CAS: 4747-07-3; N-Hexylmethylether

上下游产品

CAS号77-78-1 硫酸二甲酯 | CAS号111-27-3 正己醇 | CAS号4911-55-1 penta-1,3-diyne | CAS号106-70-7 己酸甲酯 | CAS号781-07-7 hexyl benzenesu... | CAS号124-41-4 甲醇钠 | CAS号512-56-1 磷酸三甲酯 | CAS号111-25-1 1-溴代正己烷 | CAS号41924-38-3 bis-hexyloxymet... | CAS号544-10-5 氯(代)正己烷 | CAS号101-41-7 苯乙酸甲酯 | CAS号67-56-1 甲醇 | CAS号50-00-0 甲醛 | CAS号66-25-1 正己醛 | CAS号111-27-3 正己醇 | CAS号29006-00-6 6-甲氧基-2-己酮 | CAS号142-92-7 乙酸己酯

📜己酸甲酯置于十二羰基三铁,1,1,3,3-四甲基二硅氧烷体系中,用 甲苯 作为反应溶剂,化学反应 2.0H,以73%的收率获得产物1-甲氧基-己烷
参考文献:Synthesis Of Ethers From Esters Via Fe-Catalyzed Hydrosilylation
标题:Synthesis Of Ethers From Esters Via Fe-Catalyzed Hydrosilylation
摘要:十二羰基三铁可以选择性地将酯还原为相应的醚.该方案的底物范围广泛.此外,胆甾醇佩拉罗酯在反应条件下也得到了极好的产率.
DOI:10.1039/c2Cc32142D

专利信息

专利号:US-8198465-B2
优先权日:2005-10-17
标 题 :3-alkyl-5- (4-alkyl-5-oxo-tetrahydrofutran-2-yl) pyrrolidin-2-one derivatives as intermediates in the synthesis of renin inhibitors
发明人：SEDELMEIER GOTTFRIED; GRIMLER DOMINIQUE; ACEMOGLU MURAT
权利人:SEDELMEIER GOTTFRIED; GRIMLER DOMINIQUE; ACEMOGLU MURAT; NOVARTIS AG
摘要:The invention related to a novel process, novel process steps and novel intermediates useful in the synthesis of pharmaceutically active compounds, especially renin inhibitors, such as Aliskiren. Inter alia, the invention relates to a process for the manufacture of a compound of the formula II, n nor a salt thereof, and a compound of formula VIn n nor a salt thereof, wherein R 3 and R 4 as well as Act are as defined in the specification, and processes of manufacturing these.n n Additionally transformation of compounds (VI) with metallo organic compounds (VII) give rise to the new compounds (VIII) which are direct precursors for the preparation of Aliskiren.

专利号:US-11708379-B2
优先权日:2020-03-12
标题 :Mechanochemical synthesis of metal-organic frameworks for molecular sieving and compositions and methods of use thereof
发明人：CHEN BANGLIN; LIN RUI-BIAO; SHI YANSHU
权利人:UNIV TEXAS
摘要:Methods of preparing and using a metal-organic framework (MOF) are provided herein, including methods of using an MOF comprising a repeat unit of the formula [ML]n, wherein M is a divalent metal ion and L is a ligand of the formula:The MOFs provided herein may be used in the separation of two or more molecules from each other. In some embodiments, the molecules are ethylene and ethane. In some embodiments, UTSA-280 may be synthesized from calcium oxide (CaO) or calcium hydroxide (Ca(OH)2) and squaric acid (SA) through mechanochemical synthesis.

专利号:US-2009088576-A1
优先权日:2006-01-30
标题:Process for the Stereoselective Preparation of Alcohols From Alpha, Beta-Insaturated Compounds
发明人：HEROLD PETER; STUTZ STEFAN; MAH ROBERT; STOJANOVIC ALEKSANDAR; LYOTHIER ISABELLE; BEHNKE DIRK; SPINDLER FELIX; BAPPERT ERHARD
权利人:HEROLD PETER; STUTZ STEFAN; MAH ROBERT; STOJANOVIC ALEKSANDAR; LYOTHIER ISABELLE; BEHNKE DIRK; SPINDLER FELIX; BAPPERT ERHARD
摘要:A process for the synthesis of an alcohol of formula (I), using as intermediate a compound of formula (V).

专利号:US-8455655-B2
优先权日:2010-05-07
标题:Preparation of dihydropyridines
发明人：VISHNU NEWADKAR RAVINDRANATH; PURUSHOTTAM JOSHI ANIL; KUMAR SINGH SANTOSH
权利人:VISHNU NEWADKAR RAVINDRANATH; PURUSHOTTAM JOSHI ANIL; KUMAR SINGH SANTOSH; LESVI LABORATORIOS SL
摘要:The invention relates to a method and compounds for the preparation of clevidipine butyrate, a very short acting hypertensive calcium antagonist, as well as the synthesis of these compounds useful for the preparation of clevidipine (also known as clevidipine butyrate). Moreover the invention also discloses polymorphic forms of clevidipine butyrate, useful for the preparation of pharmaceutical compositions, and processes to prepare them.

专利号:US-8268936-B2
优先权日:2005-01-04
标题:Synthesis of hybrid block copolymers and uses thereof
发明人：BREITENKAMP KURT; SILL KEVIN N
权利人:BREITENKAMP KURT; SILL KEVIN N; INTEZYNE TECHNOLOGIES INC
摘要:The present invention relates to the field of polymer chemistry and more particularly to multiblock copolymers and methods of preparing the same.

专利号:WO-9522519-A1
优先权日:1994-02-17
标题 :Synthesis of polyhydroxy fatty acid amides from triglycerides
发明人：SCHEIBEL JEFFREY JOHN; REILMAN RANDALL THOMAS; SHERMAN JOE FREDERICK
权利人:PROCTER & GAMBLE
摘要:Fats and oils such as hardened palm kernel oil are reacted directly with N-substituted polyhydroxy amines to provide high yields of N-substituted polyhydroxy fatty acid amide surfactants having improved odors and low fatty acid content. Hardened palm kernel oil is reacted with N-methylglucamine in the presence of an ethoxylated alcohol, but in the absence of methanol solvent, using sodium propylene glycolate catalyst to provide the mixed corresponding fatty acid amide of N-methylglucamine.