CAS: 2162-98-3; 1,10-Dichlorodecane

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癸烷置于氯体系中,化学反应生成1,10-二氯癸烷
参考文献:多氯代烷烃混合物的表征-蒙特卡洛建模方法.
标题:多氯代烷烃混合物的表征-蒙特卡洛建模方法.
摘要:建立了蒙特卡洛模型以表征多氯代烷烃混合物的分子组成.该模型基于自由基氯化过程的模拟,该过程通过工业上由正构烷烃生产多氯烷混合物.在该模型中,通过随机选择部分转化的烷烃分子上受氯自由基攻击的目标位置来模拟自由基氯化反应.通过实验确定或根据实验结果外推确定烷烃链上氢原子对氯自由基取代的相对反应性.模拟的结果是对任何pca混合物的详细分子组成的预测.将模型预测的分子分布与实际pca混合物的分析确定分布进行比较时,发现了很好的一致性.然后,将模型的结果与描述生物酶作用的规则相结合,以估计pca混合物有氧生物降解的上限.
Doi:10.1007/s10532-007-9099-5

专利信息

专利号:US-8258362-B2
优先权日:2009-05-04
标 题:Method for the production of α, ω-olefins by using the copper catalyzed coupling reaction of a Grignard reagent with an allylic substrate
发明人：NACHARAJU KRISHNAMURTHY; TAYLOR PAUL D; COONEY MARK J; CRABTREE LARRY A
权利人:NACHARAJU KRISHNAMURTHY; TAYLOR PAUL D; COONEY MARK J; CRABTREE LARRY A; ISP INVESTMENTS INC
摘要:A process for the synthesis of linear α,ω-diolefins from an allylic substrate comprises the steps of a) forming the bis-Grignard reagent XMgCH2(CH2)nCH2MgX from an α,ω-acyclic dihalide with X being a halogen; b) preparing a solution comprising an allylic substrate and a copper catalyst; c) catalyzing a coupling reaction by adding to the solution of step (b) the bis-Grignard reagent of step (a); and d) isolating and purifying the α,ω-olefin coupling reaction product.

专利号:US-7038072-B2
优先权日:2002-07-24
标 题 :Process for monoalkylation of C-H acidic methylene groups
发明人：BODMANN KERSTIN; MEYER OLIVER; KAUFHOLD MANFRED; FIEKER JUERGEN; PAULCZYNSKI RENATE
权利人:DEGUSSA
摘要:The present invention is directed to a process for the synthesis of monoalkylated C—H acidic methylene group-containing compounds, such as malonic esters, and malonic ester nitriles.

专利号:WO-2021013997-A1
优先权日:2019-07-25
标 题:Process for the synthesis of n-alkyl-4-pyridinamines

专利号:ES-2980492-T3
优先权日:2019-07-25
标 题:Procedure for the synthesis of N-alkyl-4-pyridinamines

专利号:EP-4003957-B1
优先权日:2019-07-25
标 题 :Process for the synthesis of n-alkyl-4-pyridinamines
发明人：CONTRERAS LASCORZ JUAN; DURà N LÓPEZ ERNESTO
权利人:MEDICHEM SA

专利号:CN-117229185-A
优先权日:2023-11-14
标 题:Synthesis of a creamy asphalt anti-aging agent and its use method