CAS: 131222-99-6; 6,12-Dibromochrysene

相似化合物

218-01-9 76670-38-7 7397-93-5

上下游产品

CAS号218-01-9 屈 | CAS号7726-95-6 溴素 | CAS号2051-10-7 屈醌

苯并[a]菲置于溴体系中,用 氯仿 用作溶剂,化学反应 24.0H,以90%的收率获得6,12-二溴屈
参考文献:通过rh催化的7-氧杂双环[2.2.1]庚2,5-二烯†的区域选择性芳烃同系物†
标题:通过rh催化的7-氧杂双环[2.2.1]庚2,5-二烯†的区域选择性芳烃同系物†
摘要:氧or催化剂与亚磷酸三苯酯作为氧受体的组合使用可以使氧双环二烯高效脱氧芳构化.反应在中性条件下进行并与各种官能团相容.将该脱氧与区域选择性溴化结合,并用呋喃捕获生成的芳烃,导致pahs的苯环π延伸.这使得可以直接使用未官能化的pah来扩展π共轭.转变的迭代一次增加了一个稠合苯环的数量,这有可能通过微调π共轭度,形状和边缘拓扑来改变pahs的性质.
Doi:10.1039/c9Cc00270G

专利信息

专利号:US-12195423-B1
优先权日:2023-08-27
标 题 :Encoded design integrated synthesis of nucleic acids, and phospholipids, and related pharmaceutical products
发明人：SCHAPER CHARLES
权利人:SCHAPER CHARLES
摘要:Provided herein are reactive aromatic molecules (e.g., substituted chrysene heterodimers) encodable as base-four sequences for the design and integrated synthesis of nucleic acids (e.g., DNA, RNA, hybrid DNA/RNA) and associated phospholipid bilayers (e.g., cellular membranes). For example, 3,6,9,12-tetrasubstituted chrysene is coupled with 6,12-disubstituted chrysene through Ï€-electron stacking to form a base-four heterodimer. The orientation of the ring structure of the tetrasubstituted chrysene in this heterodimer comprises a base-two (binary) structure and the relative alignment of the ring structure of the disubstituted chrysene to the tetrasubstituted chrysene comprises a second independent base-two (binary) structure. This collectively results in a base-four (quaternary) complex composed of four independent reaction environments. Methods of using and forming these molecules and systems associated therewith are also described.

专利号:CN-114057187-A
优先权日:2021-10-28
标 题:A kind of method of tip-induced synthesis of one-dimensional graphene

专利号:US-2025074853-A1
优先权日:2023-08-27
标 题:Encoded design integrated synthesis of nucleic acids, and phospholipids, and related pharmaceutical products