5,8-二甲氧基-[1,2,4]三唑[1,5-C]嘧啶-2-胺,2-(2,2-二氟乙氧基)-6-(三氟甲基)苯磺酰氯,3,5-二甲基吡啶置于二甲基亚砜 硫酸,乙腈,水体系中,化学反应 8.92H,以18 G Of Product Was Obtained As A White Solid Assaying At 97.4 Wt % (91% Yield)的收率获得五氟磺草胺 参考文献:Process For The Preparation Of N-([1,2,4]Triazolopyrimidin-2-yl)Aryl Sulfonamides 标题:Process For The Preparation Of N-([1,2,4]Triazolopyrimidin-2-yl)Aryl Sulfonamides 摘要:使用n-芳基磺酰氯与n-([1,2,4]三唑并[2,3-D] 嘧啶-2-基)胺的偶联反应,催化剂为n-芳基亚磺酰亚胺,可以通过选择3-哌啶或3,5-戊二醛作为碱来改善反应,形成n-([1,2,4]三唑并[2,3-D]嘧啶-2-基)芳基磺酰胺.
专利号:WO-2024256370-A1 优先权日:2023-06-13 标 题 :Synthesis of glufosinate using an amidase-based process 发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN 权利人:BASF SE 摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.
专利号:US-2025120400-A1 优先权日:2021-12-10 标题:Synthesis of glufosinate using a hydantoinase-based process 发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN 权利人:BASF SE 摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.
专利号:WO-2021130756-A1 优先权日:2019-12-25 标题:Combinations of non-protein amino acids and acetolactate synthase enzyme inhibitors 发明人:KLIPCAN LIRON; VAN-OSS PINHASI RUTH 权利人:THE STATE OF ISRAEL MINISTRY OF AGRICULTURE & RURAL DEVELOPMENT AGRICULTURAL RES ORGANIZATION ARO VO 摘要:The present invention provides compositions and methods for disrupting protein synthesis in plant cells.
专利号:WO-2021143617-A1 优先权日:2020-01-16 标题 :Cyclohexadiene oxime ether compound, synthesis method therefor and application thereof 发明人:DENG ZHAOXI; Hu Hewei; GUO SHAOXIONG; CEN JIN; TAN BIN; DU BINGBING; YANG LINA; LI JUNPEI 权利人:ZHENGZHOU INSTITUTE OF CHIRAL DRUGS RES CO LTD 摘要:The present invention provides a cyclohexadiene oxime ether compound having the following structural formula: (I) or (II) or (III); group R 1 and group R 3 are each selected from -H, an aliphatic substituent containing 1-6 carbon atoms, a halogenated aliphatic substituent, a cyano-substituted aliphatic substituent, amino or amide, phenyl, and a halogenated aromatic substituent or a cyano-substituted aromatic substituent; group R 2 is selected from -H, an aliphatic substituent containing 1-6 carbon atoms, a halogenated aliphatic substituent, a cyano-substituted aliphatic substituent, amino or amide, phenyl, a halogenated aromatic substituent, and a cyano-substituted aromatic substituent, a nitro-substituted aromatic substituent or a heterocyclic aromatic substituent; and the heterocyclic aromatic substituent is selected from (iv), (v) or (vi), wherein X is selected from -H, halogen, -CN, -NO 2 , and -CF 3 , -C(CF 3 ) 3 , and n is the number of substituents and is selected from 1, 2, and 3. The present invention also provides a preparation method for the above-mentioned cyclohexadiene oxime ether compound and an application thereof.
专利号:US-11919928-B2 优先权日:2016-03-16 标题 :Method for producing dihydrotentoxin 发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI 权利人:KUMIAI CHEMICAL INDUSTRY CO 摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.
专利号:US-2021386068-A1 优先权日:2018-11-07 标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides 发明人:KISTER JEREMY; SATCHIVI NORBERT M 权利人:CORTEVA AGRISCIENCE LLC 摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.
摘要:Crop Protection Handbook Volume 96, Meister Media Worldwide, Willoughby, OH 2010, p. 504 摘要:California Environmental Protection Agency/Department of Pesticide Regulation; Summary of Toxicology Data on Penoxsulam p.8 (2005). Available from, as of February 7, 2011: 摘要:Lyman WJ et al; Handbook of Chemical Property Estimation Methods. Washington, DC: Amer Chem Soc pp. 7-4, 7-5, 8-12 (1990) 摘要:USEPA/Prevention, Pesticides, and Toxic Substances; Citizen's Guide to Pest Control and Pesticide Safety p.22 (March 2005) EPA 730-K-04-002 摘要:Dow AgroSciences LLC; Product Label for Grasp SC Herbicide (May 14, 2008). Available from, as of February 15, 2011: https://www.cdms.net/ldat/ld6SA010.pdf