CAS: 6753-98-6; (1E,4E,8E)-2,6,6,9-Tetramethylcycloundeca-1,4,8-Triene

该化合物是一种自然产生的松树,存在于各种植物的基本油类中,包括跳和丁香,其特点是独特的木质,土芳香,通常用于调味和香味应用.化学上,它被归类为具有分子式C15H24的双循环化合物.α-氟乙烯表现出潜在的反炎和抗菌特性,因此对制药和化妆品研究感兴趣.它的稳定性和低毒性进一步提高了其工业用途的适宜性.作为基本油配方的关键成分,它有助于复杂的气味特征,同时为天然产品开发提供功能上的惠益.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

(5E,9E)-11-chloro-3,3,5,9-tetramethylundeca-5,9-dien-1-yne (5E,9E)-11-Bromo-3,3,6,10-tetramethyl-undeca-5,9-dien-1-yne 3,3,7-trinethyl-11-oxo-4E,7E-dodecadienal (2E,6E,9E)-2,5,5,9-Tetramethyl-cycloundeca-2,6,9-trienol levulinic acid methyl ester 1,4-Pentanediol 2,2-dimethylsuccinic acid Humulan

合成工艺路线路线简述

    📜8-Hydroxygeranyl Acetate置于吡啶,2,4,6-三甲基吡啶,氢氧化钾,正丁基锂,三溴化磷,甲基磺酰氯,Lithium Chloride体系中,用 四氢呋喃,乙醚,乙醇,苯 作为反应溶剂,化学反应 29.0H,反应生成 大麻
    参考文献:通过钯催化卤代烯基硼烷的环化反应合成新的humulene立体和区域特异性
    标题:通过钯催化卤代烯基硼烷的环化反应合成新的humulene立体和区域特异性
    摘要:我们描述了一种新的立体异构和区域特异性合成的ene草烯,蛇麻草的主要倍半萜烯,通过钯催化的从香叶基卤化物通过4个主要步骤衍生的卤代烯基硼烷环化.
    DOI:10.1016/s0040-4039(01)80019-8

    海关参考信息

    专利信息


    专利号:US-2018105838-A1
    优先权日:2015-03-11
    标 题:Process for de novo microbial synthesis of terpenes
    发明人:SCHRADER JENS; BUCHHAUPT MARKUS; SONNTAG FRANK; KRONER CORA; BRÜSER HEIKE; Schröder Hartwig; PELZER RALF
    权利人:BASF SE
    摘要:The invention relates to microbial terpene production. Known methods for microbial production of terpenes are mostly based on the direct conversion of sugars. Therefore alternative substrates, in particular alternative carbon sources, for use in microbial terpene production were desirable. The invention relates to a methylotrophic bacterium containing recombinant DNA coding for at least one polypeptide with enzymatic activity for heterologous expression in said bacterium, wherein said at least one polypeptide with enzymatic activity is selected from the group consisting an enzyme of a heterologous mevalonate pathway, a heterologous terpene synthase and optionally a heterologous synthase of a prenyl diphosphate precursor. The invention further relates in particular to a method for de novo microbial synthesis of sesquiterpenes or diterpenes from methanol and/or ethanol.

    专利号:WO-2018122860-A1
    优先权日:2017-01-02
    标题:System and method for early detection for prevention of postharvest chilling injury
    发明人:NOAM ALKIN
    权利人:US AGRICULTURE; NOAM ALKIN
    摘要:Aspects of the present invention include detection of volatile compounds related to response of vegetable or fruit, (e.g., mango), as result of stress like suboptimal temperature. Such response may lead to activation of some metabolic pathways that can induce synthesis of volatile compounds which may serve according to embodiments of the present invention as signals which indicate onset of CI and/or deterioration of fruit quality. The release of such volatiles compounds may be detected long before CI symptoms become notable. According to some embodiments of the invention, output from sensors detecting presence of volatile compounds indicating that fruits are starting to suffer from chilling stress, are received by at least one control module which operates conditioning system so as to alter storage conditions for avoiding CI and/or quality deterioration of fruits or vegetables.

    专利号:US-7919125-B2
    优先权日:2001-06-20
    标 题:Modulation of inflammation by hops fractions and derivatives
    发明人:TRIPP MATTHEW L; BABISH JOHN G; BLAND JEFFREY S; DARLAND GARY K; LERMAN ROBERT; LUKACZER DANIEL O; LISKA DEANN J; HOWELL TERRENCE M
    权利人:METAPROTEOMICS LLC
    摘要:A natural formulation of compounds that would to modulate inflammation is disclosed. The formulation would also inhibit expression of COX-2, inhibit synthesis of prostaglandin selectively in target cells, and inhibit inflammatory response selectively in target cells. The compositions containing at least one fraction isolated or derived from hops.

    专利号:US-2022162188-A1
    优先权日:2019-01-15
    标 题:Isoprenoids and methods of making thereof
    发明人:WILLIAMS GAVIN; LUND SEAN; HALL RACHAEL
    权利人:UNIV NORTH CAROLINA STATE
    摘要:Disclosed are methods for preparing isoprenoid subunits, as well as methods of employing these isoprenoid subunits for the synthesis of isoprenoids. Also provided are isoprenoids prepared using the methods described herein.

    专利号:US-2022162180-A1
    优先权日:2020-11-24
    标题 :Cannabinol-o-acetate synthesis, compositions, and methods of use
    发明人:OPPERMAN ROBERT; BRISSETTE QUINCY ALEXANDER
    权利人:Marquette Analytica
    摘要:A cannabinol derivative, cannabinol-o-acetate, synthesis, compositions comprising the same, and methods of use.

    专利号:US-2022169626-A1
    优先权日:2020-12-01
    标题 :Cannabichromene-o-acetate synthesis, compositions, and methods of use
    发明人:OPPERMAN ROBERT
    权利人:Marquette Analytica
    摘要:A cannabichromene derivative, cannabichromene-o-acetate, synthesis, compositions comprising the same, and methods of use.

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1007/s00894-011-1160-y
    摘要:Hu S, Yu J, Zeng EY. UV-spectroscopy, electronic structure and ozonolytic reactivity of sesquiterpenes: a theoretical study. Journal of Molecular Modeling. 2011 Jul 16;18(4):1455–62. doi: 10.1007/s00894-011-1160-y.
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