CAS: 89972-77-0; 4-(P-Tolyl)-2,2:6,2-Terpyridine

该化合物是有机化合物,其结构复杂,包括一个框架,具有有机化合物的特征.该化合物具有三根环状腺,在线性安排下连接,在终端位置之一以4-甲基苯替代.苯环上的甲基组的存在有助于其疏水特性,并能够影响其电子特性.据了解,其具有切热金属离子的能力,使这种化合物有可能用于化学和材料科学的协调.此外,由于芳香环的共振系统,该化合物可能具有令人感兴趣的光物理特性,例如荧光.其溶性和再活性可能因溶剂和条件而不同而不同,这对于有机合成和催化的应用非常重要.

结构式图片

相似化合物

58345-97-4 138253-30-2 209901-86-0

物理性质

MSDS等安全信息

欧盟法规

ECHA物质C&L通报

上下游产品

1-(2-oxo-2-(2-pyridyl)ethyl)pyridinium iodide (E)‐1‐(pyridin‐2‐yl)‐3‐(p‐tolyl)prop‐2‐en‐1‐one 1,5-di(2-pyridinyl)-3-p-tolylpentane-1,5-dione 2-acetylpyridine 4'-(4-bromomethylphenyl)-2,2':6',2''-terpyridine 4'-p-Tolyl-[2,2';6',2'']terpyridine 1,1''-dioxide 4'-(4-formylphenyl)-[2,2':6',2'']terpyridine diethyl 4-([2,2':6',2"-terpyridine]-4'-yl)benzylphosphonate

合成工艺路线路线简述

  • 104-87-0 + 1122-62-9 = 89972-77-0
    反应条件:1.1 Reagents: Potassium Hydroxide,Ammonia Solvents: Ethanol,Water; 24 H,34 °C
    标题:A Cu(Ii) Mof With A Flexible Bifunctionalised Terpyridine As An Efficient Catalyst For The Single-Pot Hydrocarboxylation Of Cyclohexane To Carboxylic Acid In Water/ionic Liquid Medium
    作者:Paul,Anup; Ribeiro,Ana P. C.; Karmakar,Anirban; Guedes Da Silva,M. Fatima C.; Pombeiro,Armando J. L.
    参考文献:Dalton Transactions 日期:2016 卷标:45(32) 页码:12779-12789]

    104-87-0 + 1122-62-9 = 89972-77-0
    反应条件:1.1 Reagents: Ammonium Acetate,Sodium Hydroxide Solvents: Ethanol,Water; Reflux
    标题:Zinc(Ii) Terpyridine Complexes: Substituent Effect On Photoluminescence,Antiproliferative Activity,And Dna Interaction
    作者:Li,Jiahe; Liu,Rongping; Jiang,Jinzhang; Liang,Xing; Huang,Ling; Et Al
    参考文献:Molecules 日期:2019 卷标:24(24)]

    209114-52-3 = 89972-77-0
    反应条件:1.1 Reagents: Ammonium Acetate Solvents: Methanol
    标题:Condensation Reactions Of 2-Acetylpyridine And Benzaldehydes: New Cyclohexanol Products And An Improved Synthesis Of 4'-P-Tolyl-2,2':6',2''-Terpyridine
    作者:Chamchoumis,Charles; Potvin,Pierre G.
    参考文献:Journal Of Chemical Research 日期:1998 卷标:(4) 页码:180-181]

    24582-66-9 + 2031122-00-4 = 89972-77-0
    反应条件:1.1 Reagents: Cesium Carbonate Solvents: Acetonitrile; 1 H,40 °C1.2 Reagents: Ammonium Acetate; 24 H,120 °C
    标题:One-Pot Reactions For Modular Synthesis Of Polysubstituted And Fused Pyridines
    作者:Song,Zhidong; Huang,Xin; Yi,Wenbin; Zhang,Wei
    参考文献:Organic Letters 日期:2016 卷标:18(21) 页码:5640-5643]

    104-87-0 + 1122-62-9 = 89972-77-0
    反应条件:1.1 Solvents: Ethanol; 10 Min,25 °C1.2 Reagents: Potassium Hydroxide,Ammonium Hydroxide Solvents: Ethanol,Water; 10 H,75 °C
    标题:Mechanistic Insights Into Co2 Conversion Chemistry Of Copper Bis-(Terpyridine) Molecular Electrocatalyst Using Accessible Operando Spectrochemistry
    作者:Zhang,Huihui; Xu,Chang; Zhan,Xiaowen; Yu,Yu; Zhang,Kaifu; Et Al
    参考文献:Nature Communications 日期:2022 卷标:13(1)]

    158014-83-6 + 26482-00-8 = 89972-77-0
    反应条件:1.1 Solvents: Methanol; 24 H,Reflux
    标题:Znii-2,2':6',2''-Terpyridine-Based Complex As Fluorescent Chemosensor For Ppi,Amp And Adp
    作者:Das,Priyadip; Ghosh,Amrita; Kesharwani,Manoj K.; Ramu,Vadde; Ganguly,Bishwajit; Et Al
    参考文献:European Journal Of Inorganic Chemistry 日期:2011 卷标:2011(20) 页码:3050-3058]

    104-87-0 + 1122-62-9 = 89972-77-0
    反应条件:1.1 Reagents: Ammonium Acetate Solvents: Ethylene Glycol; 5 - 9 Min
    标题:A Convenient One-Pot Synthesis Of 4'-Aryl-2,2':6',2''-Terpyridines And 2,4,6-Triarylpyridines Under Microwave Irradiation
    作者:Tu,Shujiang; Li,Tuanjie; Shi,Feng; Wang,Qian; Zhang,Jinpeng; Et Al
    参考文献:Synthesis 日期:2005 卷标:(18) 页码:3045-3050]

    104-87-0 + 1122-62-9 = 89972-77-0
    反应条件:1.1 Reagents: Ammonium Acetate; 5 - 9 Min,Heated
    标题:An Efficient Improve For The Kroehnke Reaction: One-Pot Synthesis Of 2,4,6-Triarylpyridines Using Raw Materials Under Microwave Irradiation
    作者:Tu,Shujiang; Li,Tuanjie; Shi,Feng; Fang,Fang; Zhu,Songlei; Et Al
    参考文献:Chemistry Letters 日期:2005 卷标:34(5) 页码:732-733]

    104-87-0 + 1122-62-9 = 89972-77-0
    反应条件:1.1 Reagents: Sodium Hydroxide; 30 Min,Rt1.2 Reagents: Ammonium Acetate Solvents: Acetic Acid; 2 H,Reflux
    标题:Chromium(Iii) Bis-Arylterpyridyl Complexes With Enhanced Visible Absorption Via Incorporation Of Intraligand Charge-Transfer Transitions
    作者:Barbour,Johanna C.; Kim,Amy J. I.; Devries,Elsemarie; Shaner,Sarah E.; Lovaasen,Benjamin M.
    参考文献:Inorganic Chemistry 日期:2017 卷标:56(14) 页码:8212-8222]

    104-87-0 + 1122-62-9 = 89972-77-0
    反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Water; 8 H,Rt; 8 H,80 °C1.2 Reagents: Ammonium Acetate Solvents: Ethanol; 5 H,Reflux
    标题:Synthesis,Structures,And Optical Properties Of Two Novel Two-Photon Initiators Derived From 2,2':6',2''-Terpyridine
    作者:Hu,Zhang-Jun; Yang,Jia-Xiang; Tian,Yu-Peng; Tao,Xu-Tang; Tian,Lei; Et Al
    参考文献:Bulletin Of The Chemical Society Of Japan 日期:2007 卷标:80(5) 页码:986-993]

    209114-52-3 = 89972-77-0
    反应条件:1.1 Reagents: Acetic Acid,Ammonium Acetate Solvents: Water; 2 H,Reflux
    标题:Synthesis Of Terpyridine Derivatives Containing β-Cyclodextrin
    作者:Yin,Xian Hong
    参考文献:Chinese Chemical Letters 日期:2003 卷标:14(5) 页码:445-447]

    104-87-0 + 1122-62-9 = 89972-77-0
    反应条件:1.1 Reagents: Potassium Hydroxide,Ammonia Solvents: Ethanol; 24 H,25 °C; 12 H,60 °C
    标题:Transition-Metal Chelates Of Terpyridine-Fullerene/nanotube Diads: Synthesis And Redox Properties
    作者:Wu,Zhen-Yi; Wang,Wei
    参考文献:Synthesis And Reactivity In Inorganic 日期:2016 卷标:46(3) 页码:428-436]

    104-87-0 + 1122-62-9 = 89972-77-0
    反应条件:1.1 Reagents: Potassium Hydroxide,Ammonia,Oxygen Solvents: Ethanol; 24 H,25 °C; 12 H,60 °C
    标题:Terpyridine Chelate Complex-Functionalized Single-Walled Carbon Nanotubes: Synthesis And Redox Properties
    作者:Wu,Zhen-Yi; Wang,Wei
    参考文献:Fullerenes 日期:2015 卷标:23(2) 页码:131-141]

    104-87-0 + 1122-62-9 = 89972-77-0
    反应条件:1.1 Reagents: Potassium Hydroxide,Ammonia Solvents: Ethanol,Water; 24 H,34 °C
    标题:A Near-Infrared Neutral Ph Fluorescent Probe For Monitoring Minor Ph Changes: Imaging In Living Hepg2 And Hl-7702 Cells
    作者:Tang,Bo; Yu,Fabiao; Li,Ping; Tong,Lili; Duan,Xia; Et Al
    参考文献:Journal Of The American Chemical Society 日期:2009 卷标:131(8) 页码:3016-3023
📜1-(2-Pyridyl)-3-(4-Tolyl)Propen-1-One置于ammonium Acetate,Sodium Hydroxide体系中,用 三甘醇二甲醚,乙醇 作为反应溶剂,化学反应生成 4'-(4-甲基苯基)-2,2':6',2''-三吡啶
参考文献:基于新型2,2':6',2''-吡啶的配体及其配合物的异构化和光物理性质的研究†
标题:基于新型2,2':6',2''-吡啶的配体及其配合物的异构化和光物理性质的研究†
摘要:一种新型的2,2':6',2''-基于吡啶的配体l及其配合物[ml 2](clo 4)2 .ch 2 Cl 2(m = Cd 1,Zn 2,Cu 4,Mn 5),合成[col 2](clo 4)2 3,Cdli 2 6和cdl(scn)2 7并进行充分表征.1-6的晶体结构通过单晶x射线衍射分析解决.系统地研究了所有配合物的线性吸收和发射性质以及三阶非线性光学性质.所述的平衡反式和-顺式-异构体的大号进行了实验和理论研究两者.配合物的构型和光物理性质对金属离子和阴离子的选择表现出很大的依赖性.
DOI:10.1039/c1Dt10752F

海关参考信息

专利信息


专利号:US-7772431-B1
优先权日:1999-07-27
标 题 :Performance of energy storage devices: potential areas for dendritic chemistry involvement
发明人：NEWKOME GEORGE R
权利人:NEWKOME GEORGE R
摘要:A compound consists of a fractal-like, plain or organometallic array useful for energy storage devices. A dendrimer useful in the synthesis of the fractal-like compound includes a single ligating moiety bound to a surface of each quadrant of the dendrimer. A method of making metallo-based (macro) molecules includes the steps of combining monomers selected from the group consisting of bipyridal- and terpyridal-based ligands with connecting metals and self assembling macrocycles wherein the monomes are interconnected by the metals.

专利号:US-7250534-B1
优先权日:1999-07-27
标 题:Performance of energy storage devices: potential areas for dendritic chemistry involvement
发明人：NEWKOME GEORGE R
权利人:UNIV SOUTH FLORIDA
摘要:A compound consists of a fractal-like, plain or organometallic array useful for energy storage devices. A dendrimer useful in the synthesis of the fractal-like compound includes a single ligating moiety bound to a surface of each quadrant of the dendrimer. A method of making metallo-based (macro) molecules includes the steps of combining monomers selected from the group consisting of bipyridal- and terpyridal-based ligands with connecting metals and self assembling macrocycles wherein the monomes are interconnected by the metals.

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主要参考文献

[参考文献]: Li Jiao Liang, Et Al. Zn(Ii) Complex Of Terpyridine For The Highly Selective Fluorescent Recognition Of Pyrophosphate. Analyst. 2012 Feb 21;137(4):953-8.

合成参考文献


摘要:Tian, T.; Li, Z., Science of Synthesis Knowledge Updates, (2020) 2, 410.
摘要:Chen, P.; Liu, G., Science of Synthesis: Special Topics, (2022) 1, 118.
摘要:Chen, P.; Liu, G., Science of Synthesis: Knowledge Updates, (2023) 1, 448.
摘要:Wang, P.-S.; Sayed, M.; Gong, L.-Z., Science of Synthesis: Knowledge Updates, (2023) 1, 179.
参考文献:10.1107/s160053681003744x
摘要:Li Y, Wei Z, Ng SW. Poly[bis(μ3-thiocyanato-κ3N:S:S′)(μ2-thiocyanato-κ2N:S)(4′-p-tolyl-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)cadmium(II)silver(I)]. Acta Crystallogr E Struct Rep Online. 2010 Sep 30;66(10):m1313–4. doi: 10.1107/s160053681003744x.
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