CAS: 492-99-9; 1,2-Bis(Hydroxyimino)Cyclohexane

该化合物是一种循环二氧化二氮化合物,其特征是两个氧化二氧化二氮功能组,在环氧环已烷骨骨上有一个精密的配置,这种结构具有很强的镀层特性,有助于协调化学,形成与过渡金属相稳定的复合体.它的僵硬环环乙烷框架加强了合成中的立体化学控制,而氧化组则能够参与凝聚和再氧化反应.该化合物在分析化学中受到重视,用于选择性金属离子探测和设计金属-有机框架的材料科学(MOFs),在温和条件下,其稳定性和再活动性使其成为有机和无机合成的多功能中间体.

结构式图片

相似化合物

765-87-7 100-64-1 1074-51-7

上下游产品

2-brom°Cyclohexanone cyclohexane-1,2-dione 2-Chlor°Cyclohexanone 4,5,6,7-tetrahydro-2,1,3-benzoxadiazol-N-oxide 4,5,6,7-tetrahydro-2,1,3-benzoxadiazol-N-oxide O-deuterio oxime )cyclohexane-1,2-dione-bis-(O-deuterio oxime ) trans-1,2-Diamin°Cyclohexane Cyclohexan-1,2-dion-bis-(-O-trimethylsilyl-oxim)

合成工艺路线路线简述

    2-溴环己酮置于盐酸,甲醇,羟胺,Sodium Acetate体系中,化学反应生成 1,2-环已二酮二肟
    参考文献:Belcher Et Al.,Journal Of The Chemical Society,1958,P. 2743
    标题:Belcher Et Al.,Journal Of The Chemical Society,1958,P. 2743

    专利信息


    专利号:US-5877186-A
    优先权日:1997-04-28
    标题 :Carotenoid synthesis inhibiting herbicides and fatty acid synthesis inhibiting oxime herbicides as anti-apicomplexa protozoan parasite agents
    发明人:LEEF JAMES L; CARLSON PETER S
    权利人:PARAPRO LLC
    摘要:Protozoan parasites of the phylum Apicomplexa include some of the most important causative agents of human and animal diseases, in particular, malaria. The discovery that an organelle found inside parasites of this phylum probably stems from a plastid of plant origin has stimulated research on the effect of chemical herbicidal agents on Apicomplexa. Members of the triazine family and of the dinitroaniline family of herbicides have been found to be active against some Apicomplexa. The present invention extends the list of chemical herbicidal agents active against Apicomplexa to include classes of herbicides active as carotenoid synthesis inhibitory agents in plants and herbicidal agents effective against fatty acid synthesis in plants.

    专利号:WO-2019218027-A1
    优先权日:2018-05-18
    标题:Core-shell particles
    发明人:MEANEY SHANE; TABOR RICHARD; FOLLINK BART
    权利人:UNIV MONASH
    摘要:The application relates to a core-shell particle having a) a cross-linked polyelectrolyte core, and b) a silica-based shell having covalently bound thereto one or more groups of formula –R–F, wherein R is an organic group and F is a functional moiety. The application also relates to a method of synthesis of a core-shell particle, the method comprising the steps of: a) providing a cross-linked polyelectrolyte core template, b) coating the core template with a silica-based shell, and c) introducing one or more groups of formula –R–F covalently bound to the silica-based shell, wherein R is an organic group and F is a functional moiety.

    专利号:US-5118797-A
    优先权日:1989-08-28
    标 题 :Rhenium tris dioxime complexes
    发明人:JURISSON SILVIA; LINDER KAREN E; FRANCESCONI LYNN C
    权利人:SQUIBB & SONS INC
    摘要:Rhenium tris dioxime complexes are useful in the synthesis of boronic acid adducts of rhenium dioxime complexes which are useful as radiotherapeutic agents.

    专利号:EP-0001105-A1
    优先权日:1977-09-07
    标 题:2-Piperidino-3-hydroxylamino-cyclohexanon oximes and a process for their preparation
    发明人:WEITZ HANS-MARTIN DR; FISCHER ROLF DR
    权利人:BASF AG
    摘要:2-piperidino-3-hydroxylamino-cyclohexanone oximes, process for the preparation of 2-piperidino-3-hydroxylamino-cyclohexanone oximes of the formula in which the individual radicals R can be the same or different and each represent a hydrogen atom, an aliphatic, cycloaliphatic, araliphatic or aromatic radical, moreover two adjacent radicals R can also denote members of a ring together with the two adjacent carbon atoms, by reaction of the corresponding 2 -Piperidino-cyclohexene, - (2) -ones with hydroxylamine.n n n The compounds I are complexing agents for heavy metal ions, they are starting materials for the production of triamines, which serve as alkaline catalysts, additives to epoxy resins and as starting materials for the synthesis of dyes and medicaments.

    专利号:CN-109174200-A
    优先权日:2018-09-04
    标 题:A kind of catalyst, preparation method and synthesis method for synthesizing 1,1-diethoxyethane
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    主要参考文献

    [参考文献]: Yumin Zheng, Et Al. Effect Of Co-Ligands On Chemical And Biological Properties Of (99M)Tc(Iii) Complexes [(99M)Tc(L)(Cdo)(Cdoh)2Bme] (L=cl, F, Scn And N3; Cdoh2=cyclohexanedione Dioxime). Nucl Med Biol. 2014 Nov-Dec;41(10):813-24.

    合成参考文献


    摘要:Merck Index - O'Neil MJ, Heckelman PE, Dobbelaar PH, Roman KJ (eds). The Merck Index, An Encyclopedia of Chemicals, Drugs, and Biologicals, 15th Ed. Cambridge, UK: The Royal Society of Chemistry, 2013.
    摘要:Bubnov, Y., Science of Synthesis, (2005) 6, 1026.
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