专利号:US-11926589-B2 优先权日:2019-07-09 标 题 :Process for the synthesis of non-racemic cyclohexenes 发明人:REISMAN SARAH; ROMBOLA MICHAEL; LADD CAROLYN L; MCLAUGHLIN MARTIN JOHN; ZUEND STEPHAN; GOETZ ROLAND 权利人:BASF CORP; CALIFORNIA INST OF TECHN 摘要:This invention relates to a process for the synthesis of a non-racemic cyclohexene compound of formula (I) by a Diels-Alder reaction of a compound of formula (II) with a compound of formula (III) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 and Y have the meanings as defined in the description in the presence of a catalyst comprising at least one m-valent metal cation M m+ wherein the metal M is selected from Scandium (Sc), Yttrium (Y), Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (Sm), Europium (Eu), Gadolinium 15 (Gd), Terbium (Tb), Dysprosium (Dy), Holmium (Ho), Erbium (Er), Thulium (Tm), Ytterbium (Yb), Lutetium (Lu), Gallium (Ga) and Indium (In), and m is an integer of 1, 2 or 3, and a chiral ligand of the formula (IV) wherein R 10a , R 10b , R 10c , R 10d , R 10a′ , R 10b′ , R 10c′ , R 10d′ , Z and Z′ have the meanings as defined in the description.
专利号:IL-289459-B1 优先权日:2019-07-09 标题:Process for the synthesis of non-racemic cyclohexenes
专利号:US-2022267247-A1 优先权日:2019-07-09 标题:Process for the synthesis of non-racemic cyclohexenes
专利号:CN-1112547-A 优先权日:1995-03-10 标 题 :Synthesis of 2-cyano-2,4-pentadienoic acid monoester and diester
专利号:US-11371063-B2 优先权日:2014-07-11 标题:Microorganisms and methods for the production of butadiene using acetyl-coA 发明人:PHARKYA PRITI; BURGARD ANTHONY P; BURK MARK J 权利人:GENOMATICA INC 摘要:The invention provides non-naturally occurring microbial organisms containing butadiene or 2,4-pentadienoate pathways comprising at least one exogenous nucleic acid encoding a butadiene or 2,4-pentadienoate pathway enzyme expressed in a sufficient amount to produce butadiene or 2,4-pentadienoate. The organism can further contain a hydrogen synthesis pathway. The invention additionally provides methods of using such microbial organisms to produce butadiene or 2,4-pentadienoate by culturing a non-naturally occurring microbial organism containing butadiene or 2,4-pentadienoate pathways as described herein under conditions and for a sufficient period of time to produce butadiene or 2,4-pentadienoate. Hydrogen can be produced together with the production of butadiene or 2,4-pentadienoate.
专利号:EP-3997082-A1 优先权日:2019-07-09 标 题 :Process for the synthesis of non-racemic cyclohexenes
[参考文献]: Jovina M Sorbetti, Et Al. Aza-Morita-Baylis-Hillman Reactions And Cyclizations Of Conjugated Dienes Activated By Sulfone, Ester, And Keto Groups. J Org Chem. 2007 Apr 27;72(9):3326-31.
合成参考文献
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