CAS: 87630-35-1; 1-(Triisopropylsilyl)-1H-Pyrrole
该化合物是一种有机硅质化合物,其特点是存在一种以三异丙基硅基组取代的火花环,三异丙基硅酸盐会提高化合物在有机溶剂中的稳定性和溶性,使其在各种合成应用中有用.这种化合物通常展示一种分子式,反映其含有氮的五人芳香环组成的热质结构.三异丙基环的存在有助于其独特的再活动,并能够影响其电子特性,使其成为有机合成中有价值的中间体,特别是在制造更复杂的分子时.此外,该化合物可能具有有趣的物理特性,例如特定的熔点和沸点,受到大量硅基亚构成者的影响.其应用可能扩大到材料科学,药用化学和催化等领域,在这些领域,电子和消化特性的操纵对于新化合物的开发至关重要.
相似化合物
87630-36-2 130408-83-2 156304-02-8物理性质
MSDS等安全信息
欧盟法规
ECHA物质C&L通报上下游产品
pyrrole triisopropylsilyl chloride potassium pyrrolide 3-bromo-1-triisopropylsilanyl-1H-pyrrole 2-(4-methylbenzenesufinyl)-1H-pyrrole 3-(p-tolylsulfinyl)-1-(triisopropylsilyl)pyrrole ethyl pyrrolo[1,2-c]pyrimidine-3-carboxylate pyridin-6-carbonsaeure-ethylester1H-Pyrrolo3,2-cpyridin-6-carbonsaeure-ethylester合成工艺路线路线简述
- 13154-24-0 = 87630-35-1
反应条件:1.1 Reagents: Sodium Hydride Solvents: Dimethylformamide
标题:Pyrrole,Imidazolone And Imidazolidinone Chemistry For The Synthesis Of Heterocyclic Natural Products
作者:Cantos-Llopart,Carme
参考文献:2003]
13154-24-0 = 87630-35-1
反应条件:1.1 Reagents: Sodium Hydride Solvents: Tetrahydrofuran; 0 °C; 90 Min,0 °C1.2 90 Min,0 °C1.3 Reagents: Water; 0 °C
标题:4-Acyl Pyrrole Capped Hdac Inhibitors: A New Scaffold For Hybrid Inhibitors Of Bet Proteins And Histone Deacetylases As Antileukemia Drug Leads
作者:Schaeker-Huebner,Linda; Et Al
参考文献:Journal Of Medicinal Chemistry 日期:2021 卷标:64(19) 页码:14620-14646]
13154-24-0 + 7697-45-2 = 87630-35-1
反应条件:1.1 Solvents: Dimethylformamide; 0 °C
标题:Synthesis,Biological Evaluation,And Docking Studies Of Various β-Substituted Porphyrin Conjugates Embedded With N-Containing Heterocycles
作者:Masaret,Ghada S.
参考文献:Journal Of Heterocyclic Chemistry 日期:2021 卷标:58(9) 页码:1836-1848]
= 87630-35-1
反应条件:1.1 Reagents: Sodium Hydride Solvents: Dimethylformamide; 0 °C2.1 Solvents: Dimethylformamide; 0 °C
标题:Synthesis,Biological Evaluation,And Docking Studies Of Various β-Substituted Porphyrin Conjugates Embedded With N-Containing Heterocycles
作者:Masaret,Ghada S.
参考文献:Journal Of Heterocyclic Chemistry 日期:2021 卷标:58(9) 页码:1836-1848
📜2-Bromo-1-(Triisopropylsilyl)Pyrrole置于正丁基锂,Dimethyl-(4-Nitro-Buta-1,3-Dienyl)-Amine体系中,用 四氢呋喃,正戊烷 作为反应溶剂,以73.4%的收率获得产物1-(三异丙基甲硅烷基)吡咯
参考文献:Condensation Reactions Of A Nitrodienamine With Organocopper And Alkyllithium Reagents Prepared From Pyrrole Derivatives
标题:Condensation Reactions Of A Nitrodienamine With Organocopper And Alkyllithium Reagents Prepared From Pyrrole Derivatives
摘要:Condensation Reactions Of A Nitrodienamine (1) With Grignard,Organocopper And Alkyllithium Reagents Prepared From Pyrrole Derivatives Were Investigated.
DOI:10.3987/com-00-8859
专利信息
专利号:US-7329769-B2
优先权日:2001-07-13
标 题:Catalytic boronate ester synthesis from boron reagents and hydrocarbons
发明人：SMITH III MILTON R
权利人:UNIV MICHIGAN STATE
摘要:A process for producing a ring-substituted arene borane which comprises reacting a ring-substituted arene with an HB organic compound in the presence of a catalytically effective amount of an iridium or rhodium complex with three or more substituents, excluding hydrogen, bonded to the iridium or rhodium and a phosphorus organic ligand, which is at least in part bonded to the iridium or rhodium, to form the ring-substituted arene borane. Also provided are catalytic compounds for catalyzing the process comprising an iridium or rhodium complex with three or substituents, excluding hydrogen, bonded to the iridium or rhodium and optionally, a phosphorus organic ligand, which is at least in part bonded to the iridium or rhodium.
专利号:WO-03102007-A1
优先权日:2002-06-03
标题:Process for synthesising c-glycosides
发明人：ARMITT DAVID JOHN; BANWELL MARTIN GERHARDT
权利人:UNIV AUSTRALIAN; ARMITT DAVID JOHN; BANWELL MARTIN GERHARDT
摘要:The invention provides a process for the synthesis of C-glycosides. In the process, an O-glycosyl trichloroimidate is reacted with a pyrrole in the presence of a Lewis acid and the C-glycoside isolated from the foregoing reaction mixture. The invention also relates to the products of the process.
专利号:CN-108794449-B
优先权日:2017-05-05
标题 :A kind of synthesis method of deuterated fumaric acid vonoprazan metabolite
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品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
参考标题:Platinum-Catalyzed Domino Reaction With Benziodoxole Reagents For Accessing Benzene-Alkynylated Indoles作者:Yifan Li,Jerome Waser |发布日期:2015.4.27
摘要:Platinum‐catalyzed Cyclization/alkynylation Domino Process To Selectively Obtain C5‐ Or C6‐functionalized Indoles Starting From Easily Available Pyrroles. The Work Combines, For The First Time, A Platinum Catalyst With Ethynylbenziodoxole Hypervalent Iodine Reagents In A Domino Process For The Synthesis Of Polyfunctionalized Arene Rings And Gives Access To Important Building Blocks For The Synthesis Of Bioactive
合成参考文献
摘要:Hopkinson, M. N.; Gouverneur, V., Science of Synthesis Knowledge Updates, (2011) 2, 111.
摘要:Lubell, W. D.; St-Cyr, D. J.; Dufour-Gallant, J.; Hopewell, R.; Boutard, N.; Kassem, T.; Dörr, A.; Zelli, R., Science of Synthesis Knowledge Updates, (2013) 1, 319.
摘要:Lubell, W. D.; St-Cyr, D. J.; Dufour-Gallant, J.; Hopewell, R.; Boutard, N.; Kassem, T.; Dörr, A.; Zelli, R., Science of Synthesis Knowledge Updates, (2013) 1, 301.
摘要:Lubell, W. D.; St-Cyr, D. J.; Dufour-Gallant, J.; Hopewell, R.; Boutard, N.; Kassem, T.; Dörr, A.; Zelli, R., Science of Synthesis Knowledge Updates, (2013) 1, 337.
摘要:Lubell, W. D.; St-Cyr, D. J.; Dufour-Gallant, J.; Hopewell, R.; Boutard, N.; Kassem, T.; Dörr, A.; Zelli, R., Science of Synthesis Knowledge Updates, (2013) 1, 306.
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