CAS: 56846-39-0; (2R,3R,4S,5S,6R)-2-(((2R,3S,4R,5R,6S)-4,5-Dihydroxy-2-(Hydroxymethyl)-6-(4-Nitrophenoxy)Tetrahydro-2H-Pyran-3-yl)Oxy)-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-3,4,5-Triol

该化合物是合成化合物,通常用作生物化学实验的基质,特别是用于研究液溶胶甘油基糖和其他酶,这种化合物具有p-硝基苯组特征,该组具有染色素特性,通过水解时的色度变化,可以量化酶活动.D-混合物结构提供一种模拟天然基质的遗传联系,使其对酶动能研究有用. P-硝基苯-D-混合物通常在水和有机溶剂中溶解,便于其在各种实验室环境中使用.该化合物的稳定性和再活动使它成为分子生物学和生物化学中调查酶机制和筛选潜在抑制剂的重要工具.在处理该化合物时,应像对待任何化学品一样采取安全防范措施,以避免接触和确保适当的实验室做法.

英文名称(2R,3R,4S,5S,6R)-2-(((2R,3S,4R,5R,6S)-4,5-Dihydroxy-2-(Hydroxymethyl)-6-(4-Nitrophenoxy)Tetrahydro-2H-Pyran-3-yl)Oxy)-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-3,4,5-Triol
中文名称4-硝基苯基-Β-D-麦牙糖苷
IUPAC名称(2R,3R,4S,5S,6R)-2-(((2R,3S,4R,5R,6S)-4,5-dihydroxy-2-(hydroxymethyl)-6-(4-nitrophenoxy)tetrahydro-2H-pyran-3-yl)oxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol
其它别名4-Nitrophenyl 4-O-Alpha-D-Glucopyranosyl-Beta-D-Glucopyranoside; P-Nitrophenyl Beta-D-Maltoside; Pnp-Beta-D-Maltoside; P-Nitrophenyl-B-D-Maltoside; 4-Nitrophenylb-D-Maltopyranoside; P-Nitrophenyl 4-O-α-D-Glucopyranosyl-β-D-Glucopyranoside; P-Nitrophenyl β-D-Maltopyranoside; P-Nitrophenyl β-Maltoside
CAS编号56846-39-0
MFCD编号:MFCD00069844
EINECS号:851-154-8
分子式:C18H25NO13分子量:463.39
产品CID: 1542636
产品分类生物化工 → 糖类化合物 → 双糖

相似结构搜索
InChIKey: IAYJZWFYUSNIPN-YMJSIHPXSA-N
InChI=1S/C18H25NO13/c20-5-9-11(22)12(23)14(25)18(30-9)32-16-10(6-21)31-17(15(26)13(16)24)29-8-3-1-7(2-4-8)19(27)28/h1-4,9-18,20-26H,5-6H2/t9-,10-,11-,12+,13-,14-,15-,16-,
计算化学: 氢键受体数13.0氢键供体数7.0可旋转键数6.0

物理性质

沸点795.6 °C at 760 mmHg
闪点435 °C
密度1.7g/cm3
pKa:12.43±0.70(预测)
PSA:224.35
LogP:-2.8791
折射率1.67
蒸汽压1.07E-26 mmHg at 25 °C
溶解性DMSO (Slightly), Methanol (Slightly), Water (Slightly)
外观形态白色至类白色固体
储存条件−20°C

欧盟法规

C&L通报

上下游产品

L-serin 4-nitrophenyl-β-D-glucoside 37H49NO23C37H49NO23 D-maltoseO4-α-D-glucopyranosyl-β-D-glucopyranoside)(4-amino-phenyl)-(O4-α-D-glucopyranosyl-β-D-glucopyranoside) 4-nitro-phenol 4-nitrophenyl-α-D-glucopyranoside alpha-D-glucopyranose

合成工艺路线路线简述

📜在 Sodium Methylate体系中,用甲醇作为反应溶剂,化学反应 3.0H,以90%的收率获得产物4-硝基苯基-β-D-麦牙糖苷
参考文献:Synthetic Catalysts For Carbohydrate Processing
标题:Synthetic Catalysts For Carbohydrate Processing
摘要:该披露涉及分子印迹交联微胶束,可以选择性地水解碳水化合物.