CAS: 23873-81-6; Diphenylglyoxime

上下游产品

CAS号134-81-6 联苯甲酰 | CAS号1796-05-0 Z-ALPHA,BETA-DI... | CAS号31247-21-9 2,3-diphenylthi... | CAS号951-87-1 内消旋-1,2-二苯基乙二胺 | CAS号29841-69-8 (1S,2S)-(-)-1,2... | CAS号35132-20-8 (1R,2R)-(+)-1,2... | CAS号7647-14-5 氯化钠 | CAS号19768-02-6 3,4-diphenyl-1,... | CAS号888-71-1 3,5-二苯基-1,2,4-噁二唑

Cis-1,2-Dinitrostilbene置于titanium(III) Chloride体系中,用 四氢呋喃,水 用作溶剂,化学反应 0.2H,以54%的收率获得二联苯乙二醛肟
参考文献:氯化钛 (III) 介导的 1-硝基-2-苯基乙烯还原
标题:氯化钛 (III) 介导的 1-硝基-2-苯基乙烯还原
摘要:除了预期的还原产物,肟和羰基化合物之外,1-硝基-2-苯基乙烯(β-硝基苯乙烯)与氯化钛(III)水溶液的反应还提供取代的吡咯.2-取代的 1-硝基-2-苯基乙烯产生二乙烯基胺衍生物而不是吡咯.通过考虑从钛 (III) 物种到硝基烯烃的电子转移,随后进行质子化,二聚,环化和/或水解,使反应机制合理化.
Doi:10.1246/bcsj.64.1787

专利信息

专利号:US-5587431-A
优先权日:1995-04-21
标 题 :Synthesis of terminally unsaturated oligomers
发明人：GRIDNEV ALEXEI A; ITTEL STEVEN D
权利人:DU PONT
摘要:This invention relates to a method for preparing compositions comprising terminally unsaturated polymers of low molecular weight, referred to as oligomers or macromonomers. In particular, a first oligomer composition is obtained by free radical polymerization of a reaction mixture comprising monomers. Terminally unsaturated oligomers in the first oligomer composition, or a selected portion of the composition, are reinitiated into free radicals in order to continue their oligomerization to a desired endpoint. The process is useful for preparing an oligomer composition having a controlled degree of polymerization. The process is also useful for preparing block copolymers. Such oligomer compositions or block polymers are useful for preparing engineered or structured polymers used in making various end products, including plastics, coatings, films, and dispersants.

专利号:EP-0821700-B1
优先权日:1995-04-21
标 题:Synthesis of terminally unsaturated oligomers

专利号:JP-2005133101-A
优先权日:1995-04-21
标 题:Synthesis of terminally unsaturated oligomers

专利号:JP-3660687-B2
优先权日:1995-04-21
标题:Synthesis of terminally unsaturated oligomers

专利号:JP-4195451-B2
优先权日:1995-04-21
标 题 :Synthesis of terminally unsaturated oligomers

专利号:AU-703566-B2
优先权日:1995-04-21
标 题 :Synthesis of terminally unsaturated oligomers