CAS: 618-91-7; Methyl 3-Iodobenzoate

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CAS号67-56-1 甲醇 | CAS号618-51-9 间碘苯甲酸 | CAS号93-58-3 苯甲酸甲酯 | CAS号98-86-2 苯乙酮 | CAS号19718-49-1 4-氨基-3-碘苯甲酸甲酯 | CAS号3240-34-4 碘苯二乙酸 | CAS号585524-77-2 3-甲氧羰基苯硼酸新戊二醇酯 | CAS号19438-10-9 间羟基苯甲酸甲酯 | CAS号107658-28-6 methyl 3-(trifl... | CAS号618-89-3 3-溴苯甲酸甲酯 | CAS号39115-94-1 3-碘苯甲酰肼 | CAS号14899-31-1 3-磷酰基苯甲酸 | CAS号207845-32-7 3-苯基乙炔-苯甲酸甲酯 | CAS号197658-21-2 methyl 3-(3-met... | CAS号3441-03-0 3-(氯羰基)苯甲酸甲酯 | CAS号21860-07-1 3-乙酰基苯甲酸甲酯 | CAS号1877-71-0 异酞酸氢甲酯 | CAS号99-36-5 3-甲基苯甲酸甲酯 | CAS号99769-19-4 3-甲氧基羰基苯硼酸 | CAS号618-89-3 3-溴苯甲酸甲酯

苯甲酸甲酯置于tetramethylammonium Hydrogen Sulfate体系中,化学反应 0.25H,以96%的收率获得产物3-碘苯甲酸甲酯
参考文献:Tetraalkylammonium Dichloroiodates As Iodinating Agents: Absence Of Activity In Solid Phases And Superelectrophilic Activity In Sulfuric Acid
标题:Tetraalkylammonium Dichloroiodates As Iodinating Agents: Absence Of Activity In Solid Phases And Superelectrophilic Activity In Sulfuric Acid
摘要:与已发表的结果相反,四烷基铵二氯碘酸盐(alk4N+icl2-)在无溶剂条件下不能作为芳烃的碘化试剂.然而,在硫酸溶液中或在与硫酸中的ag2So4存在下,四烷基铵二氯碘酸盐表现出超亲电子特性,并作为非常方便和高效率的碘化试剂用于非活化芳烃.
DOI:10.1055/s-2008-1032026

专利信息

专利号:US-2025179012-A1
优先权日:2022-03-04
标 题:Synthesis of sulfur(vi) compounds and reagents for same
发明人：LOPCHUK JUSTIN MATTHEW; SHULTZ ZACHARY
权利人:H LEE MOFFITT CANCER CT & RES
摘要:This disclosure provides reagents and processes for the synthesis of organic compounds, more particularly reagents and processes for the asymmetric synthesis of sulfur (VI) containing organic compounds.

专利号:WO-2015131100-A1
优先权日:2014-02-28
标题:Ligand-controlled c(sp3)-h arylation and olefination in synthesis of unnatural chiral alpha amino acids
发明人：YU JIN-QUAN
权利人:SCRIPPS RESEARCH INST
摘要:The use of ligands to tune the reactivity and selectivity of transition metal-catalysts for C(-sp3)-H bond functionalization is a central challenge in synthetic organic chemistry. Herein, we report a rare example of catalyst-controlled C(sp3)-H arylation using pyridine and quinoline derivatives: the former promotes exclusive monoarylation, whereas the latter activates the catalyst further to achieve diarylation. Successive application of these ligands enables the sequential diarylation of a methyl group in an alanine derivative with two different aryl iodides, affording a wide range of β-Ar-p-Ar ' -cc-amino acids with excellent levels of diastereoselectivity (d.r. > 20:1). Both configurations of the β-chiral center can be accessed by choosing the order in which the aryl groups are installed. The use of a quinoline derivative as a ligand also enables C(sp3)-H olefination of a protected alanine.

专利号:US-10226449-B2
优先权日:2013-12-20
标 题:Heterocyclic modulators of lipid synthesis and combinations thereof
发明人：HEUER TIMOTHY SEAN; OSLOB JOHAN D; MCDOWELL ROBERT S; JOHNSON RUSSELL; YANG HANBIAO; EVANCHIK MARC; ZAHARIA CRISTIANA A; CAI HAIYING; HU LILY W; DUKE GREGORY; OHOL-GUPTA YAMINI; O'FARRELL MARIE
权利人:3 V BIOSCIENCES INC
摘要:Heterocyclic modulators of lipid synthesis are provided as well as pharmaceutically acceptable salts thereof; pharmaceutical compositions comprising such compounds; and methods of treating conditions characterized by dysregulation of a fatty acid synthase pathway by the administration of such compounds and combinations of such compounds and other therapeutic agents.

专利号:US-10189822-B2
优先权日:2015-03-19
标 题:Heterocyclic modulators of lipid synthesis
发明人：OSLOB JOHAN D; MCDOWELL ROBERT S; JOHNSON RUSSELL; YANG HANBIAO; EVANCHIK MARC; ZAHARIA CRISTIANA A; CAI HAIYING; HU LILY W; DUKE GREGORY; OHOL-GUPTA YAMINI; HEUER TIMOTHY SEAN; O'FARRELL MARIE
权利人:3 V BIOSCIENCES INC
摘要:Compounds that are fatty acid synthesis modulators are provided. The compounds may be used to treat disorders characterized by disregulation of the fatty acid synthase function by modulating the function and/or the fatty acid synthase pathway. Methods are provided for treating such disorders including viral infections, such as hepatitis C infection, cancer and metabolic disorders.

专利号:US-11034690-B2
优先权日:2016-11-11
标 题:Heterocyclic modulators of lipid synthesis
发明人：BUCKLEY DOUGLAS I; DUKE GREGORY; WAGMAN ALLAN S; EVANCHIK MARC; MCDOWELL ROBERT S
权利人:SAGIMET BIOSCIENCES INC; SAGINIET BIOSCIENCES INC
摘要:Compounds that are fatty acid synthesis modulators are provided. The compounds may be used to treat disorders characterized by disregulation of the fatty acid synthase function by modulating the function and/or the fatty acid synthase pathway. Methods are provided for treating such disorders including viral infections, such as hepatitis C infection, cancer and metabolic disorders, such as non-alcoholic steatohepatitis (NASH).

专利号:US-9428502-B2
优先权日:2012-07-03
标题:Heterocyclic modulators of lipid synthesis
发明人：OSLOB JOHAN D; MCDOWELL ROBERT S; JOHNSON RUSSELL; YANG HANBIAO; EVANCHIK MARC; ZAHARIA CRISTIANA A; CAI HAIYING; HU LILY W; WAGMAN ALLAN S
权利人:3-V BIOSCIENCES INC
摘要:Heterocyclic modulators of lipid synthesis are provided as well as pharmaceutically acceptable salts thereof; pharmaceutical compositions comprising such compounds; and methods of treating conditions characterized by disregulation of a fatty acid synthase pathway by the administration of such compounds.