CAS: 547-67-1; Nickel(Ii) Oxalate

英文名称Nickel(Ii) Oxalate
中文名称草酸镍
IUPAC名称nickel(2+);oxalate
其它别名Ethanedioic acid,nickel salt
CAS编号547-67-1
MFCD编号:MFCD00167155
EINECS号:208-933-7
分子式:C2NiO4
分子量:0.0
产品CID: 2498882
产品分类无机化工 → 无机盐 → 金属氧化物酸盐、金属过氧化物酸盐

相似结构搜索
InChIKey: DOLZKNFSRCEOFV-UHFFFAOYSA-L
1S/C2H2O4.Ni/c3-1(4)2(5)6;/h(H,3,4)(H,5,6);/q;+2/p-2…
计算化学: 氢键受体数4.0氢键供体数0.0可旋转键数0.0

MSDS等安全信息

GHS象形图
GHS符号GHS08 & GHS07 & GHS09;
注释: Health hazard & Exclamation mark & Environment
危险类别致癌性类别1A
致突变性类别2
特定目标器官毒性-重复接触类别1
皮肤致敏类别1
水生急性毒性类别1
水生慢性毒性类别1
急性毒性类别4(经皮)
急性毒性类别4(经口)
Skin Mild Irrit. 3
警示词Danger(危险)
危险描述H350i |May cause cancer by inhalation.
H341 |怀疑导致遗传缺陷.
H372 |长期或反复接触损害器官.
H317 |可能引起皮肤过敏反应.
H400 |对水生生物毒性极大.
H410 |对水生生物毒性极大并具有长期持续影响.
H312 |皮肤接触有害.
H302 |吞咽有害.
H350 |可能致癌.
H316 |可能引起轻微皮肤刺激
防范说明P203, P260, P261, P264, P270, P272, P273, P280, P302+P352, P318, P319, P321, P333+P317, P362+P364, P391, P405, and P501
危险类别码See Nickel and linked occupational diseases.

欧盟法规

统一分类与标签REACH注册ECHA物质工作场所安全标识要求ECHA物质化妆品禁用物质清单C&L通报食品接触材料-禁用CMR物质REACH预注册废弃物危险特性清单

上下游产品

tetrachloromethane tetracarbonyl nickel oxalic acid oxalate dianionnickel°Cene nickel tetracarbonyl nickel nickel(II) oxide

合成工艺路线路线简述

合成目标产物 Nickel Oxalate Dihydrate 主要起始原料 Nickel(Ii) Oxide And Oxalic Acid
(文献来源)合成步骤主要原料 Nickel(Ii) Oxide 和 Oxalic Acid

[ni(II)(2,4'-Bipyridine)2(Oxalato)]*2H2O 以 Neat (No Solvent,Solid Phase) 作为反应溶剂,化学反应生成草酸镍
参考文献:
标题:
摘要:The Mixed 2,4'-Bipyridine-Oxalato Complexes Of The Formulae M(2,4'-Bipy)(2)C(2)O(4)2H(2)O (M(II)=mn,Co,Ni,Cu; 2,4'-Bipyridine=2,4'-Bipy Or L; C2O42-=ox) Have Been Prepared And Characterized. Ir Data Show That The 2,4'-Bipy Coordinated With These Metals(II) Via The Least Hindered (4')N Atom; That Oxalate Group Acts As Bidentate Chelating Ligand. Room Temperature Magnetic Moments Are Normal For The Orbital Singlet States. The Thermal Decomposition Of These Complexes Was Investigated By Tg,Dta And Dtg In Air. The Endothermic Or Exothermic Character Of The Decomposition Of Ml2(Ox)2H(2)O Was Discussed.
DOI:10.1023/a:1010193106676