📜1-(间氯苯基)乙酸烯丙酯置于双(乙腈)氯化钯(II),Sodium Methylate Manganese(Iv) Oxide体系中,用 甲醇,Petroleum Ether,苯 作为反应溶剂,化学反应 5.0H,反应生成 3-氯肉桂醛 参考文献:Crilley,Martine M. L.; Golding,Bernard T.; Pierpoint,Colin,Journal Of The Chemical Society. Perkin Transactions I,1988,P. 2061-2068 标题:Crilley,Martine M. L.; Golding,Bernard T.; Pierpoint,Colin,Journal Of The Chemical Society. Perkin Transactions I,1988,P. 2061-2068
专利号:US-8558012-B2 优先权日:2009-03-02 标 题:2-fluoro-1,3-benzodithiol 1,1,3,3-tetraoxide derivative, production method thereof, and production method of monofluoromethyl group-containing compound using the same 发明人:SHIBATA NORIO 权利人:SHIBATA NORIO; NAGOYA INST TECHNOLOGY; TOSOH P TECH INC 摘要:A 2-fluoro-1,3-benzodithiol 1,1,3,3-tetraoxide derivative as a monofluoromethyl group introduction agent that is effective as an intermediate in pharmaceutical and agrochemical synthesis, a production method thereof, and a production method of a monofluoromethyl group-containing compound using this 2-fluoro-1,3-benzodithiol 1,1,3,3-tetraoxide derivative are provided. The 2-fluoro-1,3-benzodithiol 1,1,3,3-tetraoxide derivative represented by the following general formula (1) (wherein R 1 , R 2 , R 3 , and R 4 each independently represent a hydrogen atom, a straight-chain or branched alkyl group having 1 to 4 carbon atoms, a straight-chain or branched alkyloxy group having 1 to 4 carbon atoms, a halogen atom, a nitro group, or a cyano group), the production method thereof, and various monofluoromethyl group-containing compounds are manufactured using this 2-fluoro-1,3-benzodithiol 1,1,3,3-tetraoxide derivative as a monofluoromethylating agent.
专利号:US-10829464-B2 优先权日:2016-11-23 标题 :Benzoheterocyclic alkylamine compounds and use thereof 发明人:LI JIAN; LAN LEFU; LI BAOLI; CHEN FEIFEI; NI SHUAISHUAI; LIU YIFU; WEI HANWEN; MAO FEI; ZHU JIN 权利人:UNIV EAST CHINA SCIENCE & TECH; SHANGHAI INST MATERIA MEDICA CAS 摘要:Disclosed are benzoheterocyclic alkylamine compounds, or a pharmaceutically acceptable salt thereof, or a stereoisomer thereof, and a preparation method thereof, and use of the same in the manufacture of an antibacterial drug as an inhibitor of staphyloxanthin synthesis in Staphylococcus aureus .
专利号:CN-117466815-A 优先权日:2023-07-27 标题 :A kind of synthesis method of azathrone compounds