CAS: 1671-75-6; Heptanophenone

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1674-37-9 6048-82-4 6008-36-2

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📜己酸置于4-二甲氨基吡啶,(4,4'-Di-Tert-Butyl-2,2'-Dipyridyl)-Bis-(2-Phenylpyridine(-1H))-Iridium(III) Hexafluorophosphate,水,N,N'-二异丙基碳二亚胺体系中,用 二氯甲烷,乙腈 用作溶剂,化学反应 12.0H,反应生成苯庚酮
参考文献:光氧化还原催化的甲硅烷基醚的脱羧烷基化反应,合成功能化的芳烷基酮
标题:光氧化还原催化的甲硅烷基醚的脱羧烷基化反应,合成功能化的芳烷基酮
摘要:已经开发了光氧化还原催化的甲硅烷基烯醇醚的脱羧烷基化.使用n-(酰氧基)邻苯二甲酰亚胺作为容易获得的烷基自由基源,在温和且操作简单的条件下,以中等至非常好的收率提供了多种官能化的芳基烷基酮.药物分子(如芬布芬和消炎痛)以及天然存在的羧酸(如硬脂酸和脱氢胆酸)的优异性能进一步证明了该反应的实用性.
Doi:10.1021/acs.Orglett.7B03587

专利信息

专利号:US-7517828-B2
优先权日:2003-04-25
标 题 :Chiral broensted acid catalyst for asymmetric synthesis and method of asymmetric synthesis with the catalyst
发明人：AKIYAMA TAKAHIKO
权利人:TOAGOSEI CO LTD
摘要:A compound usable as an asymmetric synthesis catalyst which can be easily synthesized without using any metal such as a lanthanoid group element; a method of asymmetric synthesis with the compound; and a chiral compound obtained by the asymmetric synthesis method. A Broensted acid is used as a catalyst in asymmetric synthesis, the chiral Broensted acid being represented by formula (1) below or formula (3) below. The asymmetric synthesis method employs the catalyst. Asymmetric synthesis with the catalyst gives a chiral compound.

专利号:US-5936128-A
优先权日:1993-11-19
标题:5,6-dihydropyrone derivatives as protease inhibitors and antiviral agents
发明人：ELLSWORTH EDMUND LEE; LUNNEY ELIZABETH; TAIT BRADLEY DEAN
权利人:WARNER LAMBERT CO
摘要:The present invention relates to novel 5,6-dihydropyrone derivatives and related structures which potently inhibit the HIV aspartyl protease blocking HIV infectivity. The 5,6-dihydropyrone derivatives are useful in the development of therapies for the treatment of bacterial and viral infections and diseases, including AIDS. The present invention is also directed to methods of synthesis of multifunctionalized 5,6-dihydropyrones and of related structures.

专利号:US-5840751-A
优先权日:1993-11-19
标题 :5,6-dihydropyrone derivatives as protease inhibitors and antiviral agents
发明人：ELLSWORTH EDMUND LEE; LUNNEY ELIZABETH; TAIT BRADLEY DEAN
权利人:WARNER LAMBERT CO
摘要:The present invention relates to novel 5,6-dihydropyrone derivatives and related structures which potently inhibit the HIV aspartyl protease blocking HIV infectivity. The 5,6-dihydropyrone derivatives are useful in the development of therapies for the treatment of bacterial and viral infections and diseases, including AIDS. The present invention is also directed to methods of synthesis of multifunctionalized 5,6-dihydropyrones and of related structures.

专利号:JP-S5527149-A
优先权日:1978-08-18
标题 :Synthesis of ketone

专利号:KR-20040026964-A
优先权日:2002-09-27
标 题 :Synthesis of cyclohexyl phenyl ketone from 1,3-butadiene and acrylic acid

专利号:RU-2005714-C1
优先权日:1986-07-01
标 题 :Process for continuous synthesis of aldehydes