CAS: 4582-21-2; Trans-Bicyclo[2.2.1]Hept-5-Ene-2,3-Dicarbonyl Dichloride

该化合物是一种具有两个反应式碳基氯化物组的手性双环化合物,其硬性或隐性骨架和定义的立体化学器使它成为不对称合成中的宝贵中间体,特别是用于建造复杂的循环框架.二氯化物功能通过核生殖替代或凝聚反应,使高效衍生,而紧张的双份债券则为循环或聚合提供机会.一种(R,2R,3R,4S)的再组合确保下游变异的立体控制.这种复合物在制药和材料化学中特别有用,其结构限制和多处反应场有助于培养有受控结构的抗免疫性纯化合物或功能化聚合物.

英文名称Trans-Bicyclo[2.2.1]Hept-5-Ene-2,3-Dicarbonyl Dichloride
中文名称反-3,6-内亚甲基-1,2,3,6-四氢邻苯二甲酰氯
IUPAC名称(2R,3R)-bicyclo[2.2.1]hept-5-ene-2,3-dicarbonyl dichloride
其它别名Trans-5-Norbornene-3-Dicarbonylchloride; Trans-Bicyclo(2.2.1)Hept-5-Enyl-2,3-Dicarbonylchloride; (2-Endo,3-Exo)-Bicyclo[2.2.1]Hept-5-Ene-2,3-Dicarbonyl Dichloride; Trans-3,6-Endo-Methylene-1,2,3,6-Tetrahydrophthaloyl Chloride,; Trans-3,6-Endo-Methylene-1,2,3,6-Tetrahydrophthaloyl Chloride; Trans-5-Norbornene-2,3-Dicarbonyl Chloride; Bicyclo[2.2.1]-5-Heptene-2,3-Dicarbonyl Chloride; 3,6-Endomethylene-1,2,3,6-Tetrahydrophthaloyl Chloride
CAS编号4582-21-2
MFCD编号:MFCD00167567
EINECS号:224-967-5
分子式:C9H8Cl2O2分子量:219.07
产品CID: 1459494
产品分类化学试剂 → 有机试剂 → 酰卤

相似结构搜索
产品信息参考;;
InChIKey: KANQIAARVSWKKG-UHFFFAOYNA-N
InChI=1S/C9H8Cl2O2/c10-8(12)6-4-1-2-5(3-4)7(6)9(11)13/h1-2,4-7H,3H2/t4-,5+,6-,7-/m1/s1
计算化学: 氢键受体数2.0氢键供体数*可旋转键数2.0

MSDS等安全信息

GHS象形图
GHS符号GHS07 & GHS05;
注释: Exclamation mark & Corrosion
危险类别急性毒性类别4(吸入)
急性毒性类别4(经皮)
皮肤腐蚀类别1B
警示词Danger(危险)
危险描述H332 |吸入有害.
H312 |皮肤接触有害.
H314 |造成严重皮肤灼伤和眼损伤.
防范说明P261-P271-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
危险等级8
UN编号UN 3265 8/PG 2
危险品标志C
包装等级III
安全声明23-26-28-36/37/39-45
危险类别码20/21/22-34
WGK Germany3

欧盟法规

ECHA物质C&L通报REACH预注册

合成工艺路线路线简述

海关参考信息

2901210000-乙烯
2901220000-丙烯
2912110000-甲醛
2912120000-乙醛
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专利信息

专利号:US-9890049-B2
优先权日:2016-03-04
标题:Molecular sieve SSZ-106, its synthesis and use
发明人：ELOMARI SALEH ALI
权利人:CHEVRON USA INC
摘要:Disclosed herein is a new crystalline molecular sieve designated SSZ-106, its synthesis in the presence of a structure directing agent comprising 2,3-bis(N-methylpyrrolidin-1-ylmethyl)bicyclo[2.2.1]heptane dication, and its use as an adsorbent and a catalyst.

专利号:US-5138023-A
优先权日:1991-10-11
标题 :Unsaturated polyesters and crosslinked membranes therefrom for aromatics/saturates separation
发明人：SARTORI GUIDO; HO W S WINSTON; NOONE ROBERT E
权利人:EXXON RESEARCH ENGINEERING CO
摘要:The present invention describes a method for the synthesis of unsaturated aliphatic polyesters, their crosslinking by thermal treatment and the use of the corresponding crosslinked membranes to separate aromatics from saturates.

专利号:US-5180496-A
优先权日:1991-10-11
标题 :Unsaturated polyesters and crosslinked membranes therefrom for aromatics/saturates separation
发明人：SARTORI GUIDO; HO W S WINSTON; NOONE ROBERT E
权利人:EXXON RESEARCH ENGINEERING CO
摘要:The present invention describes a method for the synthesis of unsaturated aliphatic polyesters, their crosslinking by thermal treatment and the use of the corresponding crosslinked membranes to separate aromatics from saturates.