CAS: 1762-34-1; 5,5'-Dimethyl-2,2'-Bipyridine

该化合物是双丙烯家族的有机化合物,其特点是存在两个由碳-碳联结连接的双丙烯环;该化合物的特点是,每个环的5个位置上附着两个甲基组,影响其化学特性和反应力;该物质一般在室温下是固体,在乙醇和丙酮等有机溶剂中溶解,但由于其水分恐惧性,在水体中溶解程度较低;这些甲基组的存在会增加其晶体,从而影响其协调化学,使其在各种金属综合体中成为有用的离子. 5,5,5欧元-二甲基-2,2欧元-双丙烯,由于能够稳定金属离子和促进电子转移过程,经常用于化学协调,催化和材料科学.此外,它可能展示有趣的光物理特性,使其与有机发光二极管(OLEDs)开发和其他直观电子应用有关.

结构式图片

相似化合物

56100-20-0 162318-34-5 1802-29-5

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合成工艺路线路线简述

    2-羟基-5-甲基嘧啶置于三溴化磷,铜体系中,化学反应生成5 5'-二甲基-2,2'-二吡啶
    参考文献:The Synthesis Of Certain Substituted 2,2'-Bipyridyls1
    标题:The Synthesis Of Certain Substituted 2,2'-Bipyridyls1
    摘要:
    Doi:10.1021/ja01216A045

    海关参考信息

    专利信息


    专利号:US-8153839-B2
    优先权日:2005-09-14
    标题:Method for synthesis of keto acids or amino acids by hydration of acetylene compound
    发明人:OGO SEIJI; FUKUZUMI SHUN-ICHI
    权利人:OGO SEIJI; FUKUZUMI SHUN-ICHI; JAPAN SCIENCE & TECH AGENCY
    摘要:An object of the present invention is to provide a method for synthesis of keto acids by hydration of an acetylene compound (acetylene-carboxylic acids) under mild conditions free from harmful mercury catalysts and a method for synthesis of amino acids from acetylene-carboxylic acids in a single container (one-pot or tandem synthesis). In one embodiment of the method according to the present invention for synthesis of keto acids, acetylene-carboxylic acids is hydrated in the presence of a metal salt represented by General Formula (1), n nwhere M 1 represents an element in Group VIII, IX, or X of the periodic table, and X 1 , X 2 , or X 3 ligand represents halogen, H 2 O, or a solvent molecule, and k represents a valence of a cation species, and Y represents an anion species, and L represents a valence of the anion species, and each of K and L independently represents 1 or 2, and k×m=L×n.

    专利号:US-2021107859-A1
    优先权日:2018-04-06
    标题 :A process for the synthesis of carbon labeled organic compounds
    发明人:AUDISIO DAVIDE; CANTAT THIBAULT; DESTRO GIANLUCA
    权利人:COMMISSARIAT ENERGIE ATOMIQUE
    摘要:A process for the synthesis of a carbon labeled organic compound containing a carbon labeled carboxyl group is described. A method of using carbon labeled organic compounds containing a carbon labeled carboxyl group according to the present disclosure; a process for manufacturing labeled pharmaceuticals and agrochemicals comprising synthesis of carbon labeled organic compounds containing a carbon labeled carboxyl group according to the present disclosure; and a process for producing tracers comprising synthesis of carbon labeled organic compounds containing a carbon labeled carboxyl group according to the present disclosure are also described.

    专利号:EP-3549927-A1
    优先权日:2018-04-06
    标 题:A process for the synthesis of carbon labeled organic compounds

    专利号:WO-2019193068-A1
    优先权日:2018-04-06
    标 题:A process for the synthesis of carbon labeled organic compounds

    专利号:US-8951400-B2
    优先权日:2007-10-17
    标题:Chemistry used in biosensors
    发明人:AHRENS MICHAEL; BERTIN PAUL A; GRAY HARRY B; MEADE THOMAS J
    权利人:AHRENS MICHAEL; BERTIN PAUL A; GRAY HARRY B; MEADE THOMAS J; OHMX CORP
    摘要:The invention relates to novel compositions of disubstituted bipyridyl osmium complexes useful for the synthesis of labeled proteins, nucleic acids, and for the modification of electrodes.

    专利号:US-9884316-B2
    优先权日:2014-03-10
    标题:Mononuclear ruthenium complex and organic synthesis reaction using same
    发明人:NAGASHIMA HIDEO; SUNADA YUSUKE; OGUSHI HAJIME; SAKUTA KOJI
    权利人:UNIV KYUSHU NAT UNIV CORP; SHINETSU CHEMICAL CO
    摘要:A neutral or cationic mononuclear ruthenium divalent complex represented by formula (1) can actualize exceptional catalytic activity in at least one reaction among a hydrosilylation reaction, hydrogenation reaction, and carbonyl compound reduction reaction. n n(In the formula, R 1 -R 6 each independently represent a hydrogen atom or an alkyl group, aryl group, aralkyl group, organooxy group, monoorganoamino group, diorganoamino group, monoorganophosphino group, diorganophosphino group, monoorganosilyl group, diorganosilyl group, triorganosilyl group, or organothio group optionally substituted by X; at least one pair comprising any of R 1 -R 3 and any of R 4 -R 6 together represents a crosslinkable substituent; X represents a halogen atom, organooxy group, monoorganoamino group, diorganoamino group, or organothio group; L each independently represent a two-electron ligand other than CO and thiourea ligands; two L may bond to each other; and m represents an integer of 3 or 4.)
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    主要参考文献


    1: Woods AD, Porter CL, Feldman SR. Abametapir for the Treatment of Head Lice: A Drug Review. Ann Pharmacother. 2022 Mar;56(3):352-357. doi: 10.1177/10600280211027968. Epub 2021 Jun 22. 106(1):91-92. 33(4):410-415. doi: 10.1097/MOP.0000000000001031. 35(5):616-621. doi: 10.1111/pde.13612. Epub 2018 Jul 12.
    5: Bowles VM, Yoon KS, Barker SC, Tran C, Rhodes C, Clark MJ. Ovicidal Efficacy of Abametapir Against Eggs of Human Head and Body Lice (Anoplura: Pediculidae). J Med Entomol. 2017 Jan;54(1):167-172. doi: 10.1093/jme/tjw132. Epub 2016 Aug 21. Erratum in: J Med Entomol. 2017 Jan 1;54(1):248.
    6: Bowles VM, Hanegraaf S, Ahveninen T, Sidgiddi S, Allenby K, Alsop H. Effect of a New Head Lice Treatment, Abametapir Lotion, 0.74%, on Louse Eggs: A Randomized, Double-Blind Study. Glob Pediatr Health. 2019 Feb 22;6:2333794X19831295. doi: 10.1177/2333794X19831295.

    合成参考文献


    参考文献:10.1107/s1600536811010579
    摘要:Ji L, Liu J, Song W. Bis(2,4-dichlorophenoxyacetato-κ2O1,O1′)(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)cobalt(II). Acta Crystallogr E Struct Rep Online. 2011 Mar 26;67(4):m493. doi: 10.1107/s1600536811010579.
    参考文献:10.1107/s1600536811011305
    摘要:Phatchimkun J, Chaichit N. Diazidobis(5,5′-dimethyl-2,2′-bipyridyl-κ2N,N′)cobalt(II) monohydrate. Acta Crystallogr E Struct Rep Online. 2011 Mar 31;67(4):m516–7. doi: 10.1107/s1600536811011305.
    参考文献:10.1107/s1600536811013353
    摘要:Ji L, Liu J, Song W. (5,5′-Dimethyl-2,2′-bipyridine-κ2N,N′)(1-naphthylacetato-κO)(1-naphthylacetato-κ2O,O′)zinc hemihydrate. Acta Crystallogr E Struct Rep Online. 2011 Apr 16;67(5):m606. doi: 10.1107/s1600536811013353.
    参考文献:10.1107/s1600536811014085
    摘要:Lundvall F, Wragg DS, Tilset M. (5,5'-Dimethyl-2,2'-bipyridine)-iodido-trimethyl-platinum(IV). Acta Crystallogr Sect E Struct Rep Online. 2011 May 01;67(Pt 5):m617–8.
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