CAS: 97416-84-7; 1,3-Dibromo-5-[2-[3,5-Dibromo-4-(2,3-Dibromo-2-Methylpropoxy)Phenyl]Propan-2-Yl]-2-(2,3-Dibromo-2-Methylpropoxy)Benzene

英文名称1,3-Dibromo-5-[2-[3,5-Dibromo-4-(2,3-Dibromo-2-Methylpropoxy)Phenyl]Propan-2-Yl]-2-(2,3-Dibromo-2-Methylpropoxy)Benzene
中文名称2,2-双[3,5-二溴-4-(2,3-二溴-2-甲基丙氧基)苯基]丙烷
IUPAC名称1,3-dibromo-5-[2-[3,5-dibromo-4-(2,3-dibromo-2-methylpropoxy)phenyl]propan-2-yl]-2-(2,3-dibromo-2-methylpropoxy)benzene
其它别名2,2-Bis[3,5-dibromo-4-(2,3-dibromo-2-methylpropoxy)phenyl]propane; 2,2-Bis[3,5-dibromo-4-(2,3-dibromo-2-methylpropyloxy)phenyl]propane
CAS编号97416-84-7
EINECS号:306-832-3
分子式:C23H24Br8O2
分子量:971.67
产品CID: 2021418
产品分类有机原料 → 烃类化合物及其衍生物 → 芳香烃

相似结构搜索
InChIKey: IYOVSGHZOIZSDC-UHFFFAOYNA-N
InChI=1S/C23H24Br8O2/c1-21(2,13-5-15(26)19(16(27)6-13)32-11-22(3,30)9-24)14-7-17(28)20(18(29)8-14)33-12-23(4,31)10-25/h5-8H,9-12H2,1-4H3…
计算化学: 氢键受体数2.0氢键供体数0.0可旋转键数10.0

MSDS等安全信息

危险描述Not Classified
Reported as not meeting GHS hazard criteria by 17 of 17 companies. For more detailed information, please visit ECHA C&L website.

上下游产品

2,2,6,6-四溴双苯酚a二甲基丙烯酸酯 2,2-Bis[3,5-Dibromo-4-(2-Methacryloxy)Phenyl]Propane 42146-13-4
四溴双酚 A Tetrabromobisphenol A 79-94-7
2,2-Bis[4-(2-Methylallyloxy)Phenyl]Propane 103915-73-7

合成工艺路线路线简述

103915-73-7 = 97416-84-7
反应条件:1.1 Reagents: Bromine Solvents: Chlorobenzene; 10 - 20 °C1.2 Reagents: Bromine Catalysts: Iron; 10 - 20 °C1.3 Reagents: Sodium Sulfite1.4 Reagents: Sodium Hydroxide; Neutralized
标题:Process For Preparation Of Flame Retardant 2,2-Bis[3,5-Dibromo-4-(2,3-Dibromo-2-Methylpropoxy)Phenyl]Propane
参考文献:China]

= 97416-84-7
反应条件:1.1 Reagents: Bromine Solvents: Chloroform; -5 - 5 °C; 2 - 3 H,-5 - 5 °C; 0.5 - 1 H,5 °C -> 25 °C
标题:Preparation Of Methyl Octabromo Ether
参考文献:China]

79-94-7 = 97416-84-7
反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Water; 0.5 H,Ph 8 - 9,Rt1.2 1 H,Rt; 5 H,Rt1.3 Reagents: Bromine Solvents: Dichloromethane; 5 H,Reflux1.4 Reagents: Sodium Sulfite Solvents: Water
标题:Method For Synthesis Of Tetrabromobisphenol A Bis(2,3-Dibromo-2-Methylpropyl) Ether
参考文献:China]

= 97416-84-7
反应条件:1.1 Reagents: Bromine Catalysts: Potassium Iodide Solvents: Dichloromethane; 20 °C -> 52 °C
标题:Preparation Method Of Tetrabromobisphenol A Diene Alkyl Ether
参考文献:China]

103915-73-7 = 97416-84-7
反应条件:1.1 Reagents: Hydrochloric Acid,Sodium Bromide; 8 H,55 °C
标题:Preparation Of 2,2-Bis[4-(2,3-Dibromo-2-Methylpropoxy)-3,5-Dibromophenyl]-Propane As Flame Retardant
参考文献:China]

74893-43-9 = 97416-84-7
反应条件:1.1 Reagents: Bromine Solvents: Dichloromethane; < 10 °C; 30 Min,5 °C1.2 Reagents: Sodium Sulfite Solvents: Water
标题:Method For Crystallizing Tetrabromodiacid A Ether Derivative
参考文献:China]

74893-43-9 = 97416-84-7
反应条件:1.1 Reagents: Bromine,Calcium Chloride Solvents: 1,2-Dichloroethane,Water,Poly(Vinyl Alcohol),Polyacrylamide; 55 °C; 1.5 H,55 °C
标题:Preparation Method Of Two-Step Synthesis Flame Retardant Methyl Octabromo Ether
参考文献:China]

103915-73-7 = 97416-84-7
反应条件:1.1 Reagents: Bromine Solvents: 1,2-Dichloroethane,1,4-Dioxane; 1 H,15 °C; 1.5 H,15 °C1.2 Catalysts: Vanadium Oxide (V2O5),Potassium Bromate Solvents: Water; 70 °C; 6 H,70 °C
标题:Synthesis Method Of 2,2-Bis[3,5-Dibromo-4-(2,3-Dibromo-2-Methylpropoxy)Phenyl]Propane
参考文献:China]

74893-43-9 = 97416-84-7
反应条件:1.1 Reagents: N-Bromosuccinimide,Ammonium Bromide,Ammonium Chloride Catalysts: 2-Iodo-N-Methylbenzamide,2-Iodo-N-(Phenylmethyl)Benzamide Solvents: 1,2-Dichloroethane; 4 H,28 °C
标题:Preparation Of Methyl Octabromo Ether
参考文献:China]

80-05-7 = 97416-84-7
反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Water; Ph 10,Rt -> 50 °C1.2 12 H,< 65 °C1.3 Reagents: Sodium Hydroxide Solvents: Water; < Ph 8,< 65 °C; < 65 °C -> Rt1.4 Reagents: Hydrochloric Acid Solvents: Water; Neutralized,Rt1.5 Reagents: Hydrogen Peroxide,Hydrogen Bromide Solvents: Water; 5 H,27 - 29 °C
标题:Method For Preparing Methyl Octabromo-Ether Flame Retardant
参考文献:China]

74893-43-9 = 97416-84-7
反应条件:1.1 Reagents: Ethanaminium,N,N,N-Triethyl-,Hydrobromide (1:3) Solvents: Dichloromethane; < 25 °C; 5.5 H,16 °C; 16 °C -> 66 °C; 6 H,66 °C; 66 °C -> 100 °C; < 2 H,100 °C
标题:Preparation Of High Content And High Melting Point Flame Retardant Methyl Octabromo Ether
参考文献:China]

74893-43-9 = 97416-84-7
反应条件:1.1 Reagents: Bromine Solvents: 1,4-Dioxane; 9 Min,Rt; 30 Min,Reflux1.2 Reagents: Sodium Bisulfite,Hydrogen Bromide Solvents: Water; Neutralized
标题:Preparation Of Organic Bromine Compounds As Flame Retardants
参考文献:United States]

74893-43-9 = 97416-84-7
反应条件:1.1 Reagents: Bromine Solvents: Dichloromethane,1,4-Dioxane; 9 Min,Rt; 30 Min,39 - 41 °C1.2 Reagents: Sodium Bisulfite Solvents: Water; 39 - 41 °C1.3 Reagents: Sodium Hydroxide Solvents: Water; Neutralized
标题:Production Method Of Bromine Compounds For Fireproofing Agents
参考文献:European Patent Organization]

79-94-7 = 97416-84-7
反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Methanol,Water; 80 Min,Ph 8,Rt; 6 H,Rt -> 65 °C1.2 Reagents: Bromine Solvents: Dichloromethane,1,4-Dioxane; 1 - 2 H,Rt; 2 H,42 °C1.3 Reagents: Sodium Sulfite Solvents: Water; Ph 6,Rt1.4 Reagents: Polyethylene Glycol Nonylphenyl Ether Solvents: Water; 3 H,Rt -> 40 °C; 40 °C -> 65 °C
标题:A Process For Preparing Tetrabromobisphenol A Bis(Dibromoalkyl) Ethers
参考文献:China]

74893-43-9 = 97416-84-7
反应条件:1.1 Reagents: Bromine Catalysts: Tin Tetrachloride Solvents: Dichloromethane; 10 °C; 0.5 H,10 °C1.2 Reagents: Sodium Sulfite Solvents: Water; 0.5 H,Neutralized,0 °C
标题:Preparation Of Methyl Octabromo Ether Of High Purity
参考文献:China]

74893-43-9 = 97416-84-7
反应条件:1.1 Reagents: Sodium Dodecyl Sulfate,Bromine Catalysts: Sodium Bromide Solvents: Water; 4 H,Rt
标题:Preparation Method Of Efficient Flame-Retardant Polypropylene Flame-Retardant Master Batch For Flame Retardant Plastic
参考文献:China]

74893-43-9 = 97416-84-7
反应条件:1.1 Reagents: Tin Tetrachloride,Bromine Solvents: Water; 10 °C; 0.5 H,10 °C
标题:Preparation Method Of High-Thermal Stability Flame Retardant Agent 1,1'-(Isopropylidene)Bis[3,5-Dibromo-4-(2,3-Dibromo-2-Methylpropoxy)Benzene]
参考文献:China]

79-94-7 = 97416-84-7
反应条件:1.1 Reagents: Sodium Hydroxide Catalysts: Tetraethylammonium Bromide Solvents: Water; Ph 9,Rt1.2 Reagents: Bromopyridine Catalysts: Sodium Bromide,Hydrogen Bromide Solvents: Carbon Tetrachloride; 0.5 - 1 H,100 °C; 1 - 2 H,60 °C; 1 - 3 H,35 °C
标题:Preparation Method Of Methyl Octabromo Ether Used As Environmentally-Friendly Flame Retardant
参考文献:China

2,2-Bis[4-(2-Methylallyloxy)Phenyl]Propane置于溴,铁粉体系中,用氯苯作为反应溶剂,以99%的收率获得产物1,1'-(2,2-丙烷二基)二[3,5-二溴-4-(2,3-二溴-2-甲基丙氧基)苯]
参考文献:阻燃剂2,2-双[3,5-二溴-4-(2,3-二溴-2-甲基丙氧基)苯基]丙烷的制备方法
标题:阻燃剂2,2-双[3,5-二溴-4-(2,3-二溴-2-甲基丙氧基)苯基]丙烷的制备方法
摘要:本发明涉及一种溴系阻燃剂2,2‑双[3,5‑二溴‑4‑(2,3‑二溴‑2‑甲基丙氧基)苯基]丙烷的合成制备方法,该方法以双酚a,3‑卤代甲基丙烯,液溴为原料,通过两步法制备2,2‑双[3,5‑二溴‑4‑(2,3‑二溴‑2‑甲基丙氧基)苯基]丙烷;本发明避免了将双酚a首先制备成四溴双酚a的三步法合成2,2‑双[3,5‑二溴‑4‑(2,3‑二溴‑2‑甲基丙氧基)苯基]丙烷,因而减少了反应步骤,降低了合成成本,同时由于将两次溴化减少成一次溴化,也减少了合成过程中的废水产量.