CAS: 942615-32-9; 4-Bromo-9,9-Dimethyl-9H-Fluorene

该化合物是一种溴化氟化物衍生物,其特点是在9位置使用二甲基替代,这增强了消毒稳定性并影响电子特性;该化合物是有机合成的多种中间体,特别是在准备同质聚合物,光电子材料和催化系统离心器时; 4位置的溴替代物通过交叉反应,如铃木或Stille联动,促进进一步功能化,从而进行精确的结构改造; 其硬性氟化物核心有助于高热力和化学稳定性,使之适合于先进材料科学的应用; 化合物通常供应纯度高,确保合成工作流程的一贯性.

英文名称4-Bromo-9,9-Dimethyl-9H-Fluorene
中文名称4-溴-9,9-二甲基芴
IUPAC名称4-bromo-9,9-dimethyl-9H-fluorene
其它别名4-Bromo-9,9'-Dimethylfluorene; 4-Bromo-9,9-Dimethylfluorene; 4-Bromo-9,9-Dimethyl-Fluorene; 4-Bromo-9,9-Dimethylfluorene, ; 4-Bromo-9,9-Dimethyl-9H-Fluorene
CAS编号942615-32-9
MFCD编号:MFCD23099415
EINECS号:807-998-4
分子式:C15H13Br
分子量:273.17
产品CID: 1992166
产品分类生物 → ELISA 试剂盒

相似结构搜索
InChIKey: SXOUNESKHJIXNK-UHFFFAOYSA-N
InChI=1S/C15H13Br/c1-15(2)11-7-4-3-6-10(11)14-12(15)8-5-9-13(14)16/h3-9H,1-2H3…
计算化学: 氢键受体数0.0氢键供体数0.0可旋转键数0.0

MSDS等安全信息

GHS象形图
GHS符号GHS07;
注释: Exclamation mark
危险类别特定目标器官毒性 - 单次接触类别3
皮肤腐蚀/刺激类别2
严重眼刺激类别2
警示词Warning(警告)
危险描述H335 |可能引起呼吸道刺激.
H315 |造成皮肤刺激.
H319 |造成严重眼刺激.
防范说明P261-P280a-P304+P340-P305+P351+P338-P405-P501a
危险品标志Xi

欧盟法规

REACH注册ECHA物质C&L通报

合成工艺路线路线简述

13029-09-9 = 942615-32-9
反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; 1 H,-78 °C; 1 H,-70 °C1.2 Solvents: Tetrahydrofuran; -70 °C; -70 °C -> Rt1.3 Reagents: Ammonium Chloride Solvents: Water; Rt1.4 Reagents: Hydrochloric Acid Solvents: Acetic Acid,Water; 4 H,75 °C
标题:Six-Five-Six Condensed Cyclic Compound Derivatives And Mixtures Containing Them And Their Use In Organic Electronic Devices And The Devices
参考文献:World Intellectual Property Organization]

1000071-27-1 = 942615-32-9
反应条件:1.1 Solvents: Tetrahydrofuran; 0 °C; 3 H,Rt1.2 Reagents: Hydrochloric Acid Solvents: Water; 30 Min,0 °C1.3 Reagents: Acetic Acid,Hydrochloric Acid Solvents: Water; 10 H,Reflux1.4 Solvents: Water; 30 Min,Reflux
标题:Fused Ring Organic Light-Emitting Compound For Organic Light-Emitting Device
参考文献:Korea]

13029-09-9 = 942615-32-9
反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; -78 °C; 1 H,-70 °C1.2 Solvents: Tetrahydrofuran; -70 °C; -70 °C -> Rt1.3 Reagents: Ammonium Chloride Solvents: Water; Rt1.4 Reagents: Acetic Acid,Hydrochloric Acid; 4 H,Rt -> 75 °C
标题:Carbazole Derivatives,Mixtures Containing Them,And Organic Electronic Devices Using Them
参考文献:World Intellectual Property Organization]

13029-09-9 = 942615-32-9
反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; -78 °C; 1 H,-70 °C1.2 Solvents: Tetrahydrofuran; -70 °C; -70 °C -> Rt1.3 Reagents: Ammonium Chloride Solvents: Water; Rt1.4 Reagents: Acetic Acid,Hydrochloric Acid; 6 H,75 °C
标题:Amine Derivatives,Mixtures Containing Them,And Organic Electronic Devices Using Them
参考文献:World Intellectual Property Organization]

13029-09-9 = 942615-32-9
反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; 1 H,-78 °C; 1 H,-70 °C1.2 Solvents: Tetrahydrofuran; -70 °C; -70 °C -> Rt1.3 Reagents: Ammonium Chloride; Rt1.4 Reagents: Acetic Acid,Hydrochloric Acid; Rt; Rt -> 75 °C; 4 H,75 °C
标题:Compounds Having Fluorene-Like Structures And Their Production And Use In Electronic Devices
参考文献:World Intellectual Property Organization]

13029-09-9 = 942615-32-9
反应条件:1.1 Reagents: Butyllithium Solvents: Dimethylformamide,Tetrahydrofuran; 1 H,-78 °C; 1 H,-70 °C1.2 Solvents: Tetrahydrofuran; -70 °C; -70 °C -> Rt1.3 Reagents: Ammonium Chloride; Rt
标题:Matrix Materials For Fluorescent Or Phosphorescent Emitters For Organic Electroluminescent Devices
参考文献:World Intellectual Property Organization]

13029-09-9 = 942615-32-9
反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; -78 °C; 1 H,-70 °C1.2 Solvents: Tetrahydrofuran; -70 °C; -70 °C -> Rt1.3 Reagents: Ammonium Chloride Solvents: Water; Rt1.4 Reagents: Acetic Acid,Hydrochloric Acid Solvents: Water; Rt -> 75 °C; 4 H,75 °C
标题:Fluorene Compounds And Organic Electronic Devices
参考文献:World Intellectual Property Organization]

2425805-73-6 = 942615-32-9
反应条件:1.1 Reagents: Triphenylphosphine Solvents: 1,2-Dichlorobenzene; Reflux
标题:Compound With Dibenzocycloheptene As Core And Its Application In Organic Light-Emitting Device
参考文献:China]

13029-09-9 = 942615-32-9
反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran; -78 °C; 2 H,-78 °C1.2 Solvents: Tetrahydrofuran; -78 °C; -78 °C -> Rt1.3 Reagents: Hydrochloric Acid Solvents: Acetic Acid,Water; 120 °C
标题:Cyclopentafluorene Compound As Electroluminescent Material And/or Organic Semiconductor Materials For Organic Light Emitting Device (Oled)
参考文献:Korea]

= 942615-32-9 [标题:Reaction Conditions
标题:Preparation Of Aromatic Amines For Organic Electric Device
参考文献:Korea]

= 942615-32-9 [标题:Reaction Conditions
标题:Preparation Of 9,9-Spirobifluorene Compound And Application In Oled
参考文献:China