CAS: 39622-79-2; 2-Aminoisophthalic Acid

该化合物是一种有机化合物,属于芳烃氨基酸类别,其特点是一个含有两个碳本体酸组和一个氨基组的苯环,具体位于异硫酸结构的2和5个位置上;该化合物一般是白色至白色晶状固体,在水和酒精等极溶剂中表现出溶解性,但在非极溶剂中不易溶解;其分子结构有助于聚合聚合聚合物中的潜在应用,特别是在生产高性能材料和树脂方面;氨基和氨基酸功能组的存在可以产生各种化学反应,包括混合反应和形成氨酸.此外,2-氨基异硫酸可以作为制药和农用化学的建筑块,突出其有机合成的多变性.其特性,如熔点和稳定性,可以因纯度和环境条件而不同而不同.

英文名称2-Aminoisophthalic Acid
中文名称2,6-二羧基苯胺
IUPAC名称2-aminoisophthalic acid
其它别名2-氨基间苯二甲酸; 2,6-Dicarboxyaniline
CAS编号39622-79-2
MFCD编号:MFCD00817808
EINECS号:674-256-2
分子式:C8H7NO4
分子量:181.15
产品CID: 1408014
产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

相似结构搜索
产品信息参考;;;;
InChIKey: LDOMKUVUXZRECL-UHFFFAOYSA-N
InChI=1S/C8H7NO4/c9-6-4(7(10)11)2-1-3-5(6)8(12)13/h1-3H,9H2,(H,10,11)(H,12,13)…
计算化学: 氢键受体数3.0氢键供体数3.0可旋转键数2.0

MSDS等安全信息

GHS象形图
GHS符号GHS07;
注释: Exclamation mark
危险类别急性毒性类别4(吸入)
急性毒性类别4(经皮)
急性毒性类别4(经口)
特定目标器官毒性 - 单次接触类别3
皮肤腐蚀/刺激类别2
严重眼刺激类别2
严重眼刺激类别2A
警示词Warning(警告)
危险描述H332 |吸入有害.
H312 |皮肤接触有害.
H302 |吞咽有害.
H335 |可能引起呼吸道刺激.
H315 |造成皮肤刺激.
H319 |造成严重眼刺激.
防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
危险品标志Xi
安全声明26-36/37/39
危险类别码36/37/38

欧盟法规

ECHA物质C&L通报

上下游产品

2-nitroisophthalic acid 2-acetamidoisophthalic acid 2-benzoylamino-isophthalic acid 2,6-dimethylaniline 2-iodoyl-1,3-benzenedicarboxylic acid 4-oxo-3,4-dihydroquinazoline-8-carboxylic acid H-benzo[d][1,3]oxazine-8-carboxylic acid2-amino-4-oxo-4H-benzo[d][1,3]oxazine-8-carboxylic acid 8-carboxyisatoic anhydride

合成工艺路线路线简述

2,6-二甲基硝基苯置于盐酸,Tin,Potassium Permanganate体系中,化学反应生成2,6-二羧基苯胺
参考文献:D'Rozario,A. Peter; Greig,Derek J.; Hudson,Robert F.,Journal Of The Chemical Society. Perkin Transactions Ii,1981,P. 590-596
标题:D'Rozario,A. Peter; Greig,Derek J.; Hudson,Robert F.,Journal Of The Chemical Society. Perkin Transactions Ii,1981,P. 590-596

海关参考信息

2905110000-甲醇
2906210000-苄醇
2912110000-甲醛
2912210000-苯甲醛
💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
详情请参考：📖 海关编码查询和海关进出口税则

专利信息

专利号:US-9890125-B2
优先权日:2013-01-08
标题:Syntheses of N-heterocyclic carbenes and intermediates therefor
发明人：NOLAN STEVEN P; MEIRIES SEBASTIEN
权利人:UNIV COURT UNIV ST ANDREWS
摘要:A method of preparing a 2,6 disubstituted anilines includes, reacting a 2-amino isophthalic acid diester with sufficient Grignard reagent R 2 CH 2 MgX to form the corresponding diol product, dehydrating the diol product to the corresponding dialkene; and hydrogenating the diol product to form the corresponding aniline. The 2,6 disubstituted anilines can be used to produce N-Heterocyclic Carbenes (NHCs). The NHCs can find application in various fields such as organic synthesis, catalysis and macromolecular chemistry. Palladium catalysts containing the NHCs are also described.

专利号:JP-7199401-B2
优先权日:2013-01-08
标题:Synthesis of N-heterocyclic carbenes and their intermediates

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优先权日:2019-01-22
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优先权日:2018-09-07
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专利号:CN-104981460-B
优先权日:2013-01-08
标题:Synthesis of N-heterocyclic carbenes and intermediates thereof

专利号:CN-104981460-A
优先权日:2013-01-08
标题 :Synthesis of N-heterocyclic carbenes and intermediates thereof