CAS: 23564-06-9; Thiophanat-Ethyl

化学文摘社编号为235664-06-9,广泛用于农业,以控制作物中的多种真菌疾病;它属于联苯胺衍生物和功能类别,它抑制真菌细胞分裂,有效地干扰病原体的生长和繁殖;它通常作为一种叶片喷雾或土壤处理法使用,以其广泛种类的活动来对付真菌,如粉色,叶点和根腐烂;该化合物的特点是对人类和动物的毒性相对较低,使它在综合虫害管理中成为首选;必须指出,虽然硫酸盐是有效的,但其使用须遵守监管准则,以尽量减少环境影响和在目标真菌中的抗药性发育;此外,它通常与其他活性成分结合,以提高功效和扩大控制范围;适当的应用技术和坚持建议剂量对于在确保安全的同时最大限度地发挥其效力至关重要.

结构式图片

相似化合物

27079-29-4 412912-51-7 949791-69-9

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

1,2-diamino-benzene Ethoxycarbonyl isothi°Cyanate

合成工艺路线路线简述

    📜邻苯二胺,异硫氰酰甲酸乙酯置于四甲基乙二胺体系中,用 乙酸乙酯 用作溶剂,化学反应 5.0H,反应生成硫菌灵
    参考文献:Tmeda催化合成n-芳基-N'-乙氧基羰基硫脲和芳烃(或聚亚甲基)-双-乙氧基羰基硫脲衍生物
    标题:Tmeda催化合成n-芳基-N'-乙氧基羰基硫脲和芳烃(或聚亚甲基)-双-乙氧基羰基硫脲衍生物
    摘要:报道了一种由 Tmeda 催化合成乙氧羰基异硫氰酸酯和乙氧羰基硫脲的新方法.通过该方法在室温下合成了一系列n-芳基-N'-乙氧基羰基硫脲和芳烃(或聚亚甲基)-双-乙氧基羰基硫脲衍生物,产率从非常好到优异.
    Doi:10.1080/10426500490474905

    海关参考信息

    专利信息


    专利号:EP-1578714-B1
    优先权日:2002-12-20
    标题:Novel chiral compounds derived from hexanoic acid esters, method and intermediate chemicals for the preparation and use thereof for synthesis of 2-(bromomethyl)2-ethyl hexanoic chiral acid
    发明人:CROCQ-STUERGA VERONIQUE; ROUSSEL PATRICK
    权利人:AVENTIS PHARMA SA
    摘要:The invention relates to a chiral compound of a formula (I), wherein R1 is hydroxyl or a carboxy activator group and R2 is alkyl eventually substituted by halogen or benzyl. The preparation and the use of the inventive compound for synthesis of 2-bromomethyl-2-ethyl hexanoic chiral acid and the novel intermediate chemicals are also disclosed.

    专利号:WO-9214492-A1
    优先权日:1991-02-14
    标 题:In situ synthesis of radiopharmaceuticals
    发明人:VERBRUGGEN ALFONS M
    权利人:MALLINCKRODT MEDICAL INC
    摘要:The present invention relates to a process of making radiopharmaceuticals in situ, i.e. wherein a radionuclide and an acyclic ligand react with constituents of the complex forming reaction solution to produce an administratable radiopharmaceutical agent. By forming radiopharmarceuticals according to the present invention, it is possible to obtain radiopharmaceuticals previously unattainable because of problems associated with the ligand synthesis or with the complex forming reaction.

    专利号:US-5350681-A
    优先权日:1986-08-18
    标题 :Enzymatic membrane method for the synthesis and separation of peptides
    发明人:IACOBUCCI GUILLERMO A; BROSE DANIEL J; RAY RODERICK J; VAN EIKEREN PAUL
    权利人:COCA COLA CO
    摘要:The present invention discloses a method for the enzymatic synthesis of a peptide. A protected peptide having a C-terminal carboxylate group or a protected, N-acyl amino acid having an alpha carboxylate group is reacted with a protected peptide having an N-terminal ammonium group or a protected amino acid having an alpha ammonium group in the presence of a condensation enzyme under conditions in which the carboxylate group and the ammonium group condense to form a protected, uncharged, peptide product. This peptide product is transported across a water-immiscible hydrophobic phase into an aqueous product phase and prevented from back diffusing across the water-immiscible hydrophobic phase. The peptide product can be converted, chemically or enzymatically, to a charged species that cannot back diffuse across the water-immiscible phase into the aqueous reaction phase. The water-immiscible hydrophobic phase is an ion rejection membrane separating the aqueous reaction phase from the product phase creating oil/water interfaces with each of the aqueous phases.

    专利号:US-9951149-B2
    优先权日:2013-06-17
    标 题 :Reversible heparin molecules and methods of making and using the same
    发明人:LIU JIAN; XU YONGMEI; LINHARDT ROBERT J; HARRIS EDWARD
    权利人:UNIV NORTH CAROLINA CHAPEL HILL; RENSSELAER POLYTECH INST; NUTECH VENTURES; RENSSELAER POLYECHNIC INST
    摘要:Methods and systems for synthesizing heparin compounds are provided. The chemoenzymatic synthesis of structurally homogeneous low molecular weight heparins that have a reversible anticoagulant activity is provided. Also disclosed are heparin compounds having anticoagulant activity, including a binding affinity to antithrombin and an anti-Xa activity, but no detectable anti-lla activity. Additionally, provided are synthetic, low-molecular weight heparin compounds with reversible anticoagulant activity, where the anticoagulant activity is reversible by protamine.

    专利号:WO-2025056767-A1
    优先权日:2023-09-15
    标题 :Process for the preparation of enantiomerically enriched aliphatic amines
    发明人:BOU HAMDAN FARHAN; GODINEAU EDOUARD; SMEJKAL TOMAS; DUMEUNIER RAPHAEL; BOUSSEMGHOUNE MOHAMED ABDELOUAHAB; BLUM MATHIAS
    权利人:SYNGENTA CROP PROTECTION AG
    摘要:The present invention relates to a process for the preparation of enantiomerically enriched cyclobutylamines of formula (I) from α-tertiary cyclobutanones and reacting said enantiomerically enriched cyclobutylamines to enantiomerically enriched cyclobutylamides. Such compounds are useful intermediates in the synthesis of microbiocidal thiazole compounds.

    专利号:US-4246373-A
    优先权日:1980-02-14
    标 题 :Synthesis of substituted cyclopentadienes and cyclopentadiene-functionalized polymers
    发明人:KENNEDY JOSEPH P; CASTNER KENNETH F
    权利人:KENNEDY JOSEPH P; CASTNER KENNETH F
    摘要:Aluminum cyclopentadienyl compounds can be used to synthesize a variety of organic molecules containing the cyclopentadiene group, e.g., substituted cyclopentadiene compounds, polymer molecules with cyclopentadiene pendant groups, and polymer molecules with cyclopentadiene terminal groups.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献


    1: Sharma VP, Kumar A, Kumar S, Barh A, Kamal S. Substrate sterilization with thiophanate-methyl and its biodegradation to carbendazim in oyster mushroom (Pleurotus ostreatus var. florida). Environ Sci Pollut Res Int. 2020 Jan;27(1):899-906. doi: 10.1007/s11356-019-07050-5. Epub 2019 Dec 9. 16(1):e05133. doi: 10.2903/j.efsa.2018.5133.
    3: Hu J, Deng S, Gao T, Lamour K, Liu X, Ren H. Thiophanate-methyl resistance in Sclerotinia homoeocarpa from golf courses in China. Pestic Biochem Physiol. 2018 Nov;152:84-89. doi: 10.1016/j.pestbp.2018.09.004. Epub 2018 Sep 14. 103(1):89-94. doi: 10.1094/PDIS-05-18-0872-RE. Epub 2018 Nov 6. 98(5):720-725. doi: 10.1007/s00128-017-2066-x. Epub 2017 Mar 23.
    248:125941. doi: 10.1016/j.chemosphere.2020.125941. Epub 2020 Jan 21.

    合成参考文献


    摘要:Oyo Yakuri. Pharmacometrics., 4(5), 1970
    摘要:Tomlin CDS, ed; The Pesticide Manual World Compendium. 11th ed., Surrey, England: British Crop Protect Council p. 1201 (1997)
    摘要:Franke C et al; Chemosphere 29: 1501-14 (1994)
    摘要:USEPA; EMMI. EPA's Environmental Monitoring Methods Index. Version 1.1. PC# 4082. Rockville, MD: Government Institutes (1997)
    摘要:USEPA; Pesticides in Ground Water Database, A Compilation of Monitoring Studies. 1971-1991. National Summary. USEPA Off Pest Programs. Prevent Pest Toxic Subst. (H7507C) USEPA-734-12-92-001 (1992)
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知