1,3-二苯基丙烷三酮置于磷酸体系中,化学反应生成安息香精油 参考文献:Schoenberg; Azzam,Journal Of The Chemical Society,1939,P. 1428 标题:Schoenberg; Azzam,Journal Of The Chemical Society,1939,P. 1428
专利号:US-10801033-B2 优先权日:2016-04-05 标题 :Recombinant polynucleotide involved in lactone synthesis and process for synthesis of lactones thereof 发明人:GUPTA VIDYA SHRIKANT; DESHPANDE ASHISH BALWANT; OAK PRANJALI SUDHIR; GIRI ASHOK PRABHAKAR 权利人:COUNCIL SCIENT IND RES 摘要:The present invention provides the polynucleotide encoding enzyme involved in lactone synthesis and a process for synthesis of lactones using said polynucleotides. The invention also provides recombinant plasmid expression vector comprising said polynucleotide sequence. The recombinant protein encoded by said polynucleotides leads to synthesis of lactones having flavour peculiar to Alphonso mangoes.
专利号:US-6770436-B1 优先权日:1996-11-14 标题:Chemical amplification for the synthesis of patterned arrays 发明人:BEECHER JODY E; GOLDBERG MARTIN J; MCGALL GLENN H 权利人:AFFYMETRIX INC 摘要:Radiation-activated catalysts (RACs), autocatalytic reactions, and protective groups are employed to achieve a highly sensitive, high resolution, radiation directed combinatorial synthesis of pattern arrays of diverse polymers. When irradiated, RACs produce catalysts that can react with enhancers, such as those involved in autocatalytic reactions. The autocatalytic reactions produce at least one product that removes protecting groups from synthesis intermediates. This invention has a wide variety of applications and is particularly useful for the solid phase combinatorial synthesis of polymers.
专利号:WO-2024153642-A1 优先权日:2023-01-16 标题 :Scarless template-free enzymatic synthesis of polynucleotides 发明人:HORGAN ADRIAN; VERARDO DAMIANO; ADELIZZI BEATRICE; RODRIGUEZ-PINZON DANIEL; THOMEE EMMA 权利人:DNA SCRIPT 摘要:Methods are provided for template-free enzymatic synthesis of polynucleotides on a solid support using double cleavage to produce scarless polynucleotides. In particular, methods are disclosed that use an initiator that comprises a cleavable group, which can be cleaved by a small molecule chemical agent, adjusting pH, heat, or photocleaved by illumination with light to release polynucleotides from a solid support after enzymatic synthesis is completed, and an enzymatic cleavage site, which can be cleaved by a cleavage enzyme to remove polynucleotide scars.
专利号:US-6512081-B1 优先权日:1997-07-21 标题:Synthesis of dithioester chain transfer agents and use of bis(thioacyl) disulfides or dithioesters as chain transfer agents 发明人:RIZZARDO ENZIO; THANG SAN HOA; MOAD GRAEME 权利人:E I DUPONT NEMOURS AND COMPANY; COMMW SCIENT IND RES ORG 摘要:This invention relates to the synthesis of dithiocarboxylic acid esters by reaction of bis(thioacyl) disulphides, thioacetals or vinylidane bis(thioether) with free-radicals (optionally in the presence of monomers). The invention also relates to processes for the synthesis of polymers utilising these dithioesters as polymerisation regulators (chain transfer agents) or to the use of bis(thioacyl) disulphides to generate dithioester chain transfer agents in situ.
专利号:US-2003182068-A1 优先权日:2001-10-30 标 题 :Device and methods for directed synthesis of chemical libraries 发明人:BATTERSBY BRONWYN J; MILLER CHRISTOPHER R; TRAU MATHIAS; WAY JEFFERY C; JOHNSTON ANGUS 摘要:The invention features a sort computer which interfaces with a sorting device in order to control the sorting of beads on a bead by bead basis. The invention further features novel methods for the directed synthesis of encoded libraries of oligomers, e.g., oligonucleotides, on beads. These methods allow the synthesis of libraries that are sufficiently large to permit complex genomic analyses to be carried out. New methods of using the encoded libraries also are described.
专利号:US-9920160-B2 优先权日:2014-09-03 标题 :Method for synthesis of polymer containing multiple epoxy groups 发明人:GAO CHAO; ZHENG YAOCHEN; PENG LI; CAI SHENGYING; WENG ZHULIN 权利人:UNIV ZHEJIANG 摘要:A method for a synthesis of a polymer containing multiple epoxy groups includes steps of: under protection of nitrogen or argon, with a photosensitive free radical initiator under an ultraviolet light irradiation, initiating a mixture of a dithiol compound and alkynyl glycidyl ether or other alkynyl-containing compounds to proceed a thiol-yne polymerization, so as to obtain the polymer. The number of the epoxy groups is able to be adjusted through changing a type of a dithiol monomer, a mixing ratio of the dithiol monomer, and a mixing ratio between the alkynyl glycidyl ether and other alkynyl compounds. The present invention has advantages of: fast reaction, convenient process, easy post-processing, a large number of the epoxy groups, and adjustable and controllable content. The obtained polymer has a wide potential application in fields of coating, adhesive, ink, encapsulating material, resin for composite material, additive, high performance material, function material, and so on.
[参考文献]: Compound Summary. Benzoin [参考文献]: B Thanuja, Et Al. Ultrasonic Studies Of Intermolecular Interactions In Binary Mixtures Of 4-Methoxy Benzoin With Various Solvents: Excess Molar Functions Of Ultrasonic Parameters At Different Concentrations And In Different Solvents. Ultrason Sonochem. 2012 Nov;19(6):1213-20. [参考文献]: Hayk Mnatsakanyan, Et Al. Controlled Assembly Of Fibronectin Nanofibrils Triggered By Random Copolymer Chemistry. Acs Appl Mater Interfaces. 2015 Aug 19;7(32):18125-35. [参考文献]: Lung Wa Chung, Et Al. The Oniom Method And Its Applications. Chem Rev. 2015 Jun 24;115(12):5678-796. [参考文献]: M S El-Shahawi, Et Al. Spectroscopic And Electrochemical Characterization Of Some Schiff Base Metal Complexes Containing Benzoin Moiety. Spectrochim Acta A Mol Biomol Spectrosc. 2013 Sep:113:459-65.
合成参考文献
参考文献:10.1002/elps.200900508 摘要:Luces CA, Warner IM. Achiral and chiral separations using MEKC, polyelectrolyte multilayer coatings, and mixed mode separation techniques with molecular micelles. Electrophoresis. 2010 Mar;31(6):1036–43. 参考文献:10.1021/ar2000716 摘要:Biju AT, Kuhl N, Glorius F. Extending NHC-catalysis: coupling aldehydes with unconventional reaction partners. Acc Chem Res. 2011 Nov 15;44(11):1182–95. doi: 10.1021/ar2000716. 参考文献:10.1107/s1600536811014541 摘要:Betz R, McCleland C, Hosten E. 2-Chloro-1,2-diphenyl-ethanone (desyl chloride). Acta Crystallogr Sect E Struct Rep Online. 2011 May 01;67(Pt 5):o1199. 参考文献:10.1107/s1600536811015960 摘要:Arslan H, Algul O, Zirek S, Tari O, Demircan A, Hardcastle KI. 2-(4-Meth-oxy-2-methyl-anilino)-1,2-diphenyl-ethanone. Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 01;67(Pt 6):o1303. 参考文献:10.1107/s1600536811019532 摘要:Nithya G, Thanuja B, Chakkaravarthi G, Kanagam CC. 2'-Chloro-4-meth-oxy-3-nitro-benzil. Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 01;67(Pt 6):o1535.