CAS: 1515-75-9; Methyl Penta-2,4-Dienoate

该化合物是具有有机合成和聚合化学应用的同质死因酯,其结构具有反应性死因系统,成为Diels-Alder反应,循环添加剂和其他需要电子丰富死因的变异物的宝贵中间体.甲基酯组增加了有机溶剂的溶解性,便利了合成工作流程的处理.该化合物对于准备功能化循环化合物和作为特殊聚合物的构件特别有用.在受控条件下和定义明确的再活动特征下,其稳定性成为需要精确死因功能的研究和工业应用的可靠选择.

结构式图片

相似化合物

2409-87-2 29739-67-1 21651-12-7

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

methanol 1,3-butadiene-1-carboxylic acid (3E)-2-acetoxypent-3-enoate malonic acid H-[1,2]oxazine-6-carboxylic acid methyl ester2-(4-chloro-phenyl)-3,6-dihydro-2H-[1,2]oxazine-6-carboxylic acid methyl ester oxazin-6-carbonsaeure-methylester3,6-Dihydro-1.2oxazin-6-carbonsaeure-methylester cyclohexanone2-5-(1-carbomethoxypent-2-enyl)cyclohexanone 1-methyl-2-(methoxycarbonyl)-3-cyclohexen-1-carboxaldehyde

合成工艺路线路线简述

    📜(3E)-2-Acetoxypent-3-Enoate置于苯体系中,化学反应生成1.3-丁二烯酸甲酯
    参考文献:Manufacture Of 1-Carbalkoxybutadienes-1,3
    标题:Manufacture Of 1-Carbalkoxybutadienes-1,3

    海关参考信息

    专利信息


    专利号:US-11926589-B2
    优先权日:2019-07-09
    标 题 :Process for the synthesis of non-racemic cyclohexenes
    发明人:REISMAN SARAH; ROMBOLA MICHAEL; LADD CAROLYN L; MCLAUGHLIN MARTIN JOHN; ZUEND STEPHAN; GOETZ ROLAND
    权利人:BASF CORP; CALIFORNIA INST OF TECHN
    摘要:This invention relates to a process for the synthesis of a non-racemic cyclohexene compound of formula (I) by a Diels-Alder reaction of a compound of formula (II) with a compound of formula (III) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 and Y have the meanings as defined in the description in the presence of a catalyst comprising at least one m-valent metal cation M m+ wherein the metal M is selected from Scandium (Sc), Yttrium (Y), Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (Sm), Europium (Eu), Gadolinium 15 (Gd), Terbium (Tb), Dysprosium (Dy), Holmium (Ho), Erbium (Er), Thulium (Tm), Ytterbium (Yb), Lutetium (Lu), Gallium (Ga) and Indium (In), and m is an integer of 1, 2 or 3, and a chiral ligand of the formula (IV) wherein R 10a , R 10b , R 10c , R 10d , R 10a′ , R 10b′ , R 10c′ , R 10d′ , Z and Z′ have the meanings as defined in the description.

    专利号:IL-289459-B1
    优先权日:2019-07-09
    标题:Process for the synthesis of non-racemic cyclohexenes

    专利号:US-2022267247-A1
    优先权日:2019-07-09
    标题:Process for the synthesis of non-racemic cyclohexenes

    专利号:CN-1112547-A
    优先权日:1995-03-10
    标 题 :Synthesis of 2-cyano-2,4-pentadienoic acid monoester and diester

    专利号:US-11371063-B2
    优先权日:2014-07-11
    标题:Microorganisms and methods for the production of butadiene using acetyl-coA
    发明人:PHARKYA PRITI; BURGARD ANTHONY P; BURK MARK J
    权利人:GENOMATICA INC
    摘要:The invention provides non-naturally occurring microbial organisms containing butadiene or 2,4-pentadienoate pathways comprising at least one exogenous nucleic acid encoding a butadiene or 2,4-pentadienoate pathway enzyme expressed in a sufficient amount to produce butadiene or 2,4-pentadienoate. The organism can further contain a hydrogen synthesis pathway. The invention additionally provides methods of using such microbial organisms to produce butadiene or 2,4-pentadienoate by culturing a non-naturally occurring microbial organism containing butadiene or 2,4-pentadienoate pathways as described herein under conditions and for a sufficient period of time to produce butadiene or 2,4-pentadienoate. Hydrogen can be produced together with the production of butadiene or 2,4-pentadienoate.

    专利号:EP-3997082-A1
    优先权日:2019-07-09
    标 题 :Process for the synthesis of non-racemic cyclohexenes

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: Jovina M Sorbetti, Et Al. Aza-Morita-Baylis-Hillman Reactions And Cyclizations Of Conjugated Dienes Activated By Sulfone, Ester, And Keto Groups. J Org Chem. 2007 Apr 27;72(9):3326-31.

    合成参考文献


    摘要:Shinmyozu, T.; Shibahara, M., Science of Synthesis, (2010) 45, 1271.
    摘要:Koo, S., Science of Synthesis, (2010) 45, 1360.
    摘要:Aitken, R. A.; Aitken, K. M., Science of Synthesis, (2010) 47, 1047.
    摘要:Fringuelli, F.; Piermatti, O.; Pizzo, F.; Vaccaro, L., Science of Synthesis, (2010) 47, 585.
    摘要:Fringuelli, F.; Piermatti, O.; Pizzo, F.; Vaccaro, L., Science of Synthesis, (2010) 47, 715.
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