CAS: 2519-10-0; Cyclopenta-1,3-Diene-1,2,3,4,5-Pentaylpentabenzene
该化合物是一种高度替代的环戊二烯衍生物,其特点是与环戊二烯环形环相连的五个苯组.这种结构配置具有严重的不育障碍和电子迁移性,使其成为有机合成和材料科学的宝贵中间体.其扩展的"融合"系统增强了其在开发包括有机半导体和发光化合物在内的光电子材料方面的效用.该化合物的稳定性和僵硬框架也使其适合催化应用和作为协调化学的离心前体.其定义明确的芳香特性有助于其在机械学研究和复杂多环系统建筑中的使用.
- 英文名称Cyclopenta-1,3-Diene-1,2,3,4,5-Pentaylpentabenzene
- 中文名称五苯基环戊二烯
- IUPAC名称cyclopenta-1,3-diene-1,2,3,4,5-pentaylpentabenzene
- 其它别名1,2,3,4,5-Pentaphenyl-1,3-Cyclopentadiene; Pentaphenylcyclopentadiene; 1,2,3,4,5-Pentaphenyl-1,3-Cyclopentadiene ; 1,2,3,4,5-Pentaphenyl-1,3-Cyclopentadiene,; 1,1',1'',1''',1''''-(1,3-Cyclopentadiene-1,2,3,4,5-Pentyl)Pentakisbenzene; 1,2,3,4,5-Pentaphenyl-2,4-Cyclopentadiene; 1,2,3,4,5-Pentaphenylcyclopentane-1,3-Diene; 1,3-Cyclopentadiene-1,2,3,4,5-Pentylpentabenzene
- CAS编号2519-10-0
- MFCD编号:MFCD00012263
- 分子式:C35H26分子量:446.59
- 产品CID: 1209706
- 产品分类有机原料 → 烃类化合物及其衍生物 → 环烃
物理性质
上下游产品
1,2,3,4,5-pentaphenylcyclopenta-2,4-dien-1-ol 1,2,3,4,5-pentaphenyl-cyclopentane-1,2-diol 1-bromo-1,2,3,4,5-pentaphenylcyclopenta-2,4-diene 2,4>-6-°Cten-8-oneendo-1,2,3,4,5,6,7-heptaphenyltricyclo3.2.1.02,4-6-°Cten-8-one lithium pentaphenylcyclopentadienide °Ct-2-ene1,2,3,4,5-Pentaphenyl-6,7,8-trioxabicyclo3.2.1°Ct-2-ene (pentaphenylcyclopentadienyl)lithium sodium pentaphenylcyclopentadienide合成工艺路线路线简述
- 合成目标产物 1,2,3,4,5-Pentaphenyl-1,3-Cyclopentadiene 主要起始原料 Tetraphenylcyclopentadienone
- (文献来源)合成步骤主要原料 Tetraphenylcyclopentadienone
📜1,2,3,4,5-Pentaphenyl-Cyclopentane-1,2-Diol置于硫酸,溶剂黄146体系中,化学反应生成五苯基环戊二烯
参考文献:Ziegler; Schnell,Justus Liebigs Annalen Der Chemie,1925,Vol. 445,P. 277
标题:Ziegler; Schnell,Justus Liebigs Annalen Der Chemie,1925,Vol. 445,P. 277
海关参考信息
- 2901210000-乙烯
2901220000-丙烯
2901241000-1,3-丁二烯
2902500000-苯乙烯 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-8153839-B2
优先权日:2005-09-14
标题:Method for synthesis of keto acids or amino acids by hydration of acetylene compound
发明人：OGO SEIJI; FUKUZUMI SHUN-ICHI
权利人:OGO SEIJI; FUKUZUMI SHUN-ICHI; JAPAN SCIENCE & TECH AGENCY
摘要:An object of the present invention is to provide a method for synthesis of keto acids by hydration of an acetylene compound (acetylene-carboxylic acids) under mild conditions free from harmful mercury catalysts and a method for synthesis of amino acids from acetylene-carboxylic acids in a single container (one-pot or tandem synthesis). In one embodiment of the method according to the present invention for synthesis of keto acids, acetylene-carboxylic acids is hydrated in the presence of a metal salt represented by General Formula (1), n nwhere M 1 represents an element in Group VIII, IX, or X of the periodic table, and X 1 , X 2 , or X 3 ligand represents halogen, H 2 O, or a solvent molecule, and k represents a valence of a cation species, and Y represents an anion species, and L represents a valence of the anion species, and each of K and L independently represents 1 or 2, and k×m=L×n.
专利号:EP-1932824-A1
优先权日:2005-09-14
标题:Method for synthesis of keto acid or amino acid by hydration of acethylene compound
专利号:US-2009216044-A1
优先权日:2005-09-14
标 题:Method for synthesis of keto acids or amino acids by hydration of acetylene compound
专利号:CN-103987757-A
优先权日:2011-11-25
标题:Synthesis of low color index polyalkylene polyamines by homogeneously catalyzed amination of alcohols in the presence of hydrogen
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
摘要:Merino, P., Science of Synthesis, (2010) 45, 143.
摘要:Merino, P., Science of Synthesis, (2010) 45, 110.
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