CAS: 4509-11-9; 3,4-Epoxytetrahydrothiophene-1,1-Dioxide

相似化合物

13031-76-0 17200-23-6 24219-36-1

上下游产品

3-Sulfolene rac-3-hydroxy-4-chlorotetrahydrothiophene-1,1-dioxide trans-4-amino-tetrahydrothiophen-3-ol 1,1-dioxide rac-3-hydroxy-4-chlorotetrahydrothiophene-1,1-dioxide trans-3-bromo-4-dihydroxythiolane 1,1-dioxide trans-3,4-dihydroxytetrahydrothiophene-1,1-dioxide

📜Alkaline Earth Salt Of/the/ Methylsulfuric Acid置于水,Barium Carbonate体系中,化学反应生成 3,4-环氧四氢噻吩-1,1-二氧化物
参考文献:Van Lohuizen; Backer,Recueil Des Travaux Chimiques Des Pays-Bas,1949,Vol. 68,P. 1137,1139
标题:Van Lohuizen; Backer,Recueil Des Travaux Chimiques Des Pays-Bas,1949,Vol. 68,P. 1137,1139

专利信息

专利号:US-7038062-B2
优先权日:2004-07-01
标题:Synthesis of cyclic trithiocarbonates from epoxides
发明人：PARKER DANE KENTON
权利人:GOODYEAR TIRE & RUBBER
摘要:This invention provides a low cost technique for synthesizing cyclic trithiocarbonates by a simple one step process from epoxides that can be conducted under atmospheric pressure. This synthesis can be depicted as follows: n nwherein R represents a moiety selected from the group consisting of alkyl groups and aryl groups, wherein R′ represents a moiety selected from the group consisting of alkyl groups, aryl groups, and hydrogen atoms, and wherein R″ represents a moiety selected from the group consisting of alkyl groups, aryl groups, and hydrogen atoms, wherein the R moiety and the R′ moiety can be bonded together to form a cyclic structure, with the proviso that R″ represents a hydrogen atom if R′ represents an alkyl group or an aryl group. In this process carbon disulfide and a thiocyanate salt, such as potassium thiocyanate, are reacted with the epoxide in an ionic liquid, such as 1-butyl-3-methylimidazolium hexafluorophosphate ([Bmim] PF 6 ) in the presence of water to produce the cyclic trithiocarbonate.

专利号:US-2006004210-A1
优先权日:2004-07-01
标题:Synthesis of cyclic trithiocarbonates from epoxides