CAS: 144054-70-6; (S)-2-Amino-3,3-Dimethyl-1,1-Diphenylbutan-1-Ol

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78603-95-9 86695-06-9 78603-91-5

上下游产品

bromobenzene L-tert-leucine methyl ester hydr°Chloride L-tert-Leucine (S)-2-amino-3,3-dimethyl-butyric acid methyl ester (2S,4S)-4-tert-butyl-2,5,5-triphenyl-oxazolidine (S)-1-hydroxy-3,3-dimethyl-1,1-diphenylbutan-2-amine hydr°Chloride (S)-1-hydroxy-3,3-dimethyl-1,1-diphenylbutan-2-amininium trifluoroacetate

L-叔亮氨酸置于氯化亚砜,Magnesium体系中,用 乙醚 用作溶剂,化学反应 32.5H,反应生成(S)-(-)-2-氨基-3,3-二甲基-1,1-二苯基-1-丁醇
参考文献:Tridentate Ligands Derived From L-Tert-Leucine For The Cu(II) Mediated Asymmetric Henry Reaction
标题:Tridentate Ligands Derived From L-Tert-Leucine For The Cu(II) Mediated Asymmetric Henry Reaction
摘要:手性三齿schiff碱配体由l-叔亮氨酸制备,并作为催化剂在cu(II)离子的存在下进行不对称亨利反应.获得了中等的对映体过剩(高达66%)和产率(高达76%)的目标β-硝醇.
Doi:10.3906/kim-1009-15