CAS: 94-48-4; (E)-3,7-Dimethylocta-2,6-Dien-1-Yl Benzoate

该化合物是来自甲醇和苯甲酸的单极酯酯,其特点是其花粉,果色芳香,使其在香味和口味配方中具有价值;其稳定的酯联系增加了对氧化的抗药性,改善了与酒精前体相比的储存寿命;2E)分解确保了嗅觉特性的一致性,使之适合于香水和香料的精确应用;Geranyl benzoate也表现出低波动性,有助于将其用作复杂的香味成分中的固定成分;它与多种溶剂和载体的兼容性进一步扩大了其工业应用的用途.

结构式图片

相似化合物

106-24-1 106-25-2 25152-85-6

物理性质

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欧盟法规

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CAS号106-24-1 香叶醇; (E)-3,7-二甲... | CAS号2902-69-4 2,2,2-三氯苯乙酮 | CAS号98-88-4 苯甲酰氯 | CAS号769-78-8 苯甲酸乙烯酯 | CAS号93-58-3 苯甲酸甲酯 | CAS号65-85-0 苯甲酸 | CAS号612058-51-2 (E)-(3,7-dimeth... | CAS号122346-13-8 3-methyl-2-(phe... | CAS号870-63-3 1-溴-3-甲基-2-丁烯 | CAS号88218-65-9 (E,E)-8-hydroxy... | CAS号88218-66-0 (3,7-dimethyl-8... | CAS号89637-67-2 benzoic acid,5-... | CAS号89637-71-8 (3-methyl-6-oxo...

合成工艺路线路线简述

  • 106-24-1 + 65-85-0 = 94-48-4
    反应条件:1.1 Reagents: Triphenylphosphine,Diethyl Azodicarboxylate Solvents: Tetrahydrofuran; 0 °C; Rt
    标题:Esterification And Etherification Of Steroid And Terpene Under Mitsunobu Conditions
    作者:Guezane Lakoud,Samia; Djerourou,Abdelhafid
    参考文献:Arabian Journal Of Chemistry 日期:2016 卷标:9]

    106-24-1 + 769-78-8 = 94-48-4
    反应条件:1.1 Catalysts: 1,3-Dihydro-1,3-Bis(2,4,6-Trimethylphenyl)-2H-Imidazol-2-Ylidene Solvents: Tetrahydrofuran; 1 H,Rt
    标题:Efficient Transesterification/acylation Reactions Mediated By N-Heterocyclic Carbene Catalysts
    作者:Grasa,Gabriela A.; Gueveli,Tatyana; Singh,Rohit; Nolan,Steven P.
    参考文献:Journal Of Organic Chemistry 日期:2003 卷标:68(7) 页码:2812-2819]

    106-24-1 + 2902-69-4 = 94-48-4
    反应条件:1.1 Catalysts: Pentamethyldiethylenetriamine Solvents: Acetonitrile; 8 H,20 - 25 °C
    标题:Organocatalytic Selective Benzoylation Of Alcohols With Trichloromethyl Phenyl Ketone: Inverse Selectivity In Benzoylation Of Alcohols Containing Phenol Or Aromatic Amine Functionality
    作者:Ram,Ram N.; Soni,Vineet Kumar; Gupta,Dharmendra Kumar
    参考文献:Tetrahedron 日期:2012 卷标:68(44) 页码:9068-9075]

    106-24-1 + 65-85-0 = 94-48-4
    反应条件:1.1 Reagents: Cyanuric Chloride Catalysts: 1-Pyrrolidinecarboxaldehyde Solvents: Ethyl Acetate; 4 H,80 °C; 10 Min,80 °C -> Rt1.2 Reagents: 4-Methylmorpholine Catalysts: 4-(Dimethylamino)Pyridine Solvents: Ethyl Acetate; 15 Min,0 °C; 0 °C -> Rt; 6 H,Rt
    标题:Formamide Catalyzed Activation Of Carboxylic Acids - Versatile And Cost-Efficient Amidation And Esterification
    作者:Huy,Peter H.; Mbouhom,Christelle
    参考文献:Chemical Science 日期:2019 卷标:10(31) 页码:7399-7406]

    106-24-1 + 98-88-4 = 94-48-4
    反应条件:1.1 Reagents: Pyridine Catalysts: 4-(Dimethylamino)Pyridine Solvents: Diethyl Ether; Rt; 20 H,Rt1.2 Reagents: Sodium Bicarbonate Solvents: Water; Rt
    标题:Biomimetic Syntheses Of Analogs Of Hongoquercin A And B By Late-Stage Derivatization
    作者:Mies,Thomas; White,Andrew J. P.; Parsons,Philip J.; Barrett,Anthony G. M.
    参考文献:Journal Of Organic Chemistry 日期:2021 卷标:86(2) 页码:1802-1817]

    106-24-1 + 93-58-3 = 94-48-4
    反应条件:1.1 Catalysts: Diethylene Glycol Monomethyl Ether,2-Propanol,Lanthanum(3+) Salt Solvents: Hexane; 1 - 2 Min,Rt1.2 3 H,Reflux; Reflux -> Rt1.3 Reagents: Water; 5 Min,Rt
    标题:Ligand-Assisted Rate Acceleration In Lanthanum(Iii) Isopropoxide Catalyzed Transesterification Of Carboxylic Esters
    作者:Hatano,Manabu; Furuya,Yoshiro; Shimmura,Takumi; Moriyama,Katsuhiko; Kamiya,Sho; Et Al
    参考文献:Organic Letters 日期:2011 卷标:13(3) 页码:426-429]

    106-24-1 + 98-88-4 = 94-48-4
    反应条件:1.1 Reagents: Manganese Catalysts: Titanocene Dichloride Solvents: 1,4-Dioxane; 15 Min,Rt1.2 Reagents: Diiodomethane Solvents: 1,4-Dioxane; 2.5 H,Rt1.3 1.5 H,Rt
    标题:Efficient O-Acylation Of Alcohols And Phenol Using Cp2Ticl As A Reaction Promoter
    作者:Duran-Pena,Maria Jesus; Botubol-Ares,Jose Manuel; Hanson,James R.; Hernandez-Galan,Rosario; Collado,Isidro G.
    参考文献:European Journal Of Organic Chemistry 日期:2016 卷标:2016(21) 页码:3584-3591]

    106-24-1 + 65-85-0 = 94-48-4
    反应条件:1.1 Reagents: N,N-Dimethyl-P,P-Diphenylphosphinous Amide Solvents: Dichloromethane; 1 H,40 °C1.2 Reagents: 2,6-Dimethyl-1,4-Benzoquinone Solvents: Dichloromethane; 1 H,Rt
    标题:Efficient Method For The Preparation Of Carboxylic Acid Alkyl Esters Or Alkyl Phenyl Ethers By A New-Type Of Oxidation-Reduction Condensation Using 2,6-Dimethyl-1,4-Benzoquinone And Alkoxydiphenylphosphines
    作者:Shintou,Taichi; Kikuchi,Wataru; Mukaiyama,Teruaki
    参考文献:Bulletin Of The Chemical Society Of Japan 日期:2003 卷标:76(8) 页码:1645-1667]

    106-24-1 + 98-88-4 = 94-48-4
    反应条件:1.1 Reagents: Pyridine Solvents: Dichloromethane; 0 °C; 6 H,Rt
    标题:Nitrosyl Triflate And Nitrous Anhydride,Same Mode Of Generation,But Very Different Reaction Pathways. Direct Synthesis Of 1,2-Oxazetes,Nitroso Or Bisoxazo Compounds From Olefins
    作者:Reddy,G. Sudhakar; Suh,Elijah J.; Corey,E. J.
    参考文献:Organic Letters 日期:2022 卷标:24(23) 页码:4202-4206]

    106-24-1 + 98-88-4 = 94-48-4
    反应条件:1.1 Catalysts: Silica; 2 Min
    标题:Microwave-Assisted Solvent-Free O-Alkylation And Acylation Of Thymol And Geraniol Using Fly Ash As Solid Support
    作者:More,D. H.; Hundiwale,D. G.; Kapadi,U. R.; Mahulikar,P. P.
    参考文献:Journal Of Scientific & Industrial Research 日期:2006 卷标:65(10) 页码:817-820]

    106-24-1 + 135364-97-5 = 94-48-4
    反应条件:1.1 Catalysts: Cesium Fluoride Solvents: Acetonitrile; 15 H,100 °C
    标题:Fluoride-Catalyzed Esterification Of Amides
    作者:Wu,Hongxiang; Guo,Weijie; Daniel,Stelck; Li,Yue; Liu,Chao; Et Al
    参考文献:Chemistry - A European Journal 日期:2018 卷标:24(14) 页码:3444-3447]

    106-24-1 + 98-88-4 = 94-48-4
    反应条件:1.1 Reagents: Triethylamine Catalysts: 4-(Dimethylamino)Pyridine Solvents: Dichloromethane; 0 °C; 0 °C -> Rt; Overnight,Rt1.2 Reagents: Water; Rt
    标题:A Direct Approach To Amines With Remote Stereocentres By Enantioselective Cuh-Catalyzed Reductive Relay Hydroamination
    作者:Zhu,Shaolin; Niljianskul,Nootaree; Buchwald,Stephen L.
    参考文献:Nature Chemistry 日期:2016 卷标:8(2) 页码:144-150]

    106-24-1 + 65-85-0 = 94-48-4
    反应条件:1.1 Reagents: Triphenylphosphine,Iodine Solvents: Dichloromethane1.2 Reagents: Imidazole1.3 10 Min,Rt1.4 Catalysts: Gadolinium Triflate; 30 Min,50 °C1.5 3 H,50 °C1.6 Reagents: Sodium Bicarbonate Solvents: Water
    标题:Gd(Otf)3-Catalyzed Synthesis Of Geranyl Esters For The Intramolecular Radical Cyclization Of Their Epoxides Mediated By Titanocene(Iii)
    作者:Garcia Santos,William H.; Puerto Galvis,Carlos E.; Kouznetsov,Vladimir V.
    参考文献:Organic & Biomolecular Chemistry 日期:2015 卷标:13(5) 页码:1358-1366]

    106-24-1 + 5145-65-3 = 94-48-4
    反应条件:1.1 Catalysts: 2,2′-Bipyridine,Bis(1,5-Cyclooctadiene)Nickel Solvents: Toluene; 18 H,80 °C
    标题:Ni-Catalyzed Direct Alcoholysis Of N-Acylpyrrole-Type Tertiary Amides Under Mild Conditions
    作者:Chen,Hang; Chen,Dong-Huang; Huang,Pei-Qiang
    参考文献:Science China: Chemistry 日期:2020 卷标:63(3) 页码:370-376]

    65-85-0 = 94-48-4 [标题:Reaction Conditions
    标题:Beyond The Tebbe Olefination: Direct Transformation Of Esters Into Ketones Or Alkenes
    作者:Domzalska-Pieczykolan,Anna M.; Furman,Bartlomiej
    参考文献:Synlett 日期:2020 卷标:31(7) 页码:730-736]

    106-24-1 + 98-88-4 = 94-48-4
    反应条件:1.1 Catalysts: Manganese Solvents: Tetrahydrofuran; 10 Min,Rt1.2 Solvents: Tetrahydrofuran; 30 Min,Rt1.3 Reagents: Hydrochloric Acid Solvents: Water; Rt
    标题:Highly Active Manganese-Mediated Acylation Of Alcohols With Acid Chlorides Or Anhydrides
    作者:Joo,Seong-Ryu; Youn,Young-Jin; Hwang,Young-Ran; Kim,Seung-Hoi
    参考文献:Synlett 日期:2017 卷标:28(19) 页码:2665-2669]

    106-24-1 + 65-85-0 = 94-48-4
    反应条件:1.1 Reagents: Dicyclohexylcarbodiimide Catalysts: 4-(Dimethylamino)Pyridine Solvents: Dichloromethane; 24 H,Rt
    标题:Metal-Free Intermolecular Allylic C-H Amination Of Alkenes Using Primary Carbamates
    作者:Obenschain,Derek C.; Tabor,John R.; Michael,Forrest E.
    参考文献:Acs Catalysis 日期:2023 卷标:13(7) 页码:4369-4375]

    106-24-1 + 85909-02-0 = 94-48-4
    反应条件:1.1 Catalysts: Cesium Carbonate Solvents: Dimethyl Sulfoxide; 12 H,23 °C1.2 Solvents: Water; 23 °C
    标题:Cesium Carbonate Catalyzed Esterification Of N-Benzyl-N-Boc-Amides Under Ambient Conditions
    作者:Ye,Danfeng; Liu,Zhiyuan; Chen,Hao; Sessler,Jonathan L.; Lei,Chuanhu
    参考文献:Organic Letters 日期:2019 卷标:21(17) 页码:6888-6892
📜苯甲酸置于1-羟基苯并三唑,盐酸-N-乙基-Nˊ-(3-二甲氨基丙基)碳二亚胺,三乙胺,Cesium Fluoride体系中,用 N,N-二甲基甲酰胺,乙腈 作为反应溶剂,化学反应 31.0H,反应生成 2,4-二甲基苄胺
参考文献:氟化物催化酰胺的酯化反应
标题:氟化物催化酰胺的酯化反应
摘要:近年来,已证明可以使用过渡金属催化剂活化并选择性裂解酰胺的碳氮键.但是,这些方法仅限于特定的酰胺.催化体系与酰胺之间存在一对一的关系,并且还使用大量的过渡金属催化剂和配体.因此,我们现在报告使用氟化物作为催化剂对普通酰胺进行酯化的一般策略.该方法显示出较高的官能团耐受性,尤其是仅需要略微过量的醇亲核试剂,这在无过渡金属的酰胺转化中很少见.而且,
DOI:10.1002/chem.201800336

海关参考信息

专利信息


专利号:US-9388345-B2
优先权日:2012-07-03
标题:Hydrocarbon synthesis methods, apparatus, and systems
发明人：MCNEFF CLAYTON V; MCNEFF LARRY C; NOWLAN DANIEL THOMAS; YAN BINGWEN; GREUEL PETER G
权利人:SARTEC CORP
摘要:Embodiments of the invention include apparatus and systems for hydrocarbon synthesis and methods regarding the same. In an embodiment, the invention includes a process for creating a hydrocarbon product stream comprising reacting a reaction mixture in the presence of a catalyst inside of a reaction vessel to form a product mixture, the reaction mixture comprising a carbon source and water. The temperature inside the reaction vessel can be between 450 degrees Celsius and 600 degrees Celsius and the pressure inside the reaction vessel can be above supercritical pressure for water. In an embodiment, the invention includes an extrusion reactor system for creating a hydrocarbon product stream. The temperature inside the extrusion reactor housing between 450 degrees Celsius and 600 degrees Celsius. Pressure inside the reaction vessel can be above supercritical pressure for water. Other embodiments are also included herein.

专利号:US-6911318-B2
优先权日:1999-03-03
标 题:Bacterial transglycosylases: assays for monitoring the activity using Lipid II substrate analogs and methods for discovering new antibiotics
发明人：KAHNE SUZANNE WALKER
权利人:UNIV PRINCETON
摘要:This invention provides a direct method for monitoring bacterial transglycosylase activity using labeled substrates produced by chemo-enzymatic synthesis wherein the labels are selected to permit the detection of both polymeric and non-polymeric products simultaneously, either directly or following the separation of product from starting material. The invention promotes the discovery of new antibiotics with activity against bacterial transglycosylases by a) laying the groundwork for structural analysis of purified, active transglycosylase (which permits structure-based design); and b) providing an assay that can be used to screen for inhibitors.

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