对二甲苯置于溴,碘体系中,用 二氯甲烷 用作溶剂,化学反应生成2,5-二溴-1,4-二甲基苯 参考文献:用于oled的高效纯有机室温磷光聚合物ppv衍生物 标题:用于oled的高效纯有机室温磷光聚合物ppv衍生物 摘要:为了提高装置效率并降低成本,有必要开发具有室温磷光(rtp)的纯有机分子.设计并合成了一种高效的纯有机rtp聚合物聚对亚苯基亚乙烯基(ppv)衍生物(br-Ppv-Cho),它在496 Nm处具有蓝色发射,发射寿命为14.1μs,并且具有光致发光性.量子产率为12.2%,Homo和lumo分别为-5.35 Ev和-2.75 Ev,显示出在oled发射层中的巨大潜力.用ppv衍生物作为发光材料层制造的器件的最大亮度为194 Cd / M 2当br-Ppv-Cho的含量为0.5重量%时,显示出最佳的rtp性能.Br-Ppv-Cho的非常好性能来自于溴和芳香醛的取代基,Ppv衍生物的分子结构设计策略为有机rtp材料的设计和合成提供了有用的指导. Doi:10.1016/j.Orgel.2018.10.012
专利信息
专利号:US-2018171086-A1 优先权日:2016-12-16 标题 :Large area monolayer of perfluoro polymers 发明人:SUN HAORAN 权利人:SOUTH DAKOTA BOARD OF REGENTS 摘要:Synthesis and growth of large area free-standing ultra-thin two-dimensional (2D) polymeric films including 2D covalent organic frameworks (COF) are achieved by utilizing fluorocarbon-soluble fluorinated aldehyde derivatives and hydrocarbon-soluble amine derivatives at a liquid-liquid interface of respective fluorocarbon and hydrocarbon solvents.
专利号:US-5852180-A 优先权日:1997-11-17 标题:Chemical synthesis of 6-O-alkyl erythromycin A 发明人:PATEL HEMANTKUMAR H 权利人:ABBOTT LAB 摘要:A process of preparing 6-O-alkyl erythromycin A is provided. The process includes the steps of protecting the oxime hydroxyl of 9-oxime erythromycin A with a benzoyl protecting group, protecting the 2'-hydroxyl group and optionally the 4'-hydroxyl group with an O-protecting group, alkylating the 6-hydroxyl, removing the benzoyl and O-protecting groups and deoximating the 9-oxime.
专利号:US-11359049-B2 优先权日:2017-09-21 标题:Gold catalyzed polymerization reactions of unsaturated substrates 发明人:AZOULAY JASON D; TROPP JOSHUA; KING ERIC 权利人:AZOULAY JASON D; TROPP JOSHUA; KING ERIC; THE UNIV OF SOUTHERN MISSISSIPPI 摘要:The present invention provides novel methods and processes for polymerizing unsaturated substrates, such as alkyne bearing monomers, with arenes. The polymerizations are catalyzed by gold (Au) catalysts/complexes and/or other cocatalysts. The invention further provides novel structurally complex polymers prepared in high yield via an intermolecular polyhydroarylation mechanism. Such resulting products comprise oligomeric and polymeric materials with novel molecular architectures and microstructures, which subsequently impart unique properties. The invention includes both the synthesis methods and processes and the resulting compounds and compositions of matter.
专利号:US-2010056750-A1 优先权日:2006-12-21 标题:Process for the synthesis of halogenated aromatic diacids 发明人:RITTER JOACHIM C 权利人:RITTER JOACHIM C 摘要:The production of high-purity halogenated aromatic diacids from halogenated dimethylbenzene by oxidation with an oxygen-containing gas is conducted using a four-component catalyst system and a two-stage temperature process.
专利号:US-7585999-B2 优先权日:2006-11-28 标题:Process for the synthesis of 2, 5-dihydroxyterephthalic acid 发明人:RITTER JOACHIM C 权利人:DU PONT 摘要:2,5-dihydroxyterephthalic acid is produced in high yields and high purity from 2,5-dihaloterephthalic acid by contact with a copper source and a ligand that coordinates to copper under basic conditions.
专利号:US-7339076-B1 优先权日:2006-11-28 标题 :Process for the synthesis of 2,5-dihydroxyterephthalic acid
[参考文献]: Nikolai Kuhnert, Et Al. The Synthesis Of Trianglimines: On The Scope And Limitations Of The [3 + 3] Cyclocondensation Reaction Between (1R,2R)-Diaminocyclohexane And Aromatic Dicarboxaldehydes. Org Biomol Chem. 2003 Apr 7;1(7):1157-70.
合成参考文献
摘要:Shi, L., Science of Synthesis: Knowledge Updates, (2024) 1, 33. 参考文献:10.2116/analsci.21p279 摘要:Han X, Yu W, Zhang L, Li H, Kong F, Wang W. Carboxyl-functionalized porous aromatic framework for rapid, selective and efficient removal of cationic pollutants from water. Anal Sci. 2022 Feb;38(2):383–92. doi: 10.2116/analsci.21p279.