CAS: 85785-20-2; Esprocarb

该化合物是一种主要用作除草剂的化学化合物,属于氨酸甲酯除草剂类别,其作用是抑制植物中的特定酶,导致其生长抑制.Esprocarb的特点是采取有选择的行动,针对某些杂草物种,同时尽量减少对作物的伤害.该化合物通常用于农业环境,以管理各种作物的意外植被.该化合物在环境中具有适度的持久性,需要谨慎管理,以防止潜在的生态影响.此外,Esprocarb的行为方式包括破坏植物中的光合作用和其他代谢过程,使其有效地控制杂草人口.在使用该物质时,如同许多农用化学品一样,安全措施对于减轻人类健康和非目标生物的风险至关重要.

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欧盟法规

ECHA物质C&L通报REACH预注册

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1,2-dimethyl-pentylamine benzyl chlorothioformate

合成工艺路线路线简述

    📜3-甲基己烷-2-胺,Benzyl Chlorothioformate置于三乙胺体系中,用 苯 作为反应溶剂,以91%的收率获得产物禾草畏
    参考文献:S-Benzyl Thiolcarbamates And Their Use In Controlling Weeds In Rice
    标题:S-Benzyl Thiolcarbamates And Their Use In Controlling Weeds In Rice
    摘要:揭示了一种新型s-苄硫代氨基甲酸酯,其化学式为##str1##其中r.Sup.1选自氢和甲氧基组,R.Sup.2选自甲基,乙基和烯丙基组,R.Sup.3选自直链c.Sub.3-C.Sub.6烷基,可选择性地取代一个或两个甲基基团,以及烯丙基.这些化合物在控制与稻作相关的杂草方面特别有效.

    海关参考信息

    专利信息


    专利号:WO-2024256370-A1
    优先权日:2023-06-13
    标 题 :Synthesis of glufosinate using an amidase-based process
    发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

    专利号:US-2025120400-A1
    优先权日:2021-12-10
    标题:Synthesis of glufosinate using a hydantoinase-based process
    发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

    专利号:US-11919928-B2
    优先权日:2016-03-16
    标题 :Method for producing dihydrotentoxin
    发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
    权利人:KUMIAI CHEMICAL INDUSTRY CO
    摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

    专利号:US-2021386068-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

    专利号:US-2021352899-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

    专利号:US-7375058-B2
    优先权日:2001-09-14
    标 题:Herbicidal mixtures based on 3-phenyluracils
    发明人:ZAGAR CYRILL; SIEVERNICH BERND; QUAKENBUSH LAURA; EVANS RICHARD R; LANDES MAX; NEWSOM LARRY J; ORTLIP CHARLES L; WITSCHEL MATTHIAS; LANDES ANDREAS
    权利人:BASF AG
    摘要:Herbidically active compositions, comprising: A) at least one phenyluracil compound of the formula (I); in which the variables R 1 -R 7 are as defined in the claims, and/or at least one of its agriculturally acceptable salts; and at least one further active compound, selected from B) herbicides of classes b1) to b15): b1) lipid biosynthesis inhibitors; b2) acetolactate synthase inhibitors (ALS inhibitors); b3) photosynthesis inhibitors; b4) protoporphyrinogen-IX oxidase inhibitors; b5) bleacher herbicides; b6) enolpyruvyl shikimate 3-phosphate synthase inhibitors (EPSP inhibitors); b7) glutamine synthetase inhibitors; b8) 7,8-dihydropteroate synthase inhibitors (DHP inhibitors); b9) mitose inhibitors; b10) inhibitors of the synthesis of very long chain fatty acids (VLCFA inhibitors); b11) cellulose biosynthesis inhibitors; b12) decoupler herbicides; b13) auxin herbicides; b14) auxin transport inhibitors; b15) other herbicides selected from the group consisting of benzoylprop, flamprop, flamprop-M, bromobutide, chlorflurenol, cinmethylin, methyldymron, etobenzanid, fosamine, metam, pyributicarb, oxaziclomefone, dazomet, triaziflam and methyl bromide; and safeners selected from: benoxacor, cloquintocet, cyometrinil, dichlormid, dicyclonon, dietholate, fenchlorazole, fenclorim, flurazole, fluxofenim, furilazole, isoxadifen, mefenpyr, mephenate, naplithalic anhydride, 2,2,5-trimethyl-3-(dichloroacetyl)-1,3-oxazolidine, 4-(dichloroacetyl)-1-oxa-4-azaspiro[4.5]decane and oxabetrinil, the agriculturally acceptable salts of the active compounds B and C and the agriculturally acceptable derivatives of the active compounds B and C, provided they have a carboxyl group

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献


    1: Ueda K, Nagai T. Relative sensitivity of duckweed Lemna minor and six algae to seven herbicides. J Pestic Sci. 2021 Aug 20;46(3):267-273. doi: 10.1584/jpestics.D21-018.
    2: Kuk YI, Kim KH, Kwon OD, Lee DJ, Burgos NR, Jung S, Guh JO. Cross-resistance pattern and alternative herbicides for Cyperus difformis resistant to sulfonylurea herbicides in Korea. Pest Manag Sci. 2004 Jan;60(1):85-94. doi: 10.1002/ps.786. 16(17):2684-2692. doi: 10.1039/d4ay00181h. 14(6):907-17. doi: 10.1007/s11248-005-0199-x. 50(7):3937-44. doi: 10.1021/acs.est.5b04577. Epub 2016 Mar 9. 117(3):411-9. doi: 10.1016/s0269-7491(01)00196-8. 42(1):1-8. doi: 10.1080/03601230601017551. 82(6):716-21. doi: 10.1007/s00128-009-9681-0. Epub 2009 Mar 10. 35(1):233-40. doi: 10.1002/etc.3162. Epub 2015 Nov 30. 263(1-3):115-25. doi: 10.1016/s0048-9697(00)00671-9. 53(2):139-46. doi: 10.2166/wst.2006.047. 54(17):6209-11. doi: 10.1021/jf061082z.

    合成参考文献


    参考文献:10.1002/ps.786
    摘要:Kuk YI, Kim KH, Kwon OD, Lee DJ, Burgos NR, Jung S, Guh JO. Cross‐resistance pattern and alternative herbicides for Cyperus difformis resistant to sulfonylurea herbicides in Korea. Pest Management Science. 2003 Nov 03;60(1):85–94. doi: 10.1002/ps.786.
    参考文献:10.1007/s11248-005-0199-x
    摘要:Kawahigashi H, Hirose S, Ozawa K, Ido Y, Kojima M, Ohkawa H, Ohkawa Y. Analysis of substrate specificity of pig CYP2B22 and CYP2C49 towards herbicides by transgenic rice plants. Transgenic Res. 2005 Dec;14(6):907–17. doi: 10.1007/s11248-005-0199-x.
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