CAS: 6780-49-0; Ethyl N-Phenylformimidate

上下游产品

CAS号539-30-0 苄基乙基醚 | CAS号122-51-0 原甲酸三乙酯 | CAS号75-03-6 碘乙烷 | CAS号103-70-8 甲酰苯胺 | CAS号864131-95-3 N,N’-diphenylfo... | CAS号60-29-7 乙醚 | CAS号55948-95-3 formanilide, si... | CAS号142-04-1 苯胺盐酸盐 | CAS号5973-71-7 3,4-二甲基苯甲醛 | CAS号21855-35-6 N-hepta-1,6-die... | CAS号66-77-3 1-萘甲醛 | CAS号260-94-6 吖啶 | CAS号538-51-2 N-苄叉苯胺 | CAS号66-99-9 2-萘甲醛 | CAS号100-47-0 苯甲腈 | CAS号864131-95-3 N,N’-diphenylfo... | CAS号109-94-4 甲酸乙酯 | CAS号621-06-7 2-苯基乙酰苯胺

原甲酸三乙酯,苯胺置于溶剂黄146体系中,用 乙醇 作为反应溶剂,化学反应生成 苯亚胺代甲酸乙酯
参考文献:芳烃镁试剂与芳基氯化物在铁催化的交叉偶联反应中作为配体的扩环n-杂环卡宾†
标题:芳烃镁试剂与芳基氯化物在铁催化的交叉偶联反应中作为配体的扩环n-杂环卡宾†
摘要:探讨了铁催化的熊田芳基-芳基偶联反应中环-N-杂环卡宾(nhcs)的结构-活性关系.这是通过比较原位反应生成的,含有空间体积不同的nhc的fe-Nhc催化剂的催化性能来实现的.特别是,从光谱和结构特征方面探讨了环大小(5-8)和n-芳基取代基的影响,这些特征会影响它们的%v Bur值.在5x4结构矩阵的对角线上发现了三个性能最佳的配体,揭示了最佳的空间体积以及微妙的空间变化对催化活性的重大影响.
DOI:10.1039/c8Cc01808A

专利信息

专利号:US-3558614-A
优先权日:1967-09-05
标题:Synthesis of tetranuclear dyes
发明人：JENKINS PHILIP W
权利人:EASTMAN KODAK CO
摘要:TETRANUCLEAR DYES DERIVED FROM A 2-IMIDAZOLIN-4-ONE, A 2-IMIDAZOLIN-4-THIONE AND A 2-IMIDAZOLIN-4-SELENONE ARE PREPARED IN GOOD YIELDS BY CONDENSING A QUATERNIZED MEROCYANINE DYE DERIVED FROM A 2-IMIDAZOLIN-4-ONE, A 2-IMIDAZOLIN-4-THIONE OR A 2-IMIDAZOLIN4-SELENONE WITH (1) A DIALKOXYALKYL ESTER OF AN ORGANIC ACID, (2) A TRIALKOXY ALKANE OR ARYL COMPOUND, (3) A 3,3-DIALKOZY-1ALKOXYPROPENE, (4) A 1-ANILINO-5-PHENYLIMINO-1,3-PENTADIENE OR (5) A SECOND QUATERNIZED MROCYANINE DYE DERIVED FROM A 2-IMIDAZOLIN-4-ONE, A 2-IMIDAZOLIN-4THIONE OR A 2-IMIDAZOLIN-4-SELENONE, EACH HAVING SUBSTITUTED ON THE CARBON IN THE 2-POSITION A GROUP SUCH AS A B-ACETANILIDOVINYL GROUP, A 4-ACETANILIDO-1,3-BUTADIENYL GROUP, AND A 6-ACETANILIDO-1,3,5-HEXADIENYL GROUP.

专利号:GB-1148493-A
优先权日:1965-01-07
标题:Methine dyestuffs and methods of synthesis therefor

专利号:GB-1092252-A
优先权日:1963-10-09
标题:Dyestuffs and methods of synthesis therefor