAc, NHAc, NCO, or CN. These mixed iodonium sulfonates are produced by reaction of iodosobenzene with certain substituted trimethylsilanes. n To make the alkynyldi(phenyliodonium) salt PhI + C.tbd.CI + Ph•2 R f SO 3 - ,a mixed iodonium sulfonate is reacted with a bistin acetylene of the kind R' 3 SnC.tbd.CSnR' 3 . Alternatively, the reaction may be performed with disubstituted tin diacetylenes to produce PhI + C.tbd.C-C.tbd.CI + Ph•2 R f SO 3 - to produce a dialkynyldi(phenyliodonium) salt. Subsequent reaction of a nucleophile with the alkynyldi(phenyl-iodonium) salt or dialkynyldi(phenyliodonium) salt produces a difunctional acetylene or a difunctional 1,3-diyne, respectively.

    专利号:US-7582758-B2
    优先权日:2004-06-08
    标 题:Lewis acid mediated synthesis of cyclic esters
    发明人:MARTIN KEVIN V
    权利人:METABASIS THERAPEUTICS INC
    摘要:Methods for the synthesis of cyclic phosphonic acid diesters from 1,3-diols are described, whereby cyclic phosphonic acid diesters are produced by reacting a chiral 1,3-diol and an activated phosphonic acid in the presence of a Lewis acid.

    专利号:US-5110970-A
    优先权日:1991-03-29
    标题 :Process for the manufacture of certain new silicone polyether copolymers for polyurethane foam manufacture
    发明人:BLEVINS II CHARLES H; MATLOCK PAUL L; MURPHY GERALD J
    权利人:UNION CARBIDE CHEM PLASTIC
    摘要:This invention relates to silicone surfactants, and more particularly, to synthesis of siloxane-polyether surfactants having polyether backbones.

    专利号:US-2022355262-A1
    优先权日:2019-07-22
    标题 :System and method for manufacturing water-based hydrophobic aerogels and aerogel composites
    发明人:SACHITHANADAM MAHESH; KHORASGANI SOGHRATI ELMIRA; NATARAJAN GAYATHRI
    权利人:KROSSLINKER PTE LTD
    摘要:Embodiments of the present invention provide users with a system and method for manufacturing water-based hydrophobic aerogels and aerogel composites. The system and method can be carried out in a manner which is more rapid than typical ways and can be readily scalable. The method of manufacture is useful for producing water based hydrophobic aerogels and aerogel composites on a large scale with good homogeneity and consistency. Advantageously, the method of manufacture also has the benefit of a shorter processing time due to the vacuum homogenizing and mixing processes, the use of microwave assisted vacuum freeze drying for ease of synthesis of water-based hydrophobic aerogels.

    专利号:US-6160128-A
    优先权日:1997-12-22
    标题:Tritioacetylating reagents and processes for preparation thereof
    发明人:SALJOUGHIAN MANOUCHEHR; MORIMOTO HIROMI; WILLIAMS PHILIP G; THAN CHIT
    权利人:UNIV CALIFORNIA
    摘要:Novel acetylating and tritioacetylating reagents suitable for preparation of nonlabelled and radiolabelled organic compounds. N-acetoxynaphthalimide, N-tritioacetoxyphthalimide, N-tritioacetoxysuccinimide, N-tritioacetoxynaphthalimide and processes of their preparation. The invention also concerns synthesis of nonlabelled acetylated and tritioacetylated organic compounds from precursors containing a free --NH 2 , --SH or --OH group.

    专利号:US-7598408-B2
    优先权日:2003-02-25
    标 题:Intermediates for synthesis of vitamin D derivatives
    发明人:IMAHORI HIDEKAZU; KOYAMA HIROYA; YOSHIHARA DAISUKE; SAWASHITA YOSHINORI; KURITA SOTA; ICHIHARA YOSHIHIRO; TAKAGI YOSHIHIRO; HIROSE KATSUTOSHI
    权利人:KNC LAB CO LTD
    摘要:The present invention provides a novel intermediate for synthesizing vitamin D derivatives by using a less expensive material. That is, the present invention provides a compound which is synthesized by using carvone as a starting material and which is represented by the following formulae.

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    合成参考文献


    摘要:Petasis, N. A., Science of Synthesis, (2010) 47, 232.
    摘要:Zhdankin, V. V., Science of Synthesis Knowledge Updates, (2015) 1, 272.
    摘要:Witt, D., Science of Synthesis Knowledge Updates, (2019) 2, 293.
    摘要:Martínez, C.; Muñiz, K., Science of Synthesis: Catalytic Oxidation in Organic Synthesis, (2017) 1, 329.
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