CAS: 934545-80-9; 3-Bromo-9-(Naphthalen-2-yl)-9H-Carbazole

该化合物是一种高纯度有机化合物,主要用于合成先进材料,特别是用于光电子应用,其结构将碳化物核心与氯化萘替代体和溴功能组相结合,具有出色的充电运输特性和金枪鱼可捕量电子特性,该化合物因其在开发有机发光二极管,有机光伏(OPVs)和其他半导体装置方面的作用而备受珍视.溴混合物会进一步提高其再活动性,促进量制分子设计的交叉反应.由于高热稳定性和高效发光性,它成为需要精确分子工程的材料科学研究和工业应用的关键中间体.

英文名称3-Bromo-9-(Naphthalen-2-yl)-9H-Carbazole
中文名称9-(2-萘基)-3-溴咔唑
IUPAC名称3-bromo-9-(naphthalen-2-yl)-9H-carbazole
CAS编号934545-80-9
MFCD编号:MFCD26127422
EINECS号:810-970-4
分子式:C22H14BrN
分子量:372.26
产品CID: 1974016
产品分类有机原料 → 杂环化合物

相似结构搜索
InChIKey: MBGUQKKYEOAENA-UHFFFAOYSA-N
InChI=1S/C22H14BrN/c23-17-10-12-22-20(14-17)19-7-3-4-8-21(19)24(22)18-11-9-15-5-1-2-6-16(15)13-18/h1-14H…
计算化学: 氢键受体数0.0氢键供体数0.0可旋转键数1.0

MSDS等安全信息

GHS象形图
GHS符号GHS07;
注释: Exclamation mark
危险类别皮肤腐蚀/刺激类别2
严重眼刺激类别2
警示词Warning(警告)
危险描述H315 |造成皮肤刺激.
H319 |造成严重眼刺激.
防范说明P305+P351+P338

欧盟法规

ECHA物质C&L通报

上下游产品

CAS号34292-03-0 N-(2-naphthyl)c... | CAS号580-13-2 2-溴萘 | CAS号86-74-8 咔唑

合成工艺路线路线简述

34292-03-0 = 934545-80-9
反应条件:1.1 Reagents: N-Bromosuccinimide Solvents: Dimethylformamide; 4 H,Rt
标题:Novel Organic Electroluminescent Compounds Having High Luminous Efficiency For Improved Driving Lifespan And Greater Efficiency In Electroluminescent Devices,And Organic Electroluminescent Devices Comprising The Organic Electroluminescent Compounds
参考文献:World Intellectual Property Organization]

1592-95-6 + 612-55-5 = 934545-80-9
反应条件:1.1 Reagents: Potassium Carbonate Catalysts: Copper,18-Crown-6 Solvents: Dimethylformamide; 24 H,140 °C; 140 °C -> Rt1.2 Reagents: Hydrochloric Acid Solvents: Water; 30 Min,Rt
标题:Preparation Of Carbazole Compounds For Electronic Device
参考文献:World Intellectual Property Organization]

1592-95-6 + 580-13-2 = 934545-80-9
反应条件:1.1 Reagents: Sodium Tert-Butoxide Catalysts: Tris(Dibenzylideneacetone)Dipalladium,2-Dicyclohexylphosphino-2′,6′-Dimethoxybiphenyl Solvents: Toluene; Rt -> 108 °C; 3 H,108 °C
标题:Adamantyl-Containing Carbazole-Type Organic Compounds,Organic Electroluminescent Device And Electronic Device Comprising The Same
参考文献:China]

1592-95-6 + 612-55-5 = 934545-80-9
反应条件:1.1 Reagents: Potassium Carbonate,Sodium Sulfate Catalysts: Copper Solvents: Nitrobenzene; 200 °C
标题:Amine Based Hole Transport Layer And Carbazole-Based Light Emitting Auxiliary Layer For Organic Electroluminescent Device
参考文献:Korea]

1592-95-6 + 612-55-5 = 934545-80-9
反应条件:1.1 Reagents: Sodium Tert-Butoxide Catalysts: Tri-Tert-Butylphosphine,Tris(Dibenzylideneacetone)Dipalladium Solvents: O-Xylene; 16 H,135 - 140 °C
标题:Preparation Of (Dibenzofuranyl)Indolo[2,3-B]Carbazole Derivatives As Organic Light Emitting Layer And Its Applications In Oleds
参考文献:China]

1592-95-6 + 580-13-2 = 934545-80-9
反应条件:1.1 Reagents: Potassium Carbonate Catalysts: 1,10-Phenanthroline,Cuprous Iodide Solvents: Dimethylformamide; 16 H,150 °C
标题:Organic Electroluminescence Device And Amine Compound For Organic Electroluminescence Device
参考文献:United States]

1592-95-6 + 612-55-5 = 934545-80-9
反应条件:1.1 Reagents: Potassium Acetate Catalysts: 1,10-Phenanthroline,Cuprous Iodide Solvents: Dimethylformamide; 18 H,Rt -> Reflux
标题:Two Organic Host Materials For Organic Optoelectronic Element And Display Device
参考文献:World Intellectual Property Organization]

1592-95-6 + 612-55-5 = 934545-80-9
反应条件:1.1 Reagents: Potassium Carbonate Catalysts: 1,10-Phenanthroline,Cuprous Iodide Solvents: Xylene; 6 H,Reflux
标题:Preparation Of Phosphindolo[2,3-B]Carbazole 7-Oxide Derivatives For Organic Electroluminescent Devices
参考文献:Korea]

1592-95-6 + 612-55-5 = 934545-80-9
反应条件:1.1 Reagents: Sodium Tert-Butoxide Catalysts: Copper,18-Crown-6 Solvents: Toluene; 24 H,100 °C
标题:Azacarbazole Compounds As Organic Electronic Device Materials
参考文献:World Intellectual Property Organization]

1592-95-6 + 612-55-5 = 934545-80-9
反应条件:1.1 Reagents: Potassium Carbonate Catalysts: 1,10-Phenanthroline,Cuprous Iodide,18-Crown-6 Solvents: Dimethylformamide; Overnight,Rt -> Reflux
标题:Preparation Of Heterocyclic Compounds For Organic Electroluminescent Devices
参考文献:China]

1592-95-6 + 612-55-5 = 934545-80-9
反应条件:1.1 Catalysts: Tributylphosphine,Tris(Dibenzylideneacetone)Dipalladium Solvents: Toluene,Water; 12 H,Rt
标题:Organic Light-Emitting Devices And Displays With Emitting Layers Employing Multiple Hosts
参考文献:United States]

34292-03-0 = 934545-80-9
反应条件:1.1 Reagents: N-Bromosuccinimide Solvents: Tetrahydrofuran; 20 H,Rt
标题:Hole Transport Materials And Organic Electroluminescent Devices Using Them
参考文献:Korea]

34292-03-0 = 934545-80-9
反应条件:1.1 Reagents: N-Bromosuccinimide Catalysts: Benzoyl Peroxide Solvents: Dichloromethane; 12 H,Rt
标题:New Bipolar Green Host Materials Containing Benzimidazole-Carbazole Moiety In Phosphorescent Oleds
作者:Park,Jung Hwan; Kim,Eun Kyung; El-Deeb,Ibrahim M.; Jung,Su Jin; Choi,Dae Hyuk; Et Al
参考文献:Bulletin Of The Korean Chemical Society 日期:2011 卷标:32(3) 页码:841-846]

580-13-2 = 934545-80-9
反应条件:1.1 Reagents: Potassium Carbonate,Cuprous Iodide Catalysts: 18-Crown-6 Solvents: 1,3-Dimethyl-3,4,5,6-Tetrahydro-2(1H)-Pyrimidinone; 5 H,Reflux; Reflux -> Rt1.2 Reagents: Water; Rt; 30 Min,Rt1.3 Reagents: N-Bromosuccinimide Solvents: Dimethylformamide; 40 Min,0 °C; Overnight,Rt1.4 Reagents: Water
标题:Preparation Of 1,2-Benzo[a]Anthracene Derivatives As Organic Electroluminescent Materials
参考文献:China]

1592-95-6 + 612-55-5 = 934545-80-9
反应条件:1.1 Reagents: Potassium Carbonate Catalysts: Copper Solvents: Toluene; Rt -> 150 °C; 24 H,150 °C
标题:Preparation Of Anthracene-Based Compounds Useful As Electroluminescent Material In Oled
参考文献:China]

1592-95-6 + 612-55-5 = 934545-80-9
反应条件:1.1 Reagents: Potassium Carbonate,Sodium Sulfate Catalysts: Copper Solvents: Nitrobenzene; 200 °C
标题:Heteroaryl Compounds As Organic Electronic Device Materials
参考文献:World Intellectual Property Organization]

1592-95-6 + 612-55-5 = 934545-80-9
反应条件:1.1 Reagents: Potassium Carbonate,Sodium Sulfate Catalysts: Copper Solvents: Nitrobenzene; 200 °C
标题:Carbazole Compounds For Organic Electronic Device
参考文献:Korea]

1592-95-6 + 612-55-5 = 934545-80-9
反应条件:1.1 Reagents: Sodium Tert-Butoxide Catalysts: Triphenylphosphine,Tris(Dibenzylideneacetone)Dipalladium Solvents: Toluene; 100 °C
标题:Preparation Of Carbazole Compounds As Organic Electronic Device Materials
参考文献:World Intellectual Property Organization

咔唑置于n-溴代丁二酰亚胺(Nbs),18-冠醚-6,铜,Potassium Carbonate,过氧化苯甲酰体系中,用二氯甲烷,N,N-二甲基甲酰胺作为反应溶剂,化学反应 12.0H,反应生成 9-(2-萘基)-3-溴咔唑
参考文献:New Bipolar Green Host Materials Containing Benzimidazole-Carbazole Moiety In Phosphorescent Oleds
标题:New Bipolar Green Host Materials Containing Benzimidazole-Carbazole Moiety In Phosphorescent Oleds
摘要:通过将传输电子的苯并咪唑分子连接到传输空穴的咔唑单元上,设计并合成了新型绿色宿主材料--9-苯基-3-(4-(1-苯基-1H-苯并[d]咪唑-2-基)苯基)-9H-咔唑(3A)和 9-(萘基-2-基)-3-(4-(1-苯基-1H-苯并[d]咪唑-2-基)苯基)-9H-咔唑(3B).与 Cbp(4,4'-二(n-咔唑基)联苯)相比,这些化合物具有相似的 Homo,Lumo 水平和带隙特性.与基于 Cbp 的绿色磷光 Oled 相比,使用这种 3A 主化合物制造的绿色磷光 Oled 显示出更好的器件性能.在给定的 1000 Cd/$m^2$ 恒定亮度下,电流和功率效率至少提高了 60%.
DOI:10.5012/bkcs.2011.32.3.841