CAS: 3386-35-4; Octyl 4-Methylbenzenesulfonate

该化合物是一种有机化合物,其特性为:由甲苯硫酸和辛醇酸和辛醇酸衍生的酯性功能组,其特性为无色和浅黄色液体,具有典型的气味,以有机溶剂中的溶性闻名,在各种应用中,包括作为有机合成的试剂和聚合过程中的催化剂,均能发挥作用;该化合物具有中度至低毒性,在处理时应采取适当安全措施,因为它会刺激皮肤和眼睛;此外,将该物质储存在一个冷干燥的地方,远离不相容的材料,非常重要;其化学特性,如沸点和密度,可因纯度和特定配方而不同,但一般具有相对较低的挥发性.

结构式图片

相似化合物

111-87-5 24767-82-6 3386-32-1

上下游产品

CAS号111-87-5 正辛醇 | CAS号98-59-9 对甲苯磺酰氯(PTSC) | CAS号4124-41-8 对甲苯磺酸酐 | CAS号14246-16-3 (Trimethylsilyl... | CAS号455-16-3 对甲苯磺酰气氟 | CAS号70690-19-6 2-辛氧基四氢-2H-吡喃 | CAS号629-27-6 1-碘辛烷 | CAS号27126-76-7 羟基(甲苯磺酰氧代)碘苯 | CAS号7182-86-7 四丁基对甲苯磺酸铵 | CAS号1806-54-8 羧酸三辛酯 | CAS号1098102-94-3 4,8-二正辛基氧代苯并[1,... | CAS号3780-50-5 4-正辛氧基苯酚 | CAS号67399-94-4 1,2-(二辛氧荃)苯 | CAS号37682-29-4 2-硝基苯辛醚 | CAS号3698-95-1 正辛基甲基硫醚 | CAS号463-11-6 1-氟辛烷 | CAS号111-87-5 正辛醇 | CAS号111-66-0 1-辛烯 | CAS号4128-31-8 仲辛醇 | CAS号629-82-3 正-午基醚

合成工艺路线路线简述

    📜7-(Tert-Butyldimethylsilyloxy)Heptan-1-Ol置于草酰氯,Chlorophyll A,二氢吡啶,四丁基氟化铵,Sodium Hydride,二甲基亚砜,三乙胺体系中,用 四氢呋喃,乙醚,二氯甲烷,二甲基亚砜,N,N-二甲基甲酰胺,Mineral Oil 用作溶剂,化学反应 44.5H,反应生成对甲苯磺酸正辛酯
    参考文献:红光介导的 Barton-Mccombie 反应
    标题:红光介导的 Barton-Mccombie 反应
    摘要:描述了红光介导的 Barton-Mccombie 反应,其中叶绿素 A 用作光催化剂,三(三甲基甲硅烷基)硅烷或 Hantzsch 酯用作氢源.那里...
    Doi:10.1246/bcsj.20200087

    海关参考信息

    专利信息


    专利号:US-10253165-B2
    优先权日:2015-02-26
    标 题 :Control of organic impurities in polycarbonate synthesis
    发明人:BOJARSKI AARON DAVID; GARCIA AGUDO JORGE A
    权利人:SABIC GLOBAL TECHNOLOGIES BV
    摘要:Polymerization processes comprising melt polymerizing a carbonate and a dihydroxy compound in the presence of an amount of a beta organic catalyst so as to give rise to a polycarbonate product, wherein the amount of beta organic catalyst comprises at least one onium salt and also comprises triphenyl phosphonium oxide (TPPO), and wherein the TPPO represents less than about 0.3 weight % of the sum of the weights of the at least one onium salt and the TPPO in the amount of beta organic catalyst.

    专利号:WO-2018191612-A1
    优先权日:2017-04-14
    标 题 :Synthesis of a phosphorous containing monomer and the incorporation in polycarbonate by interfacial polymerization thereof

    专利号:US-9895454-B2
    优先权日:2014-07-03
    标题:Metal oxide catalyzed radiofluorination
    发明人:SERGEEV MAXIM; MORGIA FEDERICA; VAN DAM ROBERT MICHAEL; LAZARI MARK
    权利人:UNIV CALIFORNIA
    摘要:Inter alia, the first titania-catalyzed [ 18 F]-radiofluorination in highly aqueous medium is provided. In embodiments, the method utilizes titanium dioxide, 1:1 acetonitrile-thexyl alcohol solvent mixture and tetrabutylammonium bicarbonate as a base. Radiolabeling may be directly performed with aqueous [ 18 F]fluoride without the need for drying/azeotroping step, which reduces radiosynthesis time while keeping high fluoride conversion. The general applicability of the synthetic strategy to the synthesis of the wide range of PET probes from tosylated precursors is demonstrated.

    专利号:US-2020048410-A1
    优先权日:2017-04-14
    标 题:Synthesis of a phosphorous containing monomer and the incorporation in polycarbonate by interfacial polymerization thereof

    专利号:EP-3545018-B1
    优先权日:2017-04-14
    标 题:Synthesis of a phosphorous containing monomer and the incorporation in polycarbonate by interfacial polymerization thereof
    发明人:CALVERAS JORDI
    权利人:SABIC GLOBAL TECHNOLOGIES BV

    专利号:EP-3545018-A1
    优先权日:2017-04-14
    标题 :Synthesis of a phosphorous containing monomer and the incorporation in polycarbonate by interfacial polymerization thereof

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Kantchev, E. A. B.; Organ, M. G., Science of Synthesis, (2009) 48, 38.
    摘要:Wicha, J., Science of Synthesis, (2009) 48, 181.
    摘要:Kantchev, E. A. B.; Organ, M. G., Science of Synthesis, (2009) 48, 32.
    摘要:Lequeux, T. P., Science of Synthesis Knowledge Updates, (2017) 2, 263.
    摘要:Braun, M., Science of Synthesis Knowledge Updates, (2017) 1, 454.
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