📜Vanadium (Iii) Chloride * 6 Water置于氯化亚砜体系中,用 Neat (No Solvent) 作为反应溶剂,化学反应生成 氯化钒 参考文献:Seifert,H. J.,Zeitschrift Fur Anorganische Und Allgemeine Chemie 标题:Seifert,H. J.,Zeitschrift Fur Anorganische Und Allgemeine Chemie
专利信息
专利号:US-12139504-B2 优先权日:2022-08-09 标 题:Vanadium alkylidene complex, synthesis and use thereof 发明人:BUKHRYAKOV KONSTANTIN; BELOV DMITRY 权利人:BUKHRYAKOV KONSTANTIN; BELOV DMITRY; THE FLORIDA INTERNATIONAL UNIV BOARD OF TRUSTEES 摘要:The subject invention provides catalytical compounds/complexes, compositions comprising such compound/complex, synthesis of the compounds/complexes, and methods of using such compounds/complexes as catalysts in, for example, RCM reactions. Specifically, the subject invention provides the synthesis of the first catalytically active V oxo alkylidene, VO(CHSiMe 3 )(PEt 3 ) 2 Cl, which exhibits superior performance compared to other analogs.
专利号:US-2024424490-A1 优先权日:2021-01-25 标 题 :Method of synthesis of carbon-supported platinum group metal or metal alloy nanoparticles 发明人:WNUK PAWEL; LEWERA ADAM; JURCZAKOWSKI RAFAL; POWALA FILIP; KOLODZIEJCZYK JAN 权利人:UNIV WARSZAWSKI 摘要:The presented invention relates to a method of synthesis of carbon-supported platinum group metal or metal alloy nanoparticles, which comprises the following steps:n adsorbing on carbon support complexes of a platinum group metal with a urea complexing agent selected from a group comprising urea, urea derivative, a mixture of urea with at least one urea derivative, and a mixture of at least two urea derivatives; and reducing the complexes adsorbed on the carbon support to metal nanoparticles, forming a product of carbon-supported metal nanoparticles. nn The invention also provides the use of the carbon-supported platinum group metal or metal alloy nanoparticles obtained by the method of the invention as catalyst. n The present invention further relates to a method of adsorption of precursors of platinum group metals on the surface of a carbon support and use of complexes of platinum group metals with urea complexing agent for adsorption of platinum group metal precursors on carbon support.
专利号:US-11713329-B2 优先权日:2018-12-10 标 题 :Intermediates useful in the preparation of halichondrin compounds and methods for preparing the same 发明人:XU WEIPING 权利人:BEIJING TIENYI LUFU PHARMATECH CO LTD 摘要:The invention relates to intermediates useful in the preparation of halichondrin compounds, methods for preparing the same and use thereof, such as halichondrins, eribulin, or their analogs. The intermediates, the methods and use thereof are used for the synthesis of the C20-C26 fragment of halichondrin compounds. The raw materials in the synthetic route of the invention are cheap and easily obtained, the sources and the qualities of the raw materials are reliable. The choice of the methods useful in the synthesis of chiral central structures are based on the structural characteristics of the reactants, thus effectively improving the synthesis efficiency, reducing the difficulties and risks of product quality control, and avoiding the use of highly toxic and expensive organotin catalysts to significantly decrease costs and improve environmental friendliness.
专利号:US-6033624-A 优先权日:1995-02-15 标题 :Methods for the manufacturing of nanostructured metals, metal carbides, and metal alloys 发明人:GONSALVES KENNETH E; RANGARAJAN SRI PRAKASH 权利人:UNIV CONNETICUT 摘要:Methods for the manufacture of nanostructured metals, metal carbides, and metal alloys are presented, such metals including nanostructured aluminum, chromium, iron, molybdenum, vanadium, and steel. Preferably, the nanostructured steel is of the M50 type, and comprises iron, molybdenum, chromium, vanadium and carbon. Synthesis of M50 steel further comprising nanostructured aluminum, aluminum oxide, or aluminum nitride is also described. In accordance with an important feature of this invention, the grain size of the metals and metal alloys is in the nanometer range. In accordance with the method of the present invention, the nanostructured metals, metal carbides, and metal alloys are prepared via chemical synthesis from aluminum, iron, molybdenum, chromium and vanadium starting materials. Decomposition of metal precursors or co-precipitation or precipitation of metal precursors is followed by consolidation of the resulting nanostructured powders. Alternatively, nanostructured M50 steel may be obtained by mixing of nanocrystalline chromium, iron, molybdenum, and vanadium powders, followed by ball-milling, and consolidation. The nanostructured metals, metal carbides, and metal alloys of this invention find particular utility in the manufacture of cutting tools and bearings, and in ferrofluids, magnetic memory systems, and catalysis.
专利号:US-2024109787-A1 优先权日:2021-02-12 标题 :A layered double hydroxide, a process for the synthesis and uses thereof 发明人:ABELLÃ?N SÃ?EZ GONZALO; OESTREICHER VICTOR; CORONADO MIRALLES EUGENIO; ROMERO PASCUAL JORGE 权利人:UNIV VALENCIA 摘要:The present invention relates to a layered double hydroxide comprising at least one divalent cation A II or alternatively Li I , at least one trivalent cation B III selected from the group consisting of V III , Co III , Cr III , Mn III Fe III , Ga III and lanthanides. The present invention also relates to a process for the synthesis of said layered double hydroxide and uses thereof.
专利号:US-2024199566-A1 优先权日:2022-11-16 标题:Catalytic synthesis of delta-valerolactone (dvl) from furfural-derived 2-hydroxytetrahydropyran (hthp) 发明人:HUBER GEORGE; DASTIDAR RAKA; JOHNSTONE SAM; MCCLELLAND DANIEL 权利人:WISCONSIN ALUMNI RES FOUND 摘要:A method to make delta-valerolactone (“DVLâ€?) by dehydrogenating 2-hydroxytetrahydropyran (“HTHPâ€?). The HTHP is contacted with a supported-metal catalyst for a time, at a temperature, and at a pressure wherein at least a portion of the HTHP is converted to DVL via dehydrogenation of the HTHP. The HTHP may be derived from biomass. Thus, the method yields DVL without requiring a petroleum-based feedstock.