CAS: 125288-25-7; (2R,3S,4S,5R,6S)-2-(Hydroxymethyl)-6-(2,4,6-Trimethoxyphenoxy)Tetrahydro-2H-Pyran-3,4,5-Triol

英文名称(2R,3S,4S,5R,6S)-2-(Hydroxymethyl)-6-(2,4,6-Trimethoxyphenoxy)Tetrahydro-2H-Pyran-3,4,5-Triol
中文名称(2R,3S,4S,5R,6S)-2-(羟甲基)-6-(2,4,6-三甲氧基苯氧基)四氢-2H-吡喃-3,4,5-三醇
IUPAC名称(2R,3S,4S,5R,6S)-2-(hydroxymethyl)-6-(2,4,6-trimethoxyphenoxy)tetrahydro-2H-pyran-3,4,5-triol
其它别名2,4,6-Trimethoxyphel 1-O-Beta-D-Glucopyraside; 2,4,6-Trimethoxyphenol 1-O-Beta-D-Glucopyranoside; 2,4,6-Trimethoxyphenol Glucoside; (2R,3S,4S,5R,6S)-2-(Hydroxymethyl)-6-(2,4,6-Trimethoxyphenoxy)Tetrahydro-2H-Pyran-3,4,5-Triol; β-D-Glucopyranoside, 2,4,6-Trimethoxyphenyl; 2,4,6-Trimethoxyphenylβ-D-Glucopyranoside
CAS编号125288-25-7
分子式:C15H22O9分子量:346.33
产品CID: 376158
产品分类有机原料→分子砌块→手性化合物→手性砌块

相似结构搜索
InChIKey: YBNSHGZGFVJIGM-VVSAWPALSA-N
InChI=1S/C15H22O9/c1-20-7-4-8(21-2)14(9(5-7)22-3)24-15-13(19)12(18)11(17)10(6-16)23-15/h4-5,10-13,15-19H,6H2,1-3H3/t10-,11-,12+,13-,15+/m1/s1
计算化学: 氢键受体数9.0氢键供体数4.0可旋转键数6.0

相似化合物

118-34-3 3150-20-7 6032-32-2

MSDS等安全信息

危险描述H303May be harmful if swallowed+H313Skin contact may be harmful+H333Inhalation may be harmful to the body
防范说明P264+P280+P305+P351+P338+P337+P313
危险品标志Xi
安全声明H303+H313+H333

上下游产品

CAS号83013-65-4 1-(O-2,4,6-trim... | CAS号20491-92-3 2,4,6-三甲氧基苯酚

合成工艺路线路线简述

合成目标产物 2,4,6-Trimethoxyphel 1-O-Beta-D-Glucopyraside 主要起始原料 β-D-Glucopyranoside, 2,4,6-Trimethoxyphenyl, 6-(3,4,5-Trihydroxybenzoate)
(文献来源)合成步骤主要原料 β-D-Glucopyranoside, 2,4,6-Trimethoxyphenyl, 6-(3,4,5-Trihydroxybenzoate)

📜2,4,6-Trimethoxyphenol 1-O-β-D-(6'-O-Galloyl)-Glucopyranoside置于水体系中,化学反应 2.0H,以26 Mg的收率获得2,4,6-三甲氧基苯酚 1-O-Beta-D-吡喃葡萄糖苷
参考文献:Tannins And Related Compounds. Iv. Seven New Phenol Glucoside Gallates From Quercus Stenophylla Makino.
标题:Tannins And Related Compounds. Iv. Seven New Phenol Glucoside Gallates From Quercus Stenophylla Makino.
摘要:从栓皮栎(quercus Stenophylla Makino,壳斗科)的树皮中分离出七种新的酚类葡萄糖苷鞣酸酯(化合物1-7),以及没食子酸,鞣酸,(+)-表儿茶素和原花青素b-1和b-3.根据化学和光谱证据,化合物1,2,4,5和6的结构分别确定为6"-O-鞣酸酯(1),3"-O-鞣酸酯(2),4',6"-二-O-鞣酸酯(4),4",6"-二-O-鞣酸酯(5)和3",4",6"-三-O-鞣酸酯(6),它们都是salidroside(对羟基苯乙醇1-O-β-D-葡萄糖吡喃苷).类似地,化合物3和7分别被表征为3',4'-二羟基苯乙醇1-O-β-D-(6"-O-鞣酸酯)-葡萄糖吡喃苷(3)和2,4,6-三甲氧基苯酚1-O-β-D-(6'-O-鞣酸酯)-葡萄糖吡喃苷(7).
Doi:10.1248/cpb.30.2061