5-Propoxycarbonylbicyclo[2.2.1 ]Hept-2-Ene 反应生成5-降冰片烯-2-羧酸 参考文献:Asymmetric Diels-Alder Reaction Between Acrylates And Cyclopentadiene In The Presence Of Chiral Catalysts 标题:Asymmetric Diels-Alder Reaction Between Acrylates And Cyclopentadiene In The Presence Of Chiral Catalysts 摘要:Asymmetric Diels-Alder Reaction Between Cyclopentadiene And Alkyl And Cycloalkyl Acrylates In The Presence Of New Chiral Catalysts,Bbr3 Center Dot Mentoet,Alcl(2)Oment,Bbr(2)Oment,And Bbr(Oment)(2),Was Studied. Optically Active Bicyclo[2.2.1]Hept-2-Ene-5-Carboxylates Were Synthesized. The Influence Of The Reaction Conditions On The Total And Optical Yields And On The Stereoselectivity Of The Adducts Synthesized Was Examined. Doi:10.1134/s1070427206100120
专利号:US-2004242897-A1 优先权日:2002-07-31 标题 :Universal support media for synthesis of oligomeric compounds 发明人:GUZAEV ANDREI P; MANOHARAN MUTHIAH 摘要:Compounds for the synthesis of oligomeric compounds, particularly oligonucleotides and oligonucleotide mimetics, are provided. In addition, methods for functionalizing a support medium with a first monomeric subunit and methods for the synthesis of oligomeric compounds utilizing the novel compounds bound to support media are provided.
专利号:WO-2004011474-A1 优先权日:2002-07-31 标题:Universal support media for synthesis of oligomeric compounds 发明人:GUZAEV ANDREI P; MANOHARAN MUTHIAH; RAVIKUMAR VASULINGA T; KUMAR RAJU K 权利人:ISIS PHARMACEUTICALS INC; GUZAEV ANDREI P; MANOHARAN MUTHIAH; RAVIKUMAR VASULINGA T; KUMAR RAJU K 摘要:Compounds for the synthesis of oligomeric compounds, particularly oligonucleotide and oligonucleotide mimetics, are provided. In addition, methods for functionalizing a support medium with a first monomeric subunit and methods for the synthesis of oligomeric compounds utilizing the novel compounds bound to support media are provided.
专利号:US-11794179-B2 优先权日:2016-08-24 标 题 :Synthesis and characterization of metathesis catalysts 发明人:JOHNS ADAM M 权利人:UMICORE AG & CO KG 摘要:This invention relates generally to olefin metathesis catalysts, to the preparation of such compounds, compositions comprising such compounds, methods of using such compounds, and the use of such compounds in the metathesis of olefins and in the synthesis of related olefin metathesis catalysts. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and in industrial applications such as oil and gas, fine chemicals and pharmaceuticals.
专利号:US-11779912-B2 优先权日:2016-10-19 标题 :Synthesis and characterization of Ru alkylidene complexes 发明人:JOHNS ADAM M; HERRON JESSICA R; PEDERSON RICHARD L; FIAMENGO BRYAN A; BEERMAN JENNIFER A; LIN TZU-PIN; CHU CRYSTAL K; GRUBBS ROBERT H 权利人:UMICORE AG & CO KG; CALIFORNIA INST OF TECHN 摘要:This invention relates generally to olefin metathesis catalyst compounds, to the preparation of such compounds, compositions comprising such compounds, methods of using such compounds, articles of manufacture comprising such compounds, and the use of such compounds in the metathesis of olefins and olefin compounds. The invention has utility in the fields of catalysts, organic synthesis, polymer chemistry, and industrial and fine chemicals industry.
专利号:US-2024052097-A1 优先权日:2021-02-08 标题 :Synthesis of peg-based thiol-norbornene hydrogels with tunable hydroylitic degradation properties 发明人:LIN CHIEN-CHI; LIN FANG-YI 权利人:UNIV INDIANA TRUSTEES 摘要:Methods for synthesizing a hydrogel having tunable hydrolylic degradation kinetics according to certain embodiments include synthesizing a norborene-functionalized polyethylene glycol macromer having an ester linkage between a polyethylene glycol domain of the macromer and a norbornene domain of the macromer and having a carboxyl group on the norbornene; and reacting a quantity of such macromers with a quantity of dithiol molecules by an ultraviolet-initiated photo-gelation reaction to yield a hydrogel. Such macromers and such hydrogels form additional aspects of the disclosure, as do a wide variety of methods for tuning and for using such hydrogels.
专利号:US-8268936-B2 优先权日:2005-01-04 标题:Synthesis of hybrid block copolymers and uses thereof 发明人:BREITENKAMP KURT; SILL KEVIN N 权利人:BREITENKAMP KURT; SILL KEVIN N; INTEZYNE TECHNOLOGIES INC 摘要:The present invention relates to the field of polymer chemistry and more particularly to multiblock copolymers and methods of preparing the same.
[参考文献]: Benjamin D Fairbanks, Et Al. A Versatile Synthetic Extracellular Matrix Mimic Via Thiol-Norbornene Photopolymerization. Adv Mater. 2009 Dec 28;21(48):5005-5010.
合成参考文献
摘要:Xu, Z.; Bratlie, K. M., Science of Synthesis, (2021) , 559. 摘要:U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals., NX#04752