CAS: 109-31-9; Dihexyl Nonanedioate

上下游产品

hexan-1-ol N,N'-dibenzyl-nonanediamideN,N'-dibenzyl-nonanediamide azelaoyl chloride azelaic acid

📜壬二酰氯置于4-二甲氨基吡啶,α,α,α-三联吡啶,Bis(1,5-Cyclooctadiene)Nickel (0),三乙胺体系中,用 二氯甲烷,甲苯,乙腈 用作溶剂,化学反应 36.0H,反应生成壬二酸二己酯
参考文献:镍催化的脂肪族酰胺化
标题:镍催化的脂肪族酰胺化
摘要:最近的研究表明,酰胺可用于镍催化的反应中,从而导致酰胺c-N键断裂,并形成c-C或c-杂原子键.但是,这些方法的一般范围仅限于酰胺,其中羰基直接连接到芳烃或杂芳烃上.现在我们报告衍生自脂肪族羧酸的酰胺的镍催化酯化反应.该转化仅需要稍微过量的醇亲核试剂,并且可以耐受杂环,具有差向异构立体中心的底物和空间上拥挤的偶联配偶体.此外,一系列酰胺竞争实验建立了选择性原理,将有助于未来的合成设计.
Doi:10.1002/anie.201607856

专利信息

专利号:US-2010278715-A1
优先权日:2009-04-29
标 题:Systems, Devices, and/or Methods Regarding Specific Precursors or Tube Control Agent for the Synthesis of Carbon Nanofiber and Nanotube
发明人：KHE NGUYEN
权利人:TH LLC
摘要:Certain exemplary embodiments can comprise, via a tube control agent (TCA) and a metallic catalyst, producing a carbon nanotube. At least some carbon used to form the carbon nanotube can be obtained from a plant, a cellulose product, and/or a cellulosic product. At least some of the carbon can be converted into powder.

专利号:US-12163177-B2
优先权日:2015-04-15
标题:Modified fatty acid biosynthesis with ACP-dependent thiolases
发明人：GONZALEZ RAMON; CLOMBURG JAMES M
权利人:GONZALEZ RAMON
摘要:Methods of using microorganisms to make chemicals and fuels, including carboxylic acids, alcohols, hydrocarbons, and their alpha-, beta-, and omega-functionalized derivatives are described. Native or engineered thiolases are used condense a growing acyl-ACP and acetyl-ACP in combination with type II fatty acid synthesis. The resulting fatty acid biosynthesis cycle has an ATP yield analogous to the functional reverse β-oxidation cycle.