CAS: 34452-56-7; Trimethyl(Tosylethynyl)Silane
- 英文名称Trimethyl(Tosylethynyl)Silane
- 中文名称三甲基(对甲苯炔基)硅烷
- IUPAC名称trimethyl(tosylethynyl)silane
- 其它别名P-Tolyl 2-(Trimethylsilyl)Ethynyl!; 1-(P-Toluenesulfonyl)-2-(Trimethylsilyl)Acetylene, 2-(Trimethylsilyl)Ethynyl P-Tolyl Sulfone; Benzene, 1-Methyl-4-[[2-(Trimethylsilyl)Ethynyl]Sulfonyl]-; Rimethyl-[2-(4-Methylphenyl)Sulfonylethynyl]Silane
- CAS编号34452-56-7
- MFCD编号:MFCD00192508
- EINECS号:627-232-0
- 分子式:C12H16O2SSi分子量:252.41
- 产品CID: 1348018
- 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物
物理性质
MSDS等安全信息
欧盟法规
ECHA物质C&L通报上下游产品
CAS号98-59-9 对甲苯磺酰氯(PTSC) | CAS号14630-40-1 双(三甲基硅基)乙炔 | CAS号86409-87-2 (E)-1-(phenylse... | CAS号68819-94-3 Tosylphenyl selenide | CAS号1066-54-2 三甲基硅基乙炔 | CAS号227454-51-5 1-(2-bromoethyn... | CAS号160732-46-7 2-[(4-Methylphe... | CAS号13894-21-8 乙炔基对甲苯基砜 | CAS号75612-61-2 (4,5-dimethylcy...合成工艺路线路线简述
📜P-Tolyl Benzeneselenosulfonate置于偶氮二异丁腈,间氯过氧苯甲酸体系中,用 二氯甲烷,苯 用作溶剂,化学反应 99.0H,反应生成对甲苯基[2-(三甲基甲硅烷基)乙炔基]砜
参考文献:Selenosulfonation Of Acetylenes: Preparation Of Novel .Beta.-(Phenylseleno)Vinyl Sulfones And Their Conversion To Acetylenic And .Beta.-Functionalized Sulfones
标题:Selenosulfonation Of Acetylenes: Preparation Of Novel .Beta.-(Phenylseleno)Vinyl Sulfones And Their Conversion To Acetylenic And .Beta.-Functionalized Sulfones
摘要:
Doi:10.1021/jo00166A030
海关参考信息
- 2901292000-乙炔
2902300000-甲苯
2930909099-其他有机硫化合物
2904990090-其他烃的磺化、硝化、亚硝化衍生物 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
参考标题:Application Of Two Direct C(Sp3)-H Functionalizations For Total Synthesis Of (+)-Lactacystin作者:Shun Yoshioka,Masanori Nagatomo,Masayuki Inoue |发布日期:2015.1.2
摘要:Route From (S)-Pyroglutaminol To (+)-Lactacystin, A Potent Inhibitor Of The 20S Proteasome. The Photoinduced Intermolecular C(Sp3)-H Alkynylation And Intramolecular C(Sp3)-H Acylation Chemo- And Stereoselectively Constructed The Tetra- And Trisubstituted Carbon Centers, Respectively. The Obtained Bicycle Was Transformed Into The Target Compound In A Concise Manner. The Present Total Synthesis Demonstrates
合成参考文献
摘要:Kawęcki, R., Science of Synthesis Knowledge Updates, (2018) 4, 308.
摘要:Bietti, M.; Dénès, F., Science of Synthesis, (2021) , 512.
📝 需求与反馈
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