专利号:US-4970309-A 优先权日:1985-12-16 标题:Synthesis of thiolactones 发明人:KING PATRICK F 权利人:POLAROID CORP 摘要:This invention relates to a novel method of synthesizing di- and triarylmethane dye precursor compounds possessing a thiolactone ring-closing moiety, from the corresponding lactones.
专利号:US-4678613-A 优先权日:1981-12-09 标题:Process for the purification of triphenylmethane compounds 发明人:FLORES ROBERT J 权利人:PMC SPECIALTIES GROUP INC 摘要:Triphenylmethane dyes are obtained in a purified or more concentrated condition which eliminates the excess aromatic amines and by-products obtained during the synthesis of the triphenylmethane dyes. These purified triphenylmethane dyes show special utility when used in combination with an electron acceptor (Lewis acid) to produce carbonless copy paper or when used as reactants in the manufacture of other dyes.
专利号:US-4448446-A 优先权日:1981-12-09 标题:Process for the purification of triphenylmethane compounds and pressure sensitive copysheet containing same 发明人:FLORES ROBERT J 权利人:SHERWIN WILLIAMS CO 摘要:Triphenylmethane dyes are obtained in a purified or more concentrated condition which eliminates the excess aromatic amines and by-products obtained during the synthesis of the triphenylmethane dyes. These purified triphenylmethane dyes show special utility when used in combination with an electron acceptor (Lewis acid) to produce carbonless copy paper or when used as reactants in the manufacture of other dyes.
专利号:US-7071145-B2 优先权日:2001-09-25 标 题:Thermosensitive recording material, and synthesis method of oligomer composition for the recording material 发明人:MORITA MITSUNOBU; HAYAKAWA KUNIO; TORII MASAFUMI; NARUSE MITSURU 权利人:RICOH KK 摘要:A thermosensitive recording material comprising a thermosensitive layer provided on a substrate, and the thermosensitive layer comprises as main ingredients a leuco dye and a developer to make colored state of said leuco dye when heated, wherein the developer is an oligomer composition obtained from the reaction of a polyvalent isocyanate compound represented by following Formula (I) with an aromatic amine represented by following Formula (II); n nwhere X represents a try- or more-valent group, a represents an integer numeral of 3 or more, b and c represent respectively integer numerals in the range of 0 to 5 and they satisfy a relation of b+c=1 to 5, Z represents hydrogen atom, alkyl group, allyl group or aryl group, and the aryl group may include condensed ling structure thereof, and d represents an integer numeral in the range of 0 to 4. This developer shows excellent reliabilities of both image and background area, and also shows an excellent color-developing characteristics (color developing sensitivity and image density).
专利号:CN-103351108-A 优先权日:2013-07-12 标题 :Synthesis of Concrete Water Reducer from Emissions and By-products in the Production of Diarylethanes
专利号:US-8288313-B2 优先权日:2007-02-14 标 题:Thermal recording material 发明人:IKEZAWA YOSHIMI 权利人:IKEZAWA YOSHIMI; MITSUBISHI PAPER MILLS LTD 摘要:A thermal recording material comprises a support and a thermal recording layer formed thereon, the thermal recording layer containing an electron-donating dye precursor and an electron-receiving developer that causes said dye precursor to develop a color, wherein said thermal recording layer contains vapor-phase synthesis silica, preferably, the vapor-phase synthesis silica has a specific surface area, measured by a BET method, of 50 to 200 m 2 /g and further is doped with aluminum oxide, and the thermal recording layer further contains the above vapor-phase synthesis silica and a diphenyl sulfones-bridged type compound, and the thermal recording material is excellent in anti-sticking property and image stability.
[参考文献]: Kunihiro Ichimura, Et Al. Solid Phase Adsorption Of Crystal Violet Lactone On Silica Nanoparticles To Probe Mechanochemical Surface Modification. Langmuir. 2008 Jun 1;24(13):6470-9. [参考文献]: P N Whitehead, Et Al. Dermatitis From Crystal Violet. Contact Dermatitis. 1988 Aug;19(2):141-2. [参考文献]: S A Shehade, Et Al. Allergic Contact Dermatitis To Crystal Violet Lactone [参考文献]: Uli Schmidhammer, Et Al. The Key Role Of Solvation Dynamics In Intramolecular Electron Transfer: Time-Resolved Photophysics Of Crystal Violet Lactone. J Phys Chem A. 2008 Sep 18;112(37):8487-96. [参考文献]: Xiang Li, Et Al. Solvent-Controlled Electron Transfer In Crystal Violet Lactone. J Phys Chem A. 2011 Apr 28;115(16):3746-54.
合成参考文献
摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198 参考文献:10.1021/la8002178 摘要:Ichimura K, Funabiki A, Aoki K, Akiyama H. Solid phase adsorption of crystal violet lactone on silica nanoparticles to probe mechanochemical surface modification. Langmuir. 2008 Jun 01;24(13):6470–9. doi: 10.1021/la8002178.