CAS: 1523-11-1; 2-Naphthyl Acetate

相似化合物

830-81-9 146744-23-2 22426-47-7

上下游产品

pyridine benzoyl chloride acetic acid β-naphthol 1-(2-hydroxy-1-naphthyl)ethan-1-one 1-(7-hydroxy-1-naphthalenyl)ethanone 1-(6-hydroxy-2-naphthyl)ethan-1-one acetic acid

Tetralon-(2)-δ1-Enolacetat置于cesium Fluoroxysulphate体系中,用 二氯甲烷 用作溶剂,化学反应 0.25H,以78%的收率获得乙酸-2-萘酯
参考文献:有机卤素分子化学.第100部分.二氟化氙和氟代硫酸铯在烯醇乙酸酯和酮氟化中的比较行为
标题:有机卤素分子化学.第100部分.二氟化氙和氟代硫酸铯在烯醇乙酸酯和酮氟化中的比较行为
摘要:二氟化氙和氟代硫酸铯在二氯甲烷或乙腈中与各种烯醇乙酸酯,二酮和酮反应,主要生成α-氟代酮,反应过程取决于试剂和有机分子的结构.用氟代硫酸铯将来自环akanones的烯醇乙酸酯高产率地转化为α-氟代环烷酮.二氟化氙和氟代硫酸铯将苯并环烷酮-1的烯醇乙酸酯转化为α-氟苯并环烷酮,而苯并环烷酮-2的烯醇乙酸酯的反应性取决于所使用的试剂.用xef 2和csso 4转化1,3-二苯基丙烷-1,3-二酮及其烯醇乙酸酯f为单和二氟取代的产物,反应过程取决于试剂.氟化二氙将1-茚满酮转化为重排的2,2-二氟苯并烷,而氟代硫酸铯与2-茚满酮反应生成1-氟-2-茚满酮.
Doi:10.1016/s0040-4020(01)89127-4

专利信息

专利号:US-2006223883-A1
优先权日:2005-04-02
标题 :Novel hydroxylated enantiomers of (-) 3a,6,6,9a-tetramethylperhydronaphtho[2,1-b]furan as perfuming agents derived from a fungal fermentation process.
发明人：RAHMAN ATTAUR; CHOUDHARY MOHAMMAD I; MUSHARRAF SYED G
权利人:RAHMAN ATTAUR; CHOUDHARY MOHAMMAD I; MUSHARRAF SYED G
摘要:(−) 3a,6,6,9a-tetramethylperhydronaphtho[2,1-b]furan (ambrox) is a strong aromatic compound used widely in a variety of perfumery applications and is highly prized for its musky odor. We report novel polar metabolites of (−)3a,6,6,9a-tetramethylperhydronaphtho[2,1-b]furan prepared by a novel process of microbial fermentation using a fungi, Fusarium lini , of unique structures that would be difficult to predict opening up the possibilities of their chemical synthesis. The polar metabolites discovered have stronger aromatic characteristics and offer a new highly prized odiferous characteristic quite different from that of the parent compound and thus can be used in the preparation of perfumes, odor-masking and other odor-management applications.

专利号:US-2012301956-A1
优先权日:2011-05-26
标 题:Novel hydroxylated enantiomers of (-) 3a,6,6,9a-tetramethylperhydronaphtho[2,1-b]furan as perfuming agents derived from a fungal fermentation process
发明人：RAHMAN ATTAUR; CHOUDHARY MOHAMMAD IQBAL; MUSHARRAF SYED GHULAM; SAMI AMTUL
权利人:RAHMAN ATTAUR; CHOUDHARY MOHAMMAD IQBAL; MUSHARRAF SYED GHULAM; SAMI AMTUL
摘要:(−)3a,6,6,9a-tetramethylperhydronaphtho[2,1-b]furan (ambrox) is a strong aromatic compound used widely in a variety of perfumery applications and is highly prized for its musky odor. We report novel polar metabolites of (−)3a,6,6,9a-tetramethylperhydronaphtho[2,1-b]furan prepared by a novel process of microbial fermentation using a fungi, Fusarium lini, of unique structures that would be difficult to predict opening up the possibilities of their chemical synthesis. The polar metabolites discovered have stronger aromatic characteristics and offer a new highly prized odiferous characteristic quite different from that of the parent compound and thus can be used in the preparation of perfumes, odor-masking and other odor-management applications.

专利号:WO-0061767-A1
优先权日:1999-04-09
标题 :Extracellular protease from $i(acremonium chrysogenum) with cpc-acetyl hydrolase activity and its utilization in the synthesis of deacetylated derivatives of cephalosporin c and inactivation of the gene for increasing production of cephalosporin

专利号:WO-9000611-A1
优先权日:1988-07-15
标题 :Synthesis of stereospecific enzyme by non-chromosomal transformation of a host

专利号:US-3975429-A
优先权日:1973-11-05
标题:Cyclopropanemethyl esters of cinnamic acid and derivatives thereof
发明人：HENRICK CLIVE A; STAAL GERARDUS B
权利人:ZOECON CORP
摘要:Organic esters and thioesters characterized by the presence of a cyclopropane moiety, synthesis thereof, and compositions thereof for the control of mites and ticks.

专利号:JP-2002541812-A
优先权日:1999-04-09
标 题 :Synthesis of Acremonium chrysogenum extracellular protease having CPC acetylhydrolase activity and deacetylated derivative of cephalosporin C and its use in inactivating genes to increase cephalosporin yield