CAS: 592-45-0; 1,4-Hexadiene

该化合物是分子式C6H10的线性死因,其特征是其链中第一和第二个碳原子存在两层双环结,这种化合物在室温下是一种无色液体,有温和,甜味的气味,以其活性为名,特别是在聚合反应方面,使其作为单一体在生产各种合成材料方面有用.1,4-甲基丙烯在水中不溶解,但在有机溶剂中可溶解,这增强了其在化学合成中的效用.该化合物易燃,应谨慎处理,因为若吸入或吸收在皮肤中,可能会对健康造成危害.其沸点和其他物理特性使该物质适合有机合成的应用,并作为中间体,用于制造其他化学品.此外,1,4-甲基乙胺可以参与各种化学反应,包括额外的反应,因为其存在双重结合,进一步扩大其在工业应用中的效用.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

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合成工艺路线路线简述

    📜1,4-己烷二醇置于lasimo12O40体系中,用 二氯甲烷 作为反应溶剂,以73%的收率获得产物1,4-己二烯
    参考文献:一种基于醛酮缩合反应合成二烯烃类化合物的方法
    标题:一种基于醛酮缩合反应合成二烯烃类化合物的方法
    摘要:本发明提供了一种基于醛酮缩合反应合成二烯烃类化合物的方法,包括以下步骤,首先在缩合催化剂的作用下,将酮类化合物和醛类化合物进行缩合反应后,得到缩合产物;然后在还原催化剂的作用下,将上述步骤得到的缩合产物进行还原反应后,得到还原产物;在催化剂的作用下,将上述步骤得到的还原产物进行脱水反应后,得到二烯烃类化合物.本发明可利用廉价易得的酮,醛及其同系物为原料,合成丁二烯,间戊二烯及其同系物等二烯烃类化合物,实验条件温和,操作简单,具有规模化合成的前景.

    海关参考信息

    专利信息


    专利号:US-7973171-B2
    优先权日:2005-06-13
    标题:Process for synthesis of dialkoxyorganoboranes
    发明人:BURKHARDT ELIZABETH; ATKINS WILLIAM
    权利人:BURKHARDT ELIZABETH; ATKINS WILLIAM
    摘要:The invention relates to a process for the synthesis of dialkoxyorganoboranes, in particular to a process for the synthesis of dialkoxyorganoboranes by an ester exchange reaction. Moreover, the invention relates to a process for the synthesis of organo-oxazaborolidine catalysts (organo-CBS) and of trialkylboroxins. Furthermore, the invention relates to methods of using dialkoxyorganoboranes for the preparation of organo-CBS catalysts and in Suzuki-type coupling reactions.

    专利号:WO-2023102600-A1
    优先权日:2021-12-06
    标题:Synthesis of amphiphilic block copolymers and polymeric nanofibers produced therefrom
    发明人:ZETTERLUND PER B; ISHIZUKA FUMI; KIM HYUN JIN; CHATANI SHUNSUKE; NIINO HIROSHI
    权利人:NEWSOUTH INNOVATIONS PTY LTD
    摘要:The present disclosure relates to the field of synthesis of block copolymers, and polymeric nanofibers having a core-shell morphology produced therefrom. The present disclosure relates to the field of synthesis of block copolymers where one block is more hydrophobic than the other block and is a different composition. The disclosure also relates to uses of these polymeric nanofibers in various applications, such as reinforcing a polymeric matrix and for coatings applications.

    专利号:US-6512081-B1
    优先权日:1997-07-21
    标题:Synthesis of dithioester chain transfer agents and use of bis(thioacyl) disulfides or dithioesters as chain transfer agents
    发明人:RIZZARDO ENZIO; THANG SAN HOA; MOAD GRAEME
    权利人:E I DUPONT NEMOURS AND COMPANY; COMMW SCIENT IND RES ORG
    摘要:This invention relates to the synthesis of dithiocarboxylic acid esters by reaction of bis(thioacyl) disulphides, thioacetals or vinylidane bis(thioether) with free-radicals (optionally in the presence of monomers). The invention also relates to processes for the synthesis of polymers utilising these dithioesters as polymerisation regulators (chain transfer agents) or to the use of bis(thioacyl) disulphides to generate dithioester chain transfer agents in situ.

    专利号:US-3742080-A
    优先权日:1969-04-11
    标 题 :Rhodium based catalysts for the synthesis of 1,4-dienes
    发明人:SU A
    权利人:DU PONT
    摘要:Improved catalysts are provided for the synthesis of 1,4-dienes from Alpha -monoolefins and conjugated dienes. The catalysts are rhodium (III) salts in combination with amides, phosphoramides, phosphine oxides, or water. The improved catalysts allow control of the trans-cis ratio of the 1,4-diene formed and are operable at useful rates in a wide range of solvent systems, both protonic and aprotic.

    专利号:US-6479599-B1
    优先权日:1997-04-04
    标题:Catalyst system for high yield synthesis of polyolefins
    发明人:PEIL KEVIN P; WILSON DAVID R
    权利人:BP CHEM INT LTD
    摘要:This invention relates to a supported metallocene catalyst system for the high yield synthesis of polyolefins, to methods of preparation of the catalyst system, to polymerization processes which use the catalyst system and to polyolefin polymers produced by the polymerization processes.

    专利号:US-10611864-B2
    优先权日:2015-09-22
    标 题:Synthesis of substituted amidobenzoate compounds, the compounds obtained and the use thereof as phthalate free internal electron donor for polymerization of olefins
    发明人:ZUIDEVELD MARTIN ALEXANDER; SAINANI JAIPRAKASH BRIJLAL; AL-HUMAIDAN OSAMAH; PADMANABHAN SUDHAKAR R; SHINGE PRASHANT SUKUMAR; SHETTY SHARANKUMAR G; SHAIKH ABBAS-ALLI GHUDUBHAI
    权利人:SABIC GLOBAL TECHNOLOGIES BV
    摘要:The present invention relates to a compound according to Formula (I) wherein R 1 is a hydrocarbyl group selected from the group consisting of alkyl, alkenyl, aryl, aralkyl, and alkylaryl groups, and one or more combinations thereof; wherein R 2 is a hydrogen atom, an aryl group or an alkyl group; and wherein R 3 , R 4 , R 5 and R 6 , are the same or different and are each independently a hydrogen atom, a halogen atom, a cyano group, an amino group, a hydrocarbyl group selected from the group consisting of alkyl, alkenyl, aryl, aralkyl, and alkylaryl groups or an alkoxy group, and one or more combinations thereof as internal electron donor and to a process for the synthesis of a compound according to Formula (I), wherein R 1 is a hydrocarbyl group selected from the group consisting of alkyl, alkenyl, aryl, aralkyl, alkoxycarbonyl and alkylaryl groups, and one or more combinations thereof; wherein R 2 is a hydrogen atom or an alkyl group; wherein R 3 , R 4 , R 5 and R 6 , are the same or different and are each independently selected from a group consisting of a hydrogen atom; a hydrocarbyl, preferably, said process comprising the step of reacting a compound according to Formula (II) [R 1 —C(â•?O)Cl] with a compound according to Formula (III) to obtain the compound according to Formula (I) and to the use of these compounds as internal donor in Ziegler-Natta catalysis of lefins.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:Solid-Phase Synthesis Of Heterocycles Via Palladium-Catalyzed Annulation
    作者:Yao Wang,Tai-Nang Huang |发布日期:1998.12
    摘要:Solid-Phase Linked O-Iodoanilines (4) And O-Iodophenol (9) Reacted With 1,3- And 1,4-Dienes In The Presence Of Palladium Acetate To Generate Highly Substituted Indolines, Tetrahydroquinolines, Hydrobenzofurans And Hydrobenzopyrans, Which Provided An Efficient Way For Making Heterocyclic Molecule Libraries.

    合成参考文献


    摘要:Ohno, H.; Tomioka, K., Science of Synthesis, (2008) 44, 81.
    摘要:Taylor, R. E.; Diène, C. R.; Daly, E. M., Science of Synthesis, (2009) 46, 552.
    摘要:Muñiz, K., Science of Synthesis: Stereoselective Synthesis, (2011) 1, 10.
    摘要:Matsumoto, K.; Katsuki, T.; Arends, I. W. C. E., Science of Synthesis: Stereoselective Synthesis, (2011) 1, 101.
    摘要:Xia, F.; Ye, S., Science of Synthesis: Metal-Catalyzed Cyclization Reactions, (2016) 2, 32.
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