CAS: 87818-31-3; Cinmethylin

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TERPINEN-4-OL 1-chloromethyl-2-methylbenzene 1-(3-chloro-4,5,6,7-tetrahydropyrazolo[1,5-a]pyridin-2-yl)-5-(methyl-2-propynylamino)-1H-pyrazole-4-carbonitrile 2-exo-hydroxy-1-methyl-4-(1-methylethyl)-7-oxabicyclo[2.2.1]heptane

合成工艺路线路线简述

  • 58581-03-6 = 87818-31-3
    反应条件:1.1 Reagents: P-Toluenesulfonic Acid; 1.5 H,Reflux2.1 Reagents: Sodium Hydride Solvents: Tetrahydrofuran; 15 H,Reflux
    标题:Herbicidal Activity Of Cineole Derivatives
    作者:Barton,Allan F. M.; Et Al
    参考文献:Journal Of Agricultural And Food Chemistry 日期:2010 卷标:58(18) 页码:10147-10155]

    562-74-3 = 87818-31-3
    反应条件:1.1 Reagents: Tert-Butyl Hydroperoxide Catalysts: Vanadyl Acetylacetonate Solvents: Dichloromethane; 2 H,Reflux2.1 Reagents: P-Toluenesulfonic Acid; 1.5 H,Reflux3.1 Reagents: Sodium Hydride Solvents: Tetrahydrofuran; 15 H,Reflux
    标题:Herbicidal Activity Of Cineole Derivatives
    作者:Barton,Allan F. M.; Et Al
    参考文献:Journal Of Agricultural And Food Chemistry 日期:2010 卷标:58(18) 页码:10147-10155

海关参考信息

专利信息


专利号:US-2021386068-A1
优先权日:2018-11-07
标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
发明人:KISTER JEREMY; SATCHIVI NORBERT M
权利人:CORTEVA AGRISCIENCE LLC
摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

专利号:US-2021352899-A1
优先权日:2018-11-07
标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
发明人:KISTER JEREMY; SATCHIVI NORBERT M
权利人:CORTEVA AGRISCIENCE LLC
摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

专利号:TW-I655905-B
优先权日:2012-07-24
标题 :Contains 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid or a derivative thereof and very long chain fatty acid (VLCFA) Synthesis of herbicidal compositions with fatty acid/fat synthesis inhibiting herbicides

专利号:US-9644469-B2
优先权日:2012-07-24
标题 :Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and VLCFA and lipid synthesis inhibiting herbicides
发明人:YERKES CARLA N; MANN RICHARD K; SHIRAISHI IKUO; YANAGIYAMA SHINGO; SATCHIVI NORBERT M
权利人:DOW AGROSCIENCES LLC
摘要:A synergistic herbicidal composition containing (a) a compound of formula (I): n nor an agriculturally acceptable salt or ester thereof and (b) VLCFA and fatty acid/lipid synthesis inhibiting herbicides, including but not limited to, acetochlor, alachlor, anilofos, benfuresate, cafenstrole, dimethenamid-P, fentrazamide, indanofan, flufenacet, mefenacet, s-metolachlor, molinate, pethoxamid, pretilachlor, prosulfocarb, pyroxasulfone, thenylchlor and thiobencarb, or a salt or ester thereof, provide synergistic weed control of undesirable vegetation in direct-seeded, water-seeded and transplanted rice, cereals, wheat, barley, oats, rye, sorghum, corn or maize, sugarcane, sunflower, oilseed rape, canola, sugar beet, soybean, cotton, pineapple, pastures, grasslands, rangelands, fallowland, turf, tree and vine orchards, aquatics, plantation crops, vegetables, industrial vegetation management (IVM) or rights-of-way (ROW).

专利号:US-11866443-B2
优先权日:2017-05-19
标 题:Method for separating optically active hydroxy cineole derivatives
发明人:DITRICH KLAUS; RACK MICHAEL; BENSON STEFAN; GOETZ ROLAND; KRAUS HELMUT
权利人:BASF AGRO BV
摘要:The present invention relates to a method for separating an optically active hydroxy cineole derivatives by lixiviation and crystallization and enantiomerically pure optically active hydroxy cineole derivatives of purity greater than 99.5% that have been prepared by this process. The present invention further relates to use of the desired enantiomer having enantiomeric excess of at least 99.5% ee as prepared according to the present invention, for the synthesis of enantiomerically pure 7-oxabicyclo[2.2.1]heptane derivatives.

专利号:US-7375058-B2
优先权日:2001-09-14
标 题:Herbicidal mixtures based on 3-phenyluracils
发明人:ZAGAR CYRILL; SIEVERNICH BERND; QUAKENBUSH LAURA; EVANS RICHARD R; LANDES MAX; NEWSOM LARRY J; ORTLIP CHARLES L; WITSCHEL MATTHIAS; LANDES ANDREAS
权利人:BASF AG
摘要:Herbidically active compositions, comprising: A) at least one phenyluracil compound of the formula (I); in which the variables R 1 -R 7 are as defined in the claims, and/or at least one of its agriculturally acceptable salts; and at least one further active compound, selected from B) herbicides of classes b1) to b15): b1) lipid biosynthesis inhibitors; b2) acetolactate synthase inhibitors (ALS inhibitors); b3) photosynthesis inhibitors; b4) protoporphyrinogen-IX oxidase inhibitors; b5) bleacher herbicides; b6) enolpyruvyl shikimate 3-phosphate synthase inhibitors (EPSP inhibitors); b7) glutamine synthetase inhibitors; b8) 7,8-dihydropteroate synthase inhibitors (DHP inhibitors); b9) mitose inhibitors; b10) inhibitors of the synthesis of very long chain fatty acids (VLCFA inhibitors); b11) cellulose biosynthesis inhibitors; b12) decoupler herbicides; b13) auxin herbicides; b14) auxin transport inhibitors; b15) other herbicides selected from the group consisting of benzoylprop, flamprop, flamprop-M, bromobutide, chlorflurenol, cinmethylin, methyldymron, etobenzanid, fosamine, metam, pyributicarb, oxaziclomefone, dazomet, triaziflam and methyl bromide; and safeners selected from: benoxacor, cloquintocet, cyometrinil, dichlormid, dicyclonon, dietholate, fenchlorazole, fenclorim, flurazole, fluxofenim, furilazole, isoxadifen, mefenpyr, mephenate, naplithalic anhydride, 2,2,5-trimethyl-3-(dichloroacetyl)-1,3-oxazolidine, 4-(dichloroacetyl)-1-oxa-4-azaspiro[4.5]decane and oxabetrinil, the agriculturally acceptable salts of the active compounds B and C and the agriculturally acceptable derivatives of the active compounds B and C, provided they have a carboxyl group
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主要参考文献


1: Busi R, Dayan FE, Francis I, Goggin D, Lerchl J, Porri A, Powles SB, Sun C, Beckie HJ. Cinmethylin controls multiple herbicide-resistant Lolium rigidum and its wheat selectivity is P450-based. Pest Manag Sci. 2020 Aug;76(8):2601-2608. doi: 10.1002/ps.5798. Epub 2020 Feb 28. 78(7):3173-3182. doi: 10.1002/ps.6947. Epub 2022 May 12.
3: Jung J, Schmölzer K, Schachtschabel D, Speitling M, Nidetzky B. Selective β-Mono-Glycosylation of a C15-Hydroxylated Metabolite of the Agricultural Herbicide Cinmethylin Using Leloir Glycosyltransferases. J Agric Food Chem. 2021 May 19;69(19):5491-5499. doi: 10.1021/acs.jafc.1c01321. Epub 2021 May 11.
4: Ogawa N, Toyoshima S, Sekikawa S, Ishijima M, Katagiri K, Uematsu C, Hirano T, Ootaka A, Suzuki J. Synthesis and herbicidal activity of optically active cinmethylin, its enantiomer, and C3-substituted cinmethylin analogs. J Pestic Sci. 2023 Feb 20;48(1):11-16. doi: 10.1584/jpestics.D22-051.

合成参考文献


摘要:Farm Chemicals Handbook., -(C26), 1991
参考文献:10.1007/s13197-021-05028-1
摘要:Bharti SK, Pathak V, Alam T, Arya A, Singh VK, Verma AK, Rajkumar V. Starch bio-based composite active edible film functionalized with Carum carvi L. essential oil: antimicrobial, rheological, physic-mechanical and optical attributes. Journal of Food Science and Technology. 2021 Feb 24;59(2):456–66. doi: 10.1007/s13197-021-05028-1.
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