CAS: 91983-14-1; 2-Bromomethylphenylboronic Acid

• 英文名称2-Bromomethylphenylboronic Acid
• 中文名称2-(溴甲基)苯硼酸
• IUPAC名称(2-(bromomethyl)phenyl)boronic acid
• 其它别名2-(Bromomethyl)Phenylboronic Acid2-(溴甲基)苯硼酸; 2溴甲基苯硼酸; 2-Bromomethylphenylboronicacid; 2-(Bromomethyl)Benzeneboronic Acid
• CAS编号91983-14-1
• MFCD编号:MFCD01318941
• EINECS号:626-180-6
• 分子式:C7H8BBrO2
• 分子量:214.85
• 产品CID: 1958132
• 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

• 相似结构搜索
• InChIKey: MYVJCOQGXCONPE-UHFFFAOYSA-N
• InChI=1S/C7H8BBrO2/c9-5-6-3-1-2-4-7(6)8(10)11/h1-4,10-11H,5H2…
• 计算化学: 氢键受体数2.0氢键供体数2.0可旋转键数2.0

物理性质

• 熔点158-162°C
• 沸点358.5±44.0 °C at 760 mmHg
• 闪点170.6±28.4 °C
• 密度1.6±0.1 g/cm3
• pKa:8.44±0.58(预测)
• PSA:40.46
• LogP:0.2613
• 折射率1.582
• 蒸汽压0.0±0.8 mmHg at 25°C
• 敏感性常温常压下稳定 避免接触强氧化剂
• 外观形态淡橙色结晶粉末
• 储存条件2-8°C
• 产品应用该化合物用于氟化物抗炎抗扰动剂分子的氨与的抗反应; 使用含有氟化聚氨的氟化氢酸合成.

MSDS等安全信息

• GHS象形图
• GHS符号GHS07;
  注释: Exclamation mark
• 危险类别特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
  皮肤腐蚀 类别1B
• 警示词Warning(警告)
• 危险描述H335 |可能引起呼吸道刺激.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
  H314 |造成严重皮肤灼伤和眼损伤.
• 防范说明P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501
• 危险等级IRRITANT
• UN编号3261
• 危险品标志Xi,Xn
• 包装等级III
• 安全声明26-36/37/39-36/37-36
• 危险类别码36/37/38-20/21/22
• WGK Germany3

欧盟法规

上下游产品

合成工艺路线路线简述

• 16419-60-6 = 91983-14-1
  反应条件:1.1 Reagents: Bromine Solvents: Carbon Tetrachloride; Rt; 2 H,Rt
  标题:Indoloquinoline Derivatives And Preparation Method And Application Thereof In Antitumor And Antivirus Drugs
  参考文献:China]
  
  16419-60-6 = 91983-14-1
  反应条件:1.1 Reagents: Benzoyl Peroxide,N-Bromosuccinimide Solvents: Carbon Tetrachloride
  标题:Reductive Coupling Of Polyfunctionalized Organobismuth And Organolead Arylating Reagents In The Synthesis Of Benzopyran Derivatives
  作者:Fedorov,A. Yu.; Finet,J.-P.; Ganina,O. G.; Naumov,M. I.; Shavyrin,A. S.
  参考文献:Russian Chemical Bulletin 日期:2005 卷标:54(11) 页码:2602-2611]
  
  16419-60-6 = 91983-14-1
  反应条件:1.1 Reagents: N-Bromosuccinimide Catalysts: Benzoyl Peroxide Solvents: Carbon Tetrachloride; 2 H,Reflux
  标题:Synthesis Of (Azidomethyl)Phenylboronic Acids
  作者:Fedorov,A. Yu.; Shchepalov,A. A.; Bol'Shakov,A. V.; Shavyrin,A. S.; Kurskii,Yu. A.; Et Al
  参考文献:Russian Chemical Bulletin (Translation Of Izvestiya Akademii Nauk 日期:2004 卷标:53(2) 页码:370-375]
  
  16419-60-6 = 91983-14-1
  反应条件:1.1 Reagents: N-Bromosuccinimide Catalysts: Azobisisobutyronitrile Solvents: Carbon Tetrachloride; 2 H,Reflux
  标题:Efficient One-Step Synthesis And Properties Of Photochromic Diarylethenes Having An Indene Bridging Unit
  作者:Jin,Jiayu; Zou,Lei
  参考文献:Chinese Journal Of Chemistry 日期:2011 卷标:29(11) 页码:2445-2450]
  
  16419-60-6 = 91983-14-1
  反应条件:1.1 Reagents: Azobisisobutyronitrile,N-Bromosuccinimide Solvents: Carbon Tetrachloride
  标题:1,3,2-Dioxaborinane,2-[2-(Bromomethyl)-Phenyl]-; 1,3,2-Dioxaborinane,2-[2-(Bromomethyl)Phenyl]-5,5-Dimethyl-
  作者:Chu,Yong; Dai,Chaofeng; Wang,Binghe
  参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2007]
  
  = 91983-14-1 [标题:Reaction Conditions
  标题:Molecular Design Of Boronic Acid-Based Dye Receptors For Nucleosides
  作者:Takeuchi,Masayuki; Taguchi,Masahiro; Shinmori,Hideyuki; Shinkai,Seiji
  参考文献:Bulletin Of The Chemical Society Of Japan 日期:1996 卷标:69(9) 页码:2613-2618]
  
  91994-11-5 = 91983-14-1
  反应条件:1.1 Reagents: N-Bromosuccinimide Catalysts: Azobisisobutyronitrile Solvents: Carbon Tetrachloride; Heated
  标题:Fluorescent Lifetime Assays For Non-Invasive Quantification Of Analytes Such As Glucose
  参考文献:World Intellectual Property Organization]
  
  16419-60-6 = 91983-14-1
  反应条件:1.1 Reagents: Bromine Solvents: Carbon Tetrachloride
  标题:Synthesis Of O- And M-Boronophenylalanine And Their Optical Resolution
  作者:Takahashi,H.; Yoshino,Kazuo; Maruyama,T.; Mori,Y.
  参考文献:1993 卷标:29 页码:29-32]
  
  16419-60-6 = 91983-14-1
  反应条件:1.1 Reagents: Bromine Solvents: Carbon Tetrachloride; Rt; 1 H,Rt; 2 H,Reflux
  标题:Method For Analysis Of Different Oligosacchiride Structures
  作者:Kostadinova,Elena; Dolashka,Pavlina; Kaloyanova,Stefka; Velkova,Ludmyla; Deligeorgiev,Todor; Et Al
  参考文献:Journal Of Fluorescence 日期:2012 卷标:22(6) 页码:1609-1615]
  
  16419-60-6 = 91983-14-1
  反应条件:1.1 Reagents: Benzoyl Peroxide,N-Bromosuccinimide Solvents: Carbon Tetrachloride; Reflux
  标题:Dibenzoyl Peroxide
  作者:Rajanbabu,T. V.; Gagosz,Fabien
  参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2005 卷标:1 页码:1-11]
  
  16419-60-6 = 91983-14-1
  反应条件:1.1 Reagents: N-Bromosuccinimide Catalysts: Benzoyl Peroxide Solvents: Carbon Tetrachloride
  标题:Aryllead Triacetates In The Synthesis Of Oxaphenanthrene Derivatives
  作者:Fedorov,A. Y.; Carrara,F.; Finet,J.-P.
  参考文献:Tetrahedron Letters 日期:2001 卷标:42(34) 页码:5875-5877]
  
  16419-60-6 = 91983-14-1
  反应条件:1.1 Reagents: N-Bromosuccinimide Catalysts: Azobisisobutyronitrile Solvents: Carbon Tetrachloride; 2 H,82 °C
  标题:Dyes And Methods Of Detection Of Nucleic Acid In Immature Red Blood Cells
  参考文献:United States]
  
  16419-60-6 = 91983-14-1
  反应条件:1.1 Reagents: N-Bromosuccinimide Catalysts: Azobisisobutyronitrile Solvents: Chloroform; 2 H,Reflux
  标题:Development Of Fluorous Boronic Acid Catalysts Integrated With Sulfur For Enhanced Amidation Efficiency
  作者:Fridianto,Kevin Timothy; Wen,Ya-Ping; Lo,Lee-Chiang; Lam,Yulin
  参考文献:Rsc Advances 日期:2023 卷标:13(25) 页码:17420-17426]
  
  16419-60-6 = 91983-14-1
  反应条件:1.1 Catalysts: Benzoyl Peroxide,N-Bromosuccinimide Solvents: Carbon Tetrachloride; Reflux
  标题:Dibenzoyl Peroxide
  作者:Rajanbabu,T. V.; Gagosz,Fabien
  参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001]
  
  = 91983-14-1 [标题:Reaction Conditions
  标题:Radiolabeled Compounds And Compositions,Their Precursors And Methods For Their Production
  参考文献:United States

海关参考信息

• 2902300000-甲苯
  2903399020-溴甲烷
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