CAS: 7790-32-1; Magnesium,Diiodate

该化合物是一种无机化合物,其特点是有镁化和碘化阴离子,通常看起来像是白色晶状固体,在水中可溶解,使其分解成镁离子和碘化离子溶解物,这种化合物经常用于各种用途,包括作为碘来源的化学反应和分析化学.镁碘在正常条件下具有稳定性,但能分解供暖,释放碘和其他产品.必须小心处理这一化合物,因为碘化物可能是氧化剂,如果浸入或吸入,可能会对健康造成危害.就其化学行为而言,镁碘化物可以参与红氧化反应,并可能参与其他含碘化合物的合成.

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    专利信息


    专利号:US-2009198084-A1
    优先权日:2006-05-02
    标题:Process for the deprotection of protected amines
    发明人:ALSTERS PAULUS LAMBERTUS; VERKADE JORGE MERIJN MATHIEU; QUAEDFLIEG PETER JAN LEONARD MARIO; RUTJES FLORIS PETRUS JOHANNES
    权利人:ALSTERS PAULUS LAMBERTUS; VERKADE JORGE MERIJN MATHIEU; QUAEDFLIEG PETER JAN LEONARD MARIO; RUTJES FLORIS PETRUS JOHANNES
    摘要:The present invention relates to a process for the deprotection of protected amine compounds, wherein the protected amine compound is contacted with an electrophilic oxidating agent that is optionally formed in situ, said electrophilic oxidating agent being selected from the group of I 2 , Br 2 , Cl 2 and compounds comprising a halogen atom having a formal oxidation state of 1+, 3+, 5+ or 7+, provided that the electrophilic oxidating agent is not iodobenzene diacetate. The process can be conveniently employed in the synthesis of 1,3-amino alcohols, β-amino acids and heterocyclic compounds, in particular β-amino acids.

    专利号:CN-1225634-A
    优先权日:1996-03-20
    标 题 :Synthesis of indolylmaleimides

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    合成参考文献


    参考文献:10.1007/bf00476272
    参考文献:10.1007/bf00476273
    参考文献:10.1007/10312302_38
    摘要:Gupta RR. Nr. 508 - 710. 1986. In: Diamagnetic Susceptibility. : Springer-Verlag; 1986.
    参考文献:10.1007/bf00476271
    参考文献:10.1007/bf02547124
    摘要:Maneva M, Koleva V. Thermal and calorimetric investigations of Mg(IO3)2·nH2O (n=10, 4) and their deuterated analogues. Journal of Thermal Analysis and Calorimetry. 1994 Nov;42(5):1017–23. doi: 10.1007/bf02547124.
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