CAS: 764-60-3; Hex-2-Yn-1-Ol

该化合物是含有分子式C6H10O的烷醇,以终端氢氧基组和二碳三联为主,该化合物主要用作有机合成的中间体,特别是在生产药品,农用化学品和特殊化学品方面;其反应性烷基和氢氧基功能能够进行多种变异,包括组合反应和衍生.该化合物的界定明确的结构和高纯度使其适合精确的合成应用.由于在受控条件下的稳定性,2-Hexyn-1-ol是研究人员和工业化学家寻求开发复杂分子结构的可靠建筑块.

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5921-73-3 14916-80-4 764-33-0

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上下游产品

CAS号18937-79-6 2-己炔甲酯 | CAS号106-94-5 溴代丙烷 | CAS号107-19-7 丙炔醇 | CAS号6089-04-9 哌喃 | CAS号50-00-0 甲醛 | CAS号627-19-0 1-戊炔 | CAS号7782-61-8 硝酸铁(九水) | CAS号88517-97-9 2-hex-2-ynoxyoxane | CAS号6261-21-8 2-pent-2-ynylox... | CAS号37657-97-9 1-(1-ethoxy-eth... | CAS号104506-68-5 hex-2-yn-1-ol,m... | CAS号928-90-5 5-己炔-1-醇 | CAS号928-94-9 顺-2-已烯-1-醇 | CAS号111-27-3 正己醇 | CAS号928-95-0 反式-2-己烯-1-醇 | CAS号18495-25-5 1-溴-2-己炔 | CAS号66-25-1 正己醛 | CAS号77758-51-1 5-己炔酸甲酯 | CAS号29898-25-7 1-苯基-3-己酮 | CAS号53293-00-8 5-己炔酸

合成工艺路线路线简述

    📜2-(Hex-2-Yn-1-yl)Tetrahydropyrane置于甲醇体系中,化学反应生成 2-己炔-1-醇
    参考文献:通过同源混合物的组合合成构建挥发性化合物的化学文库:Alk-4-En-1-Ols,Alk-4-Enals 和 Methyl Alk-4-Enoates
    标题:通过同源混合物的组合合成构建挥发性化合物的化学文库:Alk-4-En-1-Ols,Alk-4-Enals 和 Methyl Alk-4-Enoates
    摘要:包含 66 个线性化合物的化合物库,六个分子家族的 11 个代表:(E)-和 (Z)-Alk-4-En-1-Ols,Alk-4-Enals 和甲基 Alk-4-Enoates 的异构体,是通过组合合成制备的,以允许创建直接可用于在 Gc/ms 分析中识别它们的质谱数据库.我们在这里证明化合物库可以通过使用长线性合成序列的组合合成来制备,即.即,在 4-Enals 的情况下为八步.由此产生的同系物混合物仍然可以完美地用于提供所需的信息,例如干净的质谱和非常好的气相色谱保留指数.
    DOI:10.1002/cbdv.202200817

    海关参考信息

    专利信息


    专利号:US-5446203-A
    优先权日:1992-08-25
    标题:Synthesis of haloenones and aryl or alkyl substituted enones or alkenes
    发明人：MCNELIS EDWARD
    权利人:UNIV NEW YORK
    摘要:Alternative methods for synthesizing haloenones and haloakenes and their use as starting materials for synthesis of substituted or unsubstituted alkyl and aryl substituted enones and alkenes, including tamoxifen and tamoxifen analogs, using such haloenones and haloalkenes.

    专利号:US-3978100-A
    优先权日:1973-04-18
    标题:Allenic esters, process for preparation thereof and process for rearrangement thereof
    发明人：FUJITA YOSHIJI; OMURA YOSHIAKI; HISHIDA TAKASHI; ITOI KAZUO
    权利人:KURARAY CO
    摘要:Allenic esters of the formula: ##EQU1## (specific examples of R, R 1 , R 2 , R 3 and R 4 are given) and a process for the preparation thereof which comprises reacting propargyl alcohol derivatives with 2-substituted ortho-acetic acid esters in the presence of an acidic catalyst. These allenic esters are rearranged in the presence of an alkali catalyst to form α, β, γ, δ-unsaturated carboxylic acid esters and are useful as intermediates in the synthesis of various perfumes, medicines, agricultural chemicals and the like.

    专利号:US-4158672-A
    优先权日:1976-01-26
    标题 :Polyfluoroalkylthio alcohols, esters and useful compositions therefrom
    发明人：DEAR ROBERT E A; BRACE NEAL O
    权利人:CIBA GEIGY CORP
    摘要:Polyfluoroalkylthio alcohols and esters thereof are disclosed with utility as intermediates for the synthesis of fluorochemicals with low free surface energies having oil and water repellent properties. The novel alcohols and esters are obtained by a free radical catalyzed addition of polyfluoroalkylthiols to acetylenic alcohols or esters thereof. The alcohols are employed in preparation of fluorine containing polyurethanes which are useful as finishes to provide oil and water repellency to textiles and as additives to plastics to provide mold release and other desirable properties.

    专利号:EP-0656878-A1
    优先权日:1992-08-25
    标题 :Synthesis of haloenones and aryl or alkyl substituted enones or alkenes

    专利号:WO-9405617-A1
    优先权日:1992-08-25
    标 题 :Synthesis of haloenones and aryl or alkyl substituted enones or alkenes

    专利号:EP-0656878-A4
    优先权日:1992-08-25
    标题:Synthesis of haloenones and aryl or alkyl substituted enones or alkenes.

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    合成参考文献


    摘要:Thieuleux, C.; Crozet, D., Science of Synthesis: N-Heterocyclic Carbenes in Catalytic Organic Synthesis, (2016) 2, 332.
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