CAS: 18820-29-6; Manganese(Ii) Sulfide

该化合物是一种无机化合物,其特点是形成一种固体晶状结构,通常以黑或深褐色粉状形式出现,由锰和硫组成,比例为1:1 摩尔. MnS因其半导体特性而著称,并经常用于各种用途,包括电子产品和陶瓷及玻璃的颜料.该化合物在水中表现出低溶性,但可溶于酸,释放硫化氢气.MnS的磁性也值得注意,其特性因温度和杂质的存在而异.在安全方面,锰硫化物如果吸入或摄入,则会构成健康风险,因此需要在工业环境中采取适当的处理和安全措施.

结构式图片

欧盟法规

REACH注册ECHA物质ECHA物质C&L通报REACH预注册

合成工艺路线路线简述

    📜硫化氢,七氧化二锰,二氧化锰 反应生成硫化锰
    参考文献:Kurek,Stefan S.;Kramarz,Wanda;Wlodarczyk,Andrzej;Zajecki,Janusz,Nafta,45,(1989) N-9,C. 116-118
    标题:Kurek,Stefan S.;Kramarz,Wanda;Wlodarczyk,Andrzej;Zajecki,Janusz,Nafta,45,(1989) N-9,C. 116-118

    专利信息


    专利号:US-2005036938-A1
    优先权日:2003-08-13
    标 题 :Method for synthesizing nanoparticles of metal sulfides
    发明人:HYEON TAEGWHAN
    摘要:A synthetic method of fabricating highly crystalline and uniform nanoparticles of metal sulfides, doped metal sulfides, and multi-metallic sulfides disclosed, using no-toxic and inexpensive reagents. A typical synthetic method comprises the steps of, synthesis of metal-surfactant complexes from the reaction of metal precursors and surfactant, addition of sulfur reagent to the solution containing said metal-surfactant complexes followed by heating to high temperature, aging at that temperature to produce metal sulfide nanoparticles and completing the formation of synthesis of nanoparticles metal sulfides and multi-metallic sulfides by adding a poor solvent followed by centrifuging.

    专利号:US-11352556-B2
    优先权日:2016-10-28
    标题:Process for the synthesis of air stable metal sulphide quantum dots
    发明人:PRASAD BHAGAVATULA LAKSHMI VARA; BERA ABHJIT
    权利人:COUNCIL SCIENT IND RES
    摘要:The present invention discloses a process for the preparation of metal sulphide quantum dots by using a very low cost sulphur precursor as a sulphur source. The metal sulphide quantum dots finds application in optical devices selected from photovoltaic cells, photodetectors and light-emission devices.

    专利号:US-6413669-B1
    优先权日:1999-06-03
    标题 :Melt impregnation of mixed metal oxide
    发明人:TAKEUCHI ESTHER S; LEISING RANDOLPH A
    权利人:GREATBATCH W LTD
    摘要:The present invention is directed to a process for preparing a cathode active material consisting of a single phase of mixed metal oxide, such as a single phase silver vanadium oxide. The synthesis technique involves first heating the starting materials to melt a decomposable starting constituent. This first heating temperature is held for a period of time sufficient to enable the decomposable starting constituent to melt and completely flow throughout and within the other starting materials. Then, the thusly produced melt impregnated reaction admixture is preferably ground to ensure complete homogeneity of the starting materials, followed by heating to the decomposition temperature of the decomposable starting constituent. To finish the synthesis, the decomposed admixture is heated to an elevated temperature above the decomposition temperature to provide the single phase mixed metal oxide.

    专利号:WO-2023056470-A1
    优先权日:2021-09-30
    标 题:MnO NANOMATERIAL BASED INHIBITORS OF INFLAMMATION AND CANCER METASTASIS
    发明人:LEONG KAM W; ZHONG YILING
    权利人:UNIV COLUMBIA; NEWSOUTH INNOVATIONS PTY LTD
    摘要:The anionic manganese oxide nanoparticle nucleic acid scavengers are biodegradable anionic scavengers with low cytotoxicity, which are able to scavenge (bind) cell-free nucleic acids (e.g., extracellular ssRNA, dsRNA, and unmethylated DNA), providing treatment for various medical conditions. The main component of the scavenger is manganese oxide, which may be synthesized by using a manganese compound (e.g., manganese acetate) and an acid (e.g., tannic acid) at high temperature (e.g., 100-150°C). Synthesis may be performed by mixing a manganese compound and an acid in water forming a mixture, which is stirred, heated, and allowed to cool. The anionic manganese oxide nanoparticles are extracted from the cooled mixture. The typical size of the resultant nanomaterials ranges from 30 to 100 nm; the zeta potential of the as-prepared nanomaterials is about -20 mV. The nanoparticles have various uses, including administration to a subject to treat inflammation or to treat cancer.

    专利号:US-2025255984-A1
    优先权日:2022-02-01
    标 题 :Mno nanomaterial based inhibitors of inflammation and cancer metastasis
    发明人:LEONG KAM W; ZHONG YILING
    权利人:UNIV COLUMBIA; NEWSOUTH INNOVATIONS PTY LTD
    摘要:The anionic manganese oxide nanoparticle nucleic acid scavengers are biodegradable anionic scavengers with low cytotoxicity, which are able to scavenge (bind) cell-free nucleic acids (e.g., extracellular ssRNA, dsRNA, and unmethylated DNA), providing treatment for various medical conditions. The main component of the scavenger is manganese oxide, which may be synthesized by using a manganese compound (e.g., manganese acetate) and an acid (e.g., tannic acid) at high temperature (e.g., 100-150° C.). Synthesis may be performed by mixing a manganese compound and an acid in water forming a mixture, which is stirred, heated, and allowed to cool. The anionic manganese oxide nanoparticles are extracted from the cooled mixture. The typical size of the resultant nanomaterials ranges from 30 to 100 nm; the zeta potential of the as-prepared nanomaterials is about −20 mV. The nanoparticles have various uses, including administration to a subject to treat inflammation or to treat cancer.

    专利号:US-2025121362-A1
    优先权日:2022-01-25
    标题 :Novel compositions for the sustainable catalysis of organic synthesis reactions
    发明人:GRISON CLAUDE; LOCK TOY KI YVETTE
    权利人:CENTRE NAT RECH SCIENT; UNIV MONTPELLIER
    摘要:A composition comprising K2CO3, KCl, and optionally K2SO4 and/or KHCO3, having a weight content of potassium between 9.0 and 60.0% relative to the total weight of the composition, preferably between 10.0 and 50.0%, more preferably between 10.0 and 40.0%, advantageously between 20.0 and 40.0%.

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    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: H M Chilton, Et Al. Use Of A Paramagnetic Substance, Colloidal Manganese Sulfide, As An Nmr Contrast Material In Rats. J Nucl Med. 1984 May;25(5):604-7.
    [参考文献]: Ji-Hoon Lee, Et Al. Manganese Sulfide Formation Via Concomitant Microbial Manganese Oxide And Thiosulfate Reduction. Environ Microbiol. 2011 Dec;13(12):3275-88.
    [参考文献]: Keita Ikeue, Et Al. Hydrothermal Synthesis Of A Doped Mn-Cd-S Solid Solution As A Visible-Light-Driven Photocatalyst For H2 Evolution. Chemsuschem. 2011 Feb 18;4(2):269-73.
    [参考文献]: Lei Zhang, Et Al. Unusual Formation Of Single-Crystal Manganese Sulfide Microboxes Co-Mediated By The Cubic Crystal Structure And Shape. Angew Chem Int Ed Engl. 2012 Jul 16;51(29):7267-70.
    [参考文献]: Swadeshmukul Santra, Et Al. Rapid And Effective Labeling Of Brain Tissue Using Tat-Conjugated Cds:Mn/zns Quantum Dots. Chem Commun (Camb). 2005 Jul 7:(25):3144-6.

    合成参考文献


    摘要:L229: Wikipedia. Manganese. Last Updated 26 May 2009.
    参考文献:10.1007/s002030050749
    摘要:Bottcher, Sievert, Kuever. Fractionation of sulfur isotopes during dissimilatory reduction of sulfate by a thermophilic gram-negative bacterium at 60 degrees C . Arch Microbiol. 1999 Aug;172(2):125–8. doi: 10.1007/s002030050749.
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