📜3-溴-置于lithium Chloride体系中,用 N,N-二甲基甲酰胺 用作溶剂,化学反应 3.0H,反应生成硫代乙酸氯代丙酯
参考文献:Preparation Of ω-Tetrahydropyran-2-Ylsulfanylalkylmagnesium Chlorides: Useful Reagents For The Synthesis Of 1-(ω-Mercaptoalkyl)-1,2-Dihydrobuckminsterfullerenes (C60)
标题:Preparation Of ω-Tetrahydropyran-2-Ylsulfanylalkylmagnesium Chlorides: Useful Reagents For The Synthesis Of 1-(ω-Mercaptoalkyl)-1,2-Dihydrobuckminsterfullerenes (C60)
摘要:Omega-Tetrahydropyran-2-Ylsulfanylalkylmagnesium Chlorides Are Prepared As Grignard Reagents Containing Protected Mercaptoalkyl Chains,Which Are Useful For The Direct Introduction Of Omega-Mercaptoalkyl Chains To Electrophiles. In Order To Prove The Usefulness Of These Reagents,They Were Reacted With Buckminsterfullerene (C(60)) To Give 1-(Omega-Mercaptoalkyl)-1,2-Dihydrobuckminsterfullerenes After The Deprotection Of Thp Group With Tfa. (C) 1998 Elsevier Science Ltd. All Rights Reserved.
Doi:10.1016/s0040-4039(98)02142-X