CAS: 1471-03-0; 1-Prop-2-Enoxypropane

该化合物其结构特征为结构,包括附在丙质脊柱上的丙氧组,该化合物由于存在碳碳双联,因此被归类为烷,这有利于其活性及有机合成的潜在应用;源自丙诺醇的丙氧组可增强该化合物在有机溶剂中的溶解性,并可能影响其物理特性,如沸点和熔点. 3-丙天-1-丙烯通常是室内温度下无色液体,可能具有一种特异味,其反应可归因于双联,使其易于增加反应,这在烷中很常见.该化合物可用于各种化学工艺,包括聚合和作为合成更复杂的有机分子的中间体.在处理和储存时,应参考安全数据,如任何化学物质,以确保采取适当的防范措施.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

propan-1-ol 1-(prop-2-en-1-yl)-pyridinium bromide allyl iodid sodium n-propoxide 1-penten N-allylpiperidine trimethoxysilane allyltrimethoxysilane

合成工艺路线路线简述

    📜Magnesium N-Propoxide,3-溴丙烯 反应 48.0H,以94%的收率获得烯丙基正丙酯
    参考文献:由相应的烷氧基镁合成苄基/烯丙基烷基醚
    标题:由相应的烷氧基镁合成苄基/烯丙基烷基醚
    摘要:在碘的存在下,醇与镁反应生成烷氧基镁,然后将其用苄基氯或烯丙基溴处理以生成苄基烷基醚或烯丙基烷基醚.
    Doi:10.1016/0040-4039(96)01046-5

    海关参考信息

    专利信息


    专利号:US-4000358-A
    优先权日:1968-12-19
    标题:Unsaturated ester-amides of halogenated alkenes
    发明人:D ALELIO GAETANO F
    权利人:ALELIO GAETANO F D
    摘要:This invention deals with new unsaturated esteramides of alpha , beta -unsaturated polycarboxylic acids derived from halogenated alcohols of the formula wherein R is a divalent hydrocarbon moiety having at least one and no more than 10 carbon atoms, X is a member selected from the class of bromine and chlorine, and R' is a member selected from the class of hydrogen, X and a monovalent hydrocarbon containing at least one and no more than 20 carbon atoms. Typical esteramides are the maleates, fumarates, itaconates and citraconates. These monomers possess fire-retardant properties and are useful for the synthesis of polymers and copolymers.

    专利号:US-3796746-A
    优先权日:1968-12-19
    标题 :Unsaturated ester of halogenated alkenes
    发明人:D ALELIO G
    权利人:ALELIO G D
    摘要:THIS INVENTION DEALS WITH NEW UNSATURATED ESTERS OF A,B-UNSATURATED CARBOXYLIC ACIDS DERIVED FROM HALOGENATED ALCOHOLS OF THE FORMULAS HO-R-C(-X)=C(-X)-R'' AND HO-R-C(-X)2-C(-X)2-R'' WHEREIN R IS A DIVALENT HYDROCARBON MOIETY HAVING AT LEAST ONE AND NO MORE THAN 10 CARBON ATOMS, X IS A MEMBER SELECTED FROM THE CLASS OF OF BROMINE AND CHLORINE, AND R'' IS A MEMBER SELECTED FROM THE CLASS OF HYDROGEN, X AND A MOLOVALENT HYDROCARBON CONTAINING AT LEAST ONE AND NO MORE THAN 20 CARBON ATOMS. TYPICAL ESTERS ARE THE ACRYLATES, METHACRYLATES, MALEATES, FURMARATES, ITACONATES AND CINNAMATES. THE MONOMERS POSSESS FIRERETARDANT PROPERTIES AND ARE USEFUL FOR THE SYNTHESIS OF POLYMERS AND COPOLYMERS.

    专利号:US-3950392-A
    优先权日:1968-12-19
    标题:Unsaturated ester-amides of halogenated alkenes
    发明人:D ALELIO GAETANO F
    权利人:ALELIO GAETANO F D
    摘要:This invention deals with new unsaturated ester-amides of alpha , beta -unsaturated polycarboxylic acids derived from halogenated alcohols of the formula XX ¦¦ HO-R-C=C-R' wherein R is a divalent hydrocarbon moiety having at least one and no more than 10 carbon atoms, X is a member selected from the class of bromine and chlorine, and R' is a member selected from the class of hydrogen and a monovalent hydrocarbon containing at least one and no more than 20 carbon atoms. Typical ester-amides are the maleates, fumarates, itaconates and citraconates. These monomers possess fire-retardant properties and are useful for the synthesis of polymers and copolymers.

    专利号:US-3557063-A
    优先权日:1968-11-25
    标题:Crosslinkable polymers
    发明人:ALELIO GAETANO F D
    权利人:GAETANO F D ALELIO
    摘要:THIS INVENTION DEALS WITH A NEW ONE-STEP PROCESS OF PREPARING CROSSLINKABLE POLYMERS HAVING A PLURALITY OF REPEATING UNITS OF THE FORMULA -CH2-C(-R)(-COO-CH2-CH(-)-CH2(-) (-OOC-C(-R)=CH2),(-OOC- R''))- BY REACTING ANHYDRIDES OF THE FORMULA CH2=C(R)COOOCR'' WITH POLYMERS CONTAINING THE REPEATING UNIT OXIRANYL-CH2-OOC-C(-)(-R)-CH2- WHEREIN R REPRESENTS H AND CH3, THE NUMBER OF SUCH REPEATING UNITS IS AT LEAST 2, AND R'' REPRESENTS H, A HYDROCARBON GROUP CONTAINING ONE TO TWELVE CARBON ATOMS AND HALOGENATED DERIVATIVES THEREOF. THE PROCESS ALLOWS THE FACILE AND ECONOMICAL SYNTHESIS OF A LARGE NUMBER OF CROSSLINKABLE POLYMERS.

    专利号:US-5491167-A
    优先权日:1993-01-29
    标题 :Hexahydronaphthalene ester derivatives, their preparation and their therapeutic uses
    发明人:ISHIHARA SADAO; KOGEN HIROSHI; KOGA TEIICHIRO; KITAZAWA EIICHI; SERIZAWA NOBUFUSA
    权利人:SANKYO CO
    摘要:Compounds of formula (I): ##STR1## and their salts and esters have the ability to inhibit the synthesis of cholesterol, and can thus be used for the treatment and prophylaxis of hypercholesterolemia and of various cardiac disorders.

    专利号:US-7208554-B2
    优先权日:2004-04-07
    标题:Polyoxyalkylene phosphonates and improved process for their synthesis
    发明人:WO SHIMING; BAKER JOHN MARSHALL
    权利人:RHODIA
    摘要:A process for preparing polyoxyalkylene phosphonates in high yield and purity without extensive isolation procedures. The process also enables hydroxy terminated polyoxyalkylene phosphonates to be produced with their attendant high aqueous solubility and the availability of the reactive group to have the end functionality easily molecularly modified. Products produced by these processes have enhanced dispersion, coating, adhesion, and plasticizing characteristics as a result of the lack of any steric hinderance on these polyoxyalkylene phosphonates.

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    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Chen, P.; Liu, G.; Engle, K. M.; Yu, J.-Q., Science of Synthesis Knowledge Updates, (2013) 2, 85.
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